The Role of Contact Adhesion in Friction and Wear of Graphene under Sliding Conditions

2013 ◽  
Vol 1505 ◽  
Author(s):  
Emil J. Sandoz-Rosado ◽  
Elon J. Terrell

ABSTRACTIn this study, the failure mechanisms of graphene under sliding are examined using atomistic simulations. A 6nm diameter diamond tip is slid (at a controlled normal load) over a graphene monolayer that is adhered to a semi-infinite silicon substrate. The impact of tip adhesion on the wear and frictional behavior of graphene is studied by comparing two diamond tips, one of which has been hydrogen-passivated and the other which is bare carbon. By contrasting the passivated and unpassivated tips, the interplay of adhesive and abrasive wear on the graphene membrane can also be compared. The results of this work indicate that chemical bonding between the tip and the graphene greatly exacerbates tearing in the graphene monolayer by plowing ahead of the indenter, causing material build-up and increasing effective contact area.

2021 ◽  
pp. 1-12
Author(s):  
Vimal Edachery ◽  
V. Swamybabu ◽  
Gurupatham Anand ◽  
Paramasamy Manikandan ◽  
Satish V. Kailas

Abstract Surface topography is a critical parameter that can influence friction and wear in engineering applications. In this work, the influence of surface topography directionality on seizure and scuffing initiation during tribological interactions is explored. For this, unidirectional sliding wear experiments were carried out in immersed lubrication conditions for various normal loads. The tribological interactions were studied using EN31-60 HRC flats and SAE52100-60HRC pins in a sphere on flat configuration. The results show that, in some cases, the sliding interactions in the initial cycles lead to a high friction coefficient of up to ∼0.68 in lubricated conditions, which was termed as ‘peak friction’, and this was accompanied by scuffing. The existence of peak friction was found to be dependent on surface topography directionality, especially when the directionality in topography was parallel to the sliding direction. Continuous ratchetting was found to be the cause of peak friction which was accompanied by seizure and scuffing. When the topography directionality was perpendicular or independent of sliding direction, elastic shakedown occurred at earlier cycles and prevented peak friction initiation, scuffing and also facilitated for higher steady-state friction values.


2021 ◽  
Author(s):  
Josiah Mushanyu ◽  
Williams Chukwu ◽  
Farai Nyabadza ◽  
Gift Muchatibaya

Superspreading phenomenon has been observed in many infectious diseases and contributes significantly to public health burden in many countries. Superspreading events have recently been reported in the transmission of the COVID-19 pandemic. The present study uses a set of nine ordinary differential equations to investigate the impact of superspreading on COVID-19 dynamics. The model developed in this study addresses the heterogeineity in infectiousness by taking into account two forms of transmission rate functions for superspreaders based on clinical (infectivity level) and social or environmental (contact level). The basic reproduction number has been derived and the contribution of each infectious compartment towards the generation of new COVID-19 cases is ascertained. Data fitting was performed and parameter values were estimated within plausible ranges. Numerical simulations performed suggest that control measures that decrease the effective contact radius and increase the transmission rate exponent will be greatly beneficial in the control of COVID-19 in the presence of superspreading phenomen


Friction ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 1-28
Author(s):  
Lei Chen ◽  
Linmao Qian

Abstract Surficial water adsorption and interfacial water condensation as natural phenomena that can alter the contact status of the solid interface and tribological performances are crucial in all length scales, i.e., from earthquakes to skating at the macroscale level and even to micro/nano-electromechanical systems (M/NEMS) at the microscale/nanoscale level. Interfacial water exhibits diverse structure and properties from bulk water because of its further interaction with solid surfaces. In this paper, the evolutions of the molecular configuration of the adsorbed water layer depending on solid surface chemistry (wettability) and structure, environmental conditions (i.e., relative humidity and temperature), and experimental parameters (i.e., sliding speed and normal load) and their impacts on tribological performances, such as adhesion, friction, and wear, are systematically reviewed. Based on these factors, interfacial water can increase or reduce adhesion and friction as well as facilitate or suppress the tribochemical wear depending on the water condensation kinetics at the interface as well as the thickness and structure of the involved interfacial water.


Author(s):  
Jin Young Kim ◽  
R. E. Hummel ◽  
R. T. DeHoff

Gold thin film metallizations in microelectronic circuits have a distinct advantage over those consisting of aluminum because they are less susceptible to electromigration. When electromigration is no longer the principal failure mechanism, other failure mechanisms caused by d.c. stressing might become important. In gold thin-film metallizations, grain boundary grooving is the principal failure mechanism.Previous studies have shown that grain boundary grooving in gold films can be prevented by an indium underlay between the substrate and gold. The beneficial effect of the In/Au composite film is mainly due to roughening of the surface of the gold films, redistribution of indium on the gold films and formation of In2O3 on the free surface and along the grain boundaries of the gold films during air annealing.


Author(s):  
Robert C. Cieslinski ◽  
H. Craig Silvis ◽  
Daniel J. Murray

An understanding of the mechanical behavior polymers in the ductile-brittle transition region will result in materials with improved properties. A technique has been developed that allows the realtime observation of dynamic plane stress failure mechanisms in the transmission electron microscope. With the addition of a cryo-tensile stage, this technique has been extented to -173°C, allowing the observation of deformation during the ductile-brittle transition.The technique makes use of an annealed copper cartridge in which a thin section of bulk polymer specimen is bonded and plastically deformed in tension in the TEM using a screw-driven tensile stage. In contrast to previous deformation studies on solvent-cast films, this technique can examine the frozen-in morphology of a molded part.The deformation behavior of polypropylene and polypropylene impact modified with EPDM (ethylene-propylene diene modified) and PE (polyethylene) rubbers were investigated as function of temperature and the molecular weight of the impact modifier.


2013 ◽  
Vol 44 (5) ◽  
pp. 311-319 ◽  
Author(s):  
Marco Brambilla ◽  
David A. Butz

Two studies examined the impact of macrolevel symbolic threat on intergroup attitudes. In Study 1 (N = 71), participants exposed to a macrosymbolic threat (vs. nonsymbolic threat and neutral topic) reported less support toward social policies concerning gay men, an outgroup whose stereotypes implies a threat to values, but not toward welfare recipients, a social group whose stereotypes do not imply a threat to values. Study 2 (N = 78) showed that, whereas macrolevel symbolic threat led to less favorable attitudes toward gay men, macroeconomic threat led to less favorable attitudes toward Asians, an outgroup whose stereotypes imply an economic threat. These findings are discussed in terms of their implications for understanding the role of a general climate of threat in shaping intergroup attitudes.


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