Technological Cascade for Purification of Zirconium Tetrafluoride from Hafnium Using Zirconium Dioxide

1964 ◽  
Vol 17 (7) ◽  
pp. 727 ◽  
Author(s):  
FK McTaggart ◽  
AG Turnbull

Zirconium difluoride was prepared by the action of atomic hydrogen on thin layers of zirconium tetrafluoride, at a temperature of approximately 350�. The compound is orthorhombic in structure. It is black, tends to take up oxygen in air, and ignites readily and burns to form zirconium dioxide. Disproportionation occurs at 800� with the formation of ZrF4 and zirconium, and other chemical properties are similar to those of the known dihalides of Group IVA.


Author(s):  
R.A. Ploc

Samples of low-nickel Zircaloy-2 (material MLI-788-see(1)), when anodically polarized in neutral 5 wt% NaCl solutions, were found to be susceptible to pitting and stress corrosion cracking. The SEM revealed that pitting of stressed samples was occurring below a 2000Å thick surface film which behaved differently from normal zirconium dioxide in that it did not display interference colours. Since the initial film thickness was approximately 65Å, attempts were made to examine the product film by transmission electron microscopy to deduce composition and how the corrosion environment could penetrate the continuous layer.


2020 ◽  
Author(s):  
I. F. Zakirov ◽  
Yu. V. Ivanova ◽  
A. V. Shak

2021 ◽  
Vol 270 ◽  
pp. 115200
Author(s):  
S. Idrissi ◽  
S. Ziti ◽  
H. Labrim ◽  
L. Bahmad

2021 ◽  
pp. 100750
Author(s):  
N. Sundar ◽  
S. Ananda Kumar ◽  
P. Keerthana ◽  
S. Johan Stanley ◽  
G. Ananda Kumar

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3102
Author(s):  
Rini Behera ◽  
Lora Mishra ◽  
Darshan Devang Divakar ◽  
Abdulaziz A. Al-Kheraif ◽  
Naomi Ranjan Singh ◽  
...  

The objective of the present study was to evaluate the one-year clinical performance of lithium disilicate (LD) and zirconium dioxide (ZrO2) class II inlay restorations. Thirty healthy individuals who met the inclusion criteria were enrolled for the study. The patients were randomly divided into two study groups (n = 15): LD (IPS e.max press) and ZrO2 (Dentcare Zirconia). In the ZrO2 group, the internal surfaces of the inlays were sandblasted and silanized with Monobond N (Ivoclar, Leichsteistein, Germany). In the LD group, the internal surfaces of the inlays were etched with 5% hydrofluoric acid. The ceramic inlays were cemented with self-cure resin cement (Multilink N). Clinical examinations were performed using modified United State Public Health Codes and Criteria (USPHS) after 2 weeks, 4 weeks, 6 months and 1 year. The one-year survival rate was evaluated. In total, one failure was observed in the ZrO2 group. The survival probability after 1 year for the ZrO2 inlays was 93%, and for the LD inlays was 100%, which was statistically insignificant. The differences between both groups for most USPHS criteria (except for colour match) were statistically insignificant. Within the imitations of the present study, the lithium disilicate- and zirconia dioxide-based inlays exhibited comparable clinical performances. However, the colour and translucency match was superior for the lithium disilicate restorations.


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