scholarly journals Further Understanding the Combined Bleaching Process of Peroxide and Optical Brightening Agent in a Spruce Thermomechanical Pulp

BioResources ◽  
2018 ◽  
Vol 13 (2) ◽  
Author(s):  
Hongjie Zhang ◽  
Ming Lei ◽  
Wenhui Zhang ◽  
Qun Li ◽  
Fengshan Zhang ◽  
...  
Keyword(s):  
Thermomechanical Pulp ◽  
Bleaching Process

scholarly journals Kinetic study on iso-concentration hydrogen peroxide bleaching of poplar chemi-thermomechanical pulp by the process of continuous chemical supplement

BioResources ◽  
2018 ◽  
Vol 13 (3) ◽  
pp. 5408-5415
Author(s):  
Xianqi Sun ◽  
Qingxi Hou ◽  
Haizhen Shi ◽  
Lichun Zhou
Keyword(s):  
Kinetic Model ◽  
Initial Phase ◽  
Reaction Rate ◽  
Reaction Order ◽  
Slow Phase ◽  
Thermomechanical Pulp ◽  
Bleaching Process ◽  
Peroxide Bleaching ◽  
Bleached Pulp ◽  
Continuous Chemical

In the authors’ previous studies, a bleaching process based on continuous chemical supplementation (CCS) was proposed to improve the effectiveness of peroxide bleaching of chemi-thermomechanical pulp (CTMP). In this study, the kinetic model of the CCS process of peroxide bleaching was applied to poplar CTMP to explore how the bleaching rate was affected. The model was based on the rate of chromophore elimination characterized by the brightness gains of bleached pulp. The reaction rate of chromophore destruction proceeded via a rapid initial phase followed by a slow phase. The equation of reaction rate was confirmed. The value of reaction order was -3.62, and the activation energy was 288.8 kJ/mol. The developed kinetic model was a good fit for the experimental results.

Pilot trials of hemicelluloses extraction prior to thermomechanical pulp production: Part 1

TAPPI Journal ◽  
2011 ◽  
Vol 10 (5) ◽  
pp. 21-28 ◽  
Author(s):  
CARL HOUTMAN ◽  
ERIC HORN
Keyword(s):  
Oxalic Acid ◽  
Energy Savings ◽  
Wood Chip ◽  
Strength Properties ◽  
Thermomechanical Pulp ◽  
Sugar Solution ◽  
Bisulfite Treatment ◽  
Pilot Trials ◽  
Pulp Production ◽  
Production Part

Pilot data indicate that wood chip pretreatment with oxalic acid reduced the specific energy required to make thermomechanical pulp. A combined oxalic acid/bisulfite treatment resulted in 21% refiner energy savings and 13% increase in brightness for aspen. A low level of oxalic acid treatment was effective for spruce. Energy savings of 30% was observed with no significant change in strength properties. Adding bisulfite did not significantly increase the brightness of the spruce pulp. For pine, the optimum treatment was a moderate level of oxalic acid, which resulted in 34% energy savings and an increase in strength properties. For all of these treatments 1–3 w/w % carbohydrates were recovered, which can be fermented to produce ethanol. The extract sugar solution contained significant quantities of arabinose.

Use of thermomechanical pulp fibers from waste woods for making eco-friendly cushioning material

TAPPI Journal ◽  
2010 ◽  
Vol 9 (7) ◽  
pp. 15-21 ◽  
Author(s):  
JI-YOUNG LEE ◽  
CHUL-HWAN KIM ◽  
JEONG-MIN SEO ◽  
HO-KYUNG CHUNG ◽  
KYUNG-KIL BACK ◽  
...  
Keyword(s):  
Impact Test ◽  
Product Distribution ◽  
Expanded Polystyrene ◽  
Thermomechanical Pulp ◽  
Fiber Structure ◽  
Pulp Fibers ◽  
Cationic Starch ◽  
Thermal Insulating ◽  
Surface Sizing ◽  
The Impact

Eco-friendly cushioning materials were made with thermomechanical pulps (TMPs) from waste woods collected from local mountains in Korea, using a suction-forming method without physical pressing. The TMP cushions had superior shock-absorbing performance, with lower elastic moduli than expanded polystyrene (EPS) or molded pulp. Even though the TMP cushions made using various suction times had many voids in their inner fiber structure, their apparent densities were a little higher than that of EPS and much lower than that of molded pulp. The addition of cationic starch contributed to an increase in the elastic modulus of the TMP cushions without increasing the apparent density, an effect which was different from that of surface sizing with starch. In the impact test, the TMP cushions showed a more ductile pattern than the brittle EPS. The porosity of the TMP cushion was a little less than that of EPS and much greater than that of molded pulp. The porous structure of the TMP cushions contributed to their excellent thermal insulating capacity, which was equivalent to that of EPS. In summary, the TMP packing cushions showed great potential for surviving external impacts during product distribution.

Photocolouration of 2,4,4,6-Tetraaryl-4H-pyrans and Their Heteroanalogues: Importance of Hypervalent Photoisomers

1995 ◽  
Vol 60 (10) ◽  
pp. 1621-1633 ◽  
Author(s):  
Stanislav Böhm ◽  
Mojmír Adamec ◽  
Stanislav Nešpůrek ◽  
Josef Kuthan
Keyword(s):  
Reaction Kinetics ◽  
Absorption Spectra ◽  
Electronic Absorption ◽  
Electronic Absorption Spectra ◽  
Theoretical Data ◽  
Order Reaction ◽  
Bleaching Process ◽  
First Order ◽  
Photodegradation Products ◽  
Hypervalent Molecules

Molecular geometries of 2,4,4,6-tetraphenyl-4H-pyran (Ia), 4,4-(biphenyl-2,2e-diyl)-2,6-diphenyl-4H-pyran (Ib) and their heterocyclic isomers II-V were optimized by the PM3 method and used for the calculation of electronic absorption spectra by the CNDO/S-CI procedure. Comparison of the theoretical data with experimental UV-VIS absorption spectra made possible to select hypervalent molecules IIIa, IIIb, IVa and IVb being responsible for the photocolouration of 4H-pyrans Ia, Ib, while compounds Va, Vb, VI and VII come into account as possible photodegradation products. The bleaching process of the UV illuminated compound Ia is analyzed in terms of dispersive first-order reaction kinetics.

An environmentally friendly bleaching process for cotton fabrics: mechanism and application of UV/H2O2 system

Cellulose ◽  
2019 ◽  
Vol 27 (2) ◽  
pp. 1071-1083
Author(s):  
Nanfang Wang ◽  
Peixin Tang ◽  
Cunyi Zhao ◽  
Zheng Zhang ◽  
Gang Sun
Keyword(s):  
Environmentally Friendly ◽  
Cotton Fabrics ◽  
Bleaching Process ◽  
H2o2 System
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