Structural Phase Transitions in Solid tert-Butylammonium Nitrate as Studied by Differential Thermal Analysis and 1H-NMR
Keyword(s):
H Nmr
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Abstract Seven solid phases including three metastable phases of (CH3)3CNH3NO3 were revealed by differential thermal analysis in the temperature range between 80 K and the melting point (418 K), and cationic dynamics in each phase was studied by use of 1H-NMR techniques. The highesttemperature solid phase obtainable above 412 K was found to be an ionic plastic phase, where the cations perform rapid translational self-diffusion and overall rotation about their center of gravity.
1989 ◽
Vol 44
(8)
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pp. 738-740
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1986 ◽
Vol 90
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pp. 598-605
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1989 ◽
Vol 44
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pp. 1111-1115
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1997 ◽
Vol 52
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pp. 493-501
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1992 ◽
Vol 47
(11)
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pp. 1127-1134
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2019 ◽
Vol 33
(28)
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pp. 1950339
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Differential Thermal Analysis and Dielectric Studies on 2-Methyl-2-Nitro-Propane under High Pressure
1995 ◽
Vol 50
(4-5)
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pp. 502-504
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