scholarly journals Chemical Constituents of the Lichen Stereocaulon azoreum

1992 ◽  
Vol 47 (7-8) ◽  
pp. 503-507 ◽  
Author(s):  
Antonio G. González ◽  
Elsa M. Rodríguez Pérez ◽  
Consuelo E. Hernández Padrón ◽  
Jaime Bermejo Barrera
Keyword(s):  
Ursolic Acid ◽  
Column Chromatography ◽  
Chemical Constituents ◽  
Acetone Extract ◽  
Ergosterol Peroxide ◽  
First Time ◽  
Acetone Condensation

Column chromatography of the acetone extract of the lichen Stereocaulon azoreum afforded several substances identified by chemical and spectral means; α-amyrin, lupeol, taraxerol, ursolic acid, ergosterol peroxide, brassicasterol, cerevisterol, stictic acid and an acetone-condensation derivative, lobaric acid. Furthermore atranorin, methyl β-orsellinate, atranol and, for the first time from the genus Stereocaulon, cryptostictic acid and the dibenzofuran, strepsilin were isolated.

Chemical Constituents of the Lichen Cladina macaronesica

1991 ◽  
Vol 46 (1-2) ◽  
pp. 12-18 ◽  
Author(s):  
Antonio G . González ◽  
Jaime Bermejo Barrera ◽  
Elsa Ma Rodríguez Pérez ◽  
Consuelo E. Hernández Padrón
Keyword(s):  
Natural Products ◽  
Phenolic Compounds ◽  
Silver Nitrate ◽  
Silica Gel ◽  
Column Chromatography ◽  
Chemical Constituents ◽  
Usnic Acid ◽  
Acetone Extract ◽  
First Time

Column chromatography of the acetone extract of the lichen Cladina macaronesica (Sephadex LH-20, silica gel and silver nitrate-im pregnated silica gel) afforded eight triterpenes identified by chemical and spectral m eans. α-Amyrenone, lupenone, taraxerol, taraxerone and /so-arborinol acetate were isolated for the first time from lichens and (-)-usnic acid and five mononuclear phenolic compounds were also obtained, four for the first time as natural products. The possible transformation of perlatolic acid into these phenolic compounds is briefly outlined.

Chemical Constituents of Euphorbia marschalliana Boiss

2004 ◽  
Vol 59 (1-2) ◽  
pp. 15-18 ◽  
Author(s):  
Amir Reza Jassbi ◽  
Simin Zamanizadehnajari ◽  
Satoshi Tahara
Keyword(s):  
Chemical Constituents ◽  
Acetone Extract ◽  
Aerial Parts ◽  
First Time

Acetone extract of aerial parts of Euphorbia marschalliana collected from Iran has been subjected to different chromatography techniques for fractionation and purification. The stereo- structures of the myrsinol esters 15-O-acetyl-3-O-propionyl-5-O-butanoyl-7-O-nicotinoylmyrsinol (1) and 15-O-acetyl-3,5-O-dibutanoyl-7-O-nicotinoylmyrsinol (2) have been probed using ROESY spectroscopy and modified for the stereochemistry at C-6, C-12 and C-13. β-Sitosterol (3), 29-norcycloart-5-ene (4), 5,8-lanostadiene-3β-ol (5), 3β,24(S),25-trihydroxycycloartane (6), 3β,24(R),25-trihydroxycycloartane (7) and 24-methylenecycloartan-3β-ol (8) were identified for the first time in this plant.

Extraction and Purification of Polyphenolic Compounds Obtained from Hsian-Tsao (Mesona Procumbens Hemsl.)

2012 ◽  
Vol 550-553 ◽  
pp. 1790-1795 ◽  
Author(s):  
Zhi Xian Huang ◽  
Ting Qiu ◽  
Xiao Cui Lin ◽  
Yan Xiang Wu
Keyword(s):  
Lipid Peroxidation ◽  
Column Chromatography ◽  
Polyphenolic Compounds ◽  
Maximum Amount ◽  
Flavonol Glycoside ◽  
Acetone Extract ◽  
Adsorption Column ◽  
Extraction And Purification ◽  
Polyphenolic Content ◽  
First Time

Extraction and purification of polyphenolic compounds from Hsian-tsao (Mesona procumbens Hemsl.) were investigated. The polyphenolic compounds were extracted by using acetone, ethanol or methanol at three different concentrations. The polyphenolic concentration and the inhibition of lipid peroxidation were determined. The results showed that, among solvents tested, 75% acetone solvent extracted a maximum amount of polyphenolic compounds from Hsian-tsao. The 75% acetone extract was purified further by AB-8 adsorption column chromatography and eight fractions, A~H, were obtained. Among eight fractions, Fraction E had the highest polyphenolic content and inhibition(76%). Moreover, Fraction E was separated into four polyphenolic compounds (1~4) by HPLC and each compound reached a purity of more than 98%. The structure of the compound was identified by LC-MS and NMR, and the compound-4 was determined to be astragalin (a flavonol glycoside) which was obtained from HT for the first time.

scholarly journals Chemical Constituents from the Fruits ofForsythia suspensaand Their Antimicrobial Activity

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Ping-Chung Kuo ◽  
Guo-Feng Chen ◽  
Mei-Lin Yang ◽  
Ya-Hua Lin ◽  
Chi-Chung Peng
Keyword(s):  
Escherichia Coli ◽  
Antimicrobial Activity ◽  
Column Chromatography ◽  
Chemical Constituents ◽  
Phenylethanoid Glycosides ◽  
Natural Sources ◽  
Methanol Extracts ◽  
Lead Compounds ◽  
Forsythia Suspensa ◽  
First Time

Lignans and phenylethanoid glycosides purified fromForsythia suspensawere reported to display various bioactivities in the previous literature, including the antimicrobial activity. Therefore, the present research is aimed to purify and identify the chemical constituents of the methanol extracts of fruits ofF. suspensa. The methanol extracts of fruits ofF. suspensawere fractionated and further purified with the assistance of column chromatography to afford totally thirty-four compounds. Among these isolates, 3β-acetoxy-20α-hydroxyursan-28-oic acid (1) was reported from the natural sources for the first time. Some of the purified principles were subjected to the antimicrobial activity examinations againstEscherichia colito explore new natural lead compounds.

scholarly journals Chemical Constituents of the Insecticidal Active Extract of Tinospora crispa

2019 ◽  
Vol 10 (1) ◽  
pp. 23
Author(s):  
Nor Aziyah Bakhari ◽  
Siti Nur Amirah Diana Fadzillah ◽  
Norain Isa
Keyword(s):  
Blood Pressure ◽  
Petroleum Ether ◽  
Silica Gel ◽  
1H Nmr ◽  
Column Chromatography ◽  
Mobile Phase ◽  
Spectroscopic Data ◽  
Chemical Constituents ◽  
Ethanol Extract ◽  
First Time

Tinospora crispa Miers (Menispermaceae) is a climbing vine with stems rich in warts. The plant is called Akar Seruntum or Patawali in Malaysia and is widely used for treating skin complaints, malaria, bacterial abscess, high blood pressure and diabetes. In the present study, the stems of T. crispa were collected from the locality and succesively extracted with petroleum ether, followed by chloroform and ethanol. The insecticidal active extract (ethanol extract) was  subjected to column chromatography of silica gel eluted with a gradient mobile phase containing hexane, chloroform and ethanol. Among the chemical constituents isolated are n-tetracosyl trans-ferulate and n-octacosyl alcohol, along with three known aporphine alkaloids; N-formylnornuciferine, N-acetylnornuciferine and lysicamine. All compounds were identified by comparing their spectroscopic data (UV, IR, 1H NMR, MS) with data from corresponding values in the literature. Isolation of n-tetracosyl trans-ferulate and n-octacosyl alcohol is reported the first time for T. crispa.

scholarly journals (4S)-4,8-dihydroxy-1-tetralone and other chemical constituents from Pestalotiopsis sp. EJC07, endophytic fromBauhinia guianensis

2016 ◽  
Vol 88 (1) ◽  
pp. 29-33 ◽  
Author(s):  
Eleane M.C. de Souza ◽  
Ellon L. Da Silva ◽  
Andrey M.R. Marinho ◽  
Patrícia S.B. Marinho
Keyword(s):  
Spectral Methods ◽  
Chemical Constituents ◽  
2D Nmr ◽  
Hydroxybenzoic Acid ◽  
Ergosterol Peroxide ◽  
First Time

The present work reports the isolation of eight compounds fromPestalotiopsis sp. EJC07 isolated as endophytic fromBauhinia guianensis, a tipical plant of the Amazon. The compounds (4S)-4,8-dihydroxy-1-tetralone (1), uracil (2), uridin (3), p-hydroxybenzoic acid (4), ergosterol (5), ergosterol peroxide (6), cerevisterol (7) and ducitol (8) were isolated by chromatographic procedures and identified by spectral methods of 1D and 2D NMR and MS. The compound 1 is being reported for the first time in the genusPestalotiopsis.

Studies on Chemical Constituents of the Baphicacanthus cusia (Nees) Bremek Root

2012 ◽  
Vol 550-553 ◽  
pp. 1759-1762 ◽  
Author(s):  
Yi Pei ◽  
Cong Shi ◽  
Jiang Li Nie ◽  
Ying Mei Han ◽  
Dong Wang
Keyword(s):  
Spectral Analysis ◽  
Physicochemical Properties ◽  
Column Chromatography ◽  
Chemical Constituents ◽  
Separation And Purification ◽  
Compound I ◽  
Analysis Methods ◽  
Compound Ii ◽  
First Time ◽  
Root Methods

Objective: Studies on the chemical constituents of the Baphicacanthus plants, Baphicacanthus cusia (Nees) Bremek root. Methods: Using Column chromatography to separation and purification. Identify the compounds structures through the Physicochemical properties and spectral analysis methods. Result: Isolated 9 compounds from the Baphicacanthus cusia (Nees) Bremek roots. They were identified as Stigmasterol-3-O-β-D–glucoside(I), Spinasterol-3-O-β-D– glucoside(Ⅱ),2-(3,4-dihydroxyphenylacetic phenylethyl)]-3O-α-L-rhamnosyl-(1 → 4)-(4-O-caffeoyl)-β-D-pyran-glucosidase(III), Lupeol(Ⅳ), Indigo(Ⅴ), Indirubin (VI), Sucrose (Ⅶ), Adenosine (VIII), β-sitosterol(IX). Among them, compound I and compound II are compounds that at the first time isolated from this plant.

scholarly journals Chemical constituents of ethanol extract of leaves and molluscicidal activity of crude extracts from vitex trifolia linn.

2013 ◽  
Vol 59 (4) ◽  
pp. 19-32 ◽  
Author(s):  
Jeet S. Jangwan ◽  
Rita P. Aquino ◽  
Teresa Mencherini ◽  
Patrizia Picerno ◽  
Raghubir Singh
Keyword(s):  
Ursolic Acid ◽  
Chemical Constituents ◽  
Ethanolic Extract ◽  
Ethanol Extract ◽  
2D Nmr ◽  
Chloroform Extract ◽  
Biomphalaria Alexandrina ◽  
The Family ◽  
Hexane Extracts ◽  
First Time

Abstract β-sitosterol and two triterpenoids: ursolic acid acetate and platanic acid have been isolated from ethanolic extract of Vitex trifola leaves. β-sitosterol was previously isolated from the leaves, stem and seeds of Vitex trifolia. Ursolic acid acetate has been isolated for the first time in this plant species. Platanic acid has been reported for the first time in Vitex trifolia and even in the family of this plant: Verbenaceae. These compounds were characterized using spectroscopic methods including 1D-1HNMR, 13CNMR, ESIMS and 2D-NMR (HSQC, HMBC, COSY) experiments and confirmed by comparison of their NMR data with those from the literature. A preliminary molluscicidal test for ethanol, chloroform and n-hexane extracts of leaves of Vitex trifolia against Biomphalaria alexandrina adult snails showed that ethanol extract of leaves with LC50 value 26.42 mg/l (27.92 mg/l - 24.99 mg/l) was more effective than n-hexane extract with LC50 value 35.48 mg/l (43.81 mg/l - 28.72mg/l) and chloroform extract with LC50 value 46.77 mg/l (53.59 mg/l - 43.81 mg/l) after 24 h exposure.

Chemical constituents from the bark of Anisopus mannii

2009 ◽  
Vol 87 (2) ◽  
pp. 397-400 ◽  
Author(s):  
Apollinaire Tsopmo ◽  
Pierre Kamnaing ◽  
Jean Watchueng ◽  
Jin-Ming Gao ◽  
Yasuo Konishi ◽  
...  
Keyword(s):  
Ferulic Acid ◽  
Spectroscopic Data ◽  
Chemical Constituents ◽  
2D Nmr ◽  
Acetone Extract ◽  
A Minor ◽  
First Time

A minor novel 1,7-naphthyridine alkaloid with an unprecedented skeleton, named anisopusine (1), was isolated from the CH2Cl2 soluble materials of an acetone extract of the bark of Anisopus mannii (Asclepiadaceae) together with four known compounds 5α-hydroxy-lup-20(29)-en-3β-yl eicosanoate (2), [6]-gingerdione (3), [6]-dehydrogingerdione (4), and ferulic acid (5). Their structures were determined on the basis of spectroscopic data, including 1D and 2D NMR, HR-EI-MS. Compounds (2–5) were characterized for the first time from this genus.

scholarly journals CHEMICAL CONSTITUENTS FROM POLYGONATUM KINGIANUM COLL. ET HEMSL. OF VIETNAM

2020 ◽  
Vol 58 (5) ◽  
pp. 549
Author(s):  
Lê Minh Hà
Keyword(s):  
Spectral Data ◽  
Nmr Spectra ◽  
Chemical Constituents ◽  
Dienoic Acid ◽  
2D Nmr ◽  
Ergosterol Peroxide ◽  
2D Nmr Spectra ◽  
First Time

Seven compounds, including two homoisoflavanones 3-(2ʹ-hydroxy-4ʹ-methoxy-benzyl)-5,7-dihydroxy-8-methyl-chroman-4-one (1), disporopsin (2) along with 2-O-methyl-α-D-fructofuranose (3), (E,E)-9-oxooctadeca-10,12-dienoic acid (4), 1-palmitoylglycerol (5), 5α,8α-ergosterol  peroxide (6),  daucosterol (7) were isolated from the rhizomes of Polygonatum kingianum of Vietnam. Their structures were determined by 1D and 2D NMR spectra and by comparison with the reported spectral data. Compounds 3, 4 and 6 are first reported from the genus Polygonatum. Compound 1 and 5 are reported for the first time from Polygonatum kingianum.

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