Abstract
1. The researches so far published on the autohesion of polymers do not make it possible to isolate the influence of the mechanical properties of rubbers, which determine the true area of contact, from the influence of polymer chain diffusion. 2. Studies of the autohesion of thin films of rubber applied by the drain-off method to quartz threads, in relation to the film thickness and contact time, show that for films less than 3.10−5 cm. thick the adhesion force is small and varies very little with contact time. This proves, on the one hand, that in this instance the contact area is small (which is obvious) and does not increase with time, and on the other hand, that diffusion processes play no part in the autohesion of films of this thickness. 3. The effects which depend on mechanical properties and on the specific interaction (per unit area of true contact) between specimens may be separated if the measured values of adhesion between all possible combinations of pairs of rubbers are compared both with their compatibilities, and with their autohesion. 4. The measurements of the adhesional shearing strength of combinations of different pairs of polymers, carried out for this purpose, showed that the results for Butyl rubber may be interpreted on the assumption that diffusion processes do not play any appreciable role and that the adhesion strength is determined both by the true contact area, which depends on the mechanical properties of the corresponding polymer specimens, and also by the influence of forces associated with the electric double layer. 5. For the other rubbers the results may be interpreted only on the assumption that diffusion processes play a significant part. For similar polarities, T12/T11>1 and for dissimilar polarities, T12/T11<1. 6. General conclusion : autohesion and mutual adhesion of rubbers is determined both by mechanical properties, which determine the true contact area, and by diffusional properties. The latter are by no means always decisive. The electric double layer also probably influences the adhesional shearing strength in some instances. It is even more likely to play a role in some cases in measurements of the work of separation of two layers.