π-π Interactions between Pyrylium and Phenyl Rings in the Crystal
1997 ◽
Vol 52
(4)
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pp. 485-489
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Abstract The crystal structures of two isomeric phenyl-substituted pyrylium perchlorates, 2,6-di-methyl-4-phenylpyrylium (1) and 2,4-dim ethyl-6-phenylpyrylium (2), have been determined. Both cations are planar in the crystal so that the electron deficient pyrylium rings can interact strongly with the phenyl rings of adjacent molecules forming stacks along the shortest crystallographic axis. The phenyl rings may act as donors in a charge transfer interaction which is more pronounced in 1 than in 2. Charge transfer appears as a non-mandatory consequence of the π-π stacking. The structures demonstrate the electrostatic nature of these interactions conforming to the model of Hunter and Sanders [ 1 ].
2002 ◽
Vol 67
(8)
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pp. 1154-1164
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2016 ◽
Vol 72
(5)
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pp. 699-703
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Towards the unification of intermolecular forces: the hydrogen bond as a charge-transfer interaction
2012 ◽
Vol 68
(a1)
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pp. s6-s6
Keyword(s):
2017 ◽
Vol 73
(11)
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pp. 1726-1731
Keyword(s):
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