pO2 stability of Ba0.5Sr0.5Co0.8Fe0.2O3-δ

2011 ◽  
Vol 1309 ◽  
Author(s):  
Stefan F. Wagner ◽  
Simon Taufall ◽  
Christian Niedrig ◽  
Holger Götz ◽  
Wolfgang Menesklou ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Chemical Stability ◽  
Coulometric Titration ◽  
Stability Limit ◽  
Operating Conditions ◽  
Perovskite Oxide ◽  
Low Oxygen ◽  
Electrical Measurements ◽  
Oxygen Pump

ABSTRACTThe mixed-conducting perovskite oxide Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF), given its outstanding oxygen ionic and electronic transport properties, is considered a promising material composition for oxygen transport membranes (OTM) operated at high temperatures.Its long-term stability under operating conditions is, however, still an important issue. Although the incompatibility of BSCF with CO2-containing atmospheres can be avoided by appropriate means (oxyfuel processes in the absence of carbon dioxide), the thermal as well as the chemical stability of BSCF itself are still under thorough investigation.This work is focused on the stability of BSCF in the targeted temperature range for OTM applications (700…900 °C) and in atmospheres with low oxygen contents. Previous studies in literature suggest limited chemical stability below oxygen partial pressures pO2 of around 10-6 bar.By using a coulometric titration method based on a zirconia “oxygen pump” setup, precise control of the oxygen partial pressure pO2 between 1 bar and 10-18 bar was facilitated. Combining electrical measurements on dense ceramic bulk samples performed as a function of pO2 with an XRD phase composition study of single phase BSCF powders subjected to various pO2 treatments, an assessment of the chemical stability of BSCF is facilitated as a function of oxygen partial pressure. It could thus be shown that the pO2 stability limit is considerably lower than previously assumed in literature.

scholarly journals Flux-Free Brazing of Aluminum Alloys under Ultra-Low Oxygen Partial Pressure through a Zirconia Oxygen Pump

2021 ◽  
Author(s):  
Tomoyuki Shinoda ◽  
Shumpei Ozawa ◽  
Kenta Kawashima ◽  
Kazuhiko Kuribayashi ◽  
Tomoki Yamayoshi ◽  
...  
Keyword(s):  
Aluminum Alloys ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Low Oxygen ◽  
Oxygen Pump

Quantitative evaluation of the oxidation behavior of ZrB2-15 vol.%SiC at a low oxygen partial pressure

Vacuum ◽  
2013 ◽  
Vol 88 ◽  
pp. 98-102 ◽  
Author(s):  
Ai Momozawa ◽  
Rong Tu ◽  
Takashi Goto ◽  
Yuuki Kubota ◽  
Hiroshi Hatta ◽  
...  
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Quantitative Evaluation ◽  
Oxidation Behavior ◽  
Low Oxygen

Enhanced superconductivity in Nd1+xBa2-xCu3O7+δby low oxygen partial pressure annealing

1994 ◽  
Vol 23 (11) ◽  
pp. 1117-1120 ◽  
Author(s):  
M. J. Kramer ◽  
A. Karion ◽  
K. W. Dennis ◽  
M. Park ◽  
R. W. McCallum
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Low Oxygen ◽  
Enhanced Superconductivity

Controlled partial melting during isobaric and isothermal processing of dipcoated Bi-2212/Ag tapes

1998 ◽  
Vol 13 (12) ◽  
pp. 3580-3586 ◽  
Author(s):  
A. L. Crossley ◽  
J. L. MacManus-Driscoll
Keyword(s):  
Phase Diagram ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Partial Melting ◽  
Coulometric Titration ◽  
Processing Route ◽  
Optimum Processing ◽  
Partial Pressures ◽  
Titration Technique

A detailed study has been made of the control and optimization of partial melting of dipcoated Bi2Sr2Ca1Cu2O8+δAg0.1 (Bi-2212) tapes using reduced oxygen partial pressures. A coulometric titration technique has been employed to vary the oxygen partial pressure in a region of the phase diagram corresponding to binary melting, and the amount of partial melting has been quantified. Using this information, tapes have been processed using both isothermal and isobaric techniques. An optimum processing route was determined which combined isothermal and isobaric processes. Highly aligned material at the point of optimum melting was obtained.

CHEMICAL STABILITY OF0.50.50.80.23-δUNDER DIFFERENT OXYGEN PARTIAL PRESSURE

2012 ◽  
pp. 228-234
Author(s):  
FANG WANG ◽  
KEIJI YASHIRO ◽  
KOJI AMEZAWA ◽  
JUNICHIRO MIZUSAKI
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Chemical Stability

Tensile Properties and Creep Behavior of SiC-Based Fibers under Various Oxygen Partial Pressures

2005 ◽  
Vol 475-479 ◽  
pp. 1333-1336 ◽  
Author(s):  
Jan Ji Sha ◽  
J.S. Park ◽  
Tatsuya Hinoki ◽  
Akira Kohyama ◽  
J. Yu
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Tensile Properties ◽  
Creep Behavior ◽  
Elevated Temperatures ◽  
Low Oxygen ◽  
X Ray Diffraction ◽  
Sic Fibers ◽  
Partial Pressures ◽  
Ar Gas

Three kinds of atmospheres (air, highly-pure Ar and ultra highly-pure Ar gas) with different oxygen partial pressures were applied to investigate the tensile properties and creep behavior of SiC fibers such as Hi-NicalonTM and TyrannoTM-SA. These fibers were annealed and crept at elevated temperatures ranging from1273-1773 K in such environments. After annealing at 1773 K, the room temperature tensile strengths of SiC-based fibers decreased with decreasing the oxygen partial pressure and the near stoichiometric fiber TyrannoTM-SA shows excellent strength retention. At temperatures above the 1573 K, the creep resistance of SiC fibers evaluated by bending stress relaxation (BSR) method under high oxygen partial pressure was lower than that of in low oxygen partial pressure. The microstructural features on these fibers were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD).

Preparation of NdBaCuO superconductor by zone-melting under low oxygen partial pressure

2003 ◽  
Vol 386 ◽  
pp. 241-244 ◽  
Author(s):  
Zhanguo Fan ◽  
Weiying Gao ◽  
Fenghua Li ◽  
Jue Wang ◽  
Deahua Soh
Keyword(s):  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Zone Melting ◽  
Low Oxygen

Examples of the Practical Use of Non-Stoichiometric Compounds

1994 ◽  
Author(s):  
Koji Kosuge
Keyword(s):  
Solid State ◽  
Oxygen Partial Pressure ◽  
Partial Pressure ◽  
Oxygen Pressure ◽  
Closed System ◽  
Electromotive Force ◽  
Solid Electrolytes ◽  
Coulometric Titration ◽  
Preparation Methods ◽  
Basic Characteristics

In this chapter, we describe four kinds of non-stoichiometric compound, which are or will be in practical use, from the viewpoint of preparation methods or utility. As a first example, the solid electrolyte (ZrO2)0.85(CaO)0.15 is described, which are discussed in Sections 1.4.6–1.4.8 from the viewpoint of basic characteristics. The second example is the magnetic material Mn–Zn ferrite, for which the control of non-stoichiometry and the manufacturing process will be described. Then the metal hydrides or hydrogen absorbing alloys, which are one of the most promising materials for storing and transporting hydrogen in the solid state, are described, mainly focusing on the phase relation. Finally, we describe the relation between the control of composition and the growth of a single crystal of the semiconductive compound GaAs, which is expected to give electronic materials for 1C and LSI etc. Solid electrolytes, which show ionic conductivity in the solid state, are considered to be potential materials for practical use, some are already used as mentioned below. Solid electrolytes have characteristic functions, such as electromotive force, ion selective transmission, and ion omnipresence. Here we describe the practical use of calcia stabilized zirconia (CSZ), (ZrO2)0.85(CaO)0.15, the structure and basic properties of which are discussed in detail in Sections 1.4.5–1.4.8. The most simple practical application of CSZ is for the gauge of oxygen partial pressure, as mentioned in Sections 1.4.7 and 1.4.8. The oxygen partial pressure P2o2 in the closed system as shown in Fig. 3.1 can be measured, taking the air as the standard oxygen pressure P1o2. The electromotive force (EMF) of this concentration cell is expressed as . . . E = (RT/4F)ln(P1o2/ P2o2) . . . This principle is applied in the measurement of oxygen partial pressure in laboratory experiments and of the oxygen activity of slag in refineries. Based on the principle of coulometric titration (see Section 1.4.8), the oxygen partial pressure of a closed system can be kept constant by feedback of the EMF, in the oxygen pressure range 1 to 10−7 atm. By use of this closed system, investigations on redox reactions of metals and also enzyme reactions have been carried out.

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