Theoretical confirmation of Ga-stabilized anti-ferromagnetism in plutonium metal
Keyword(s):
The Face
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ABSTRACTThe density-functional-theory model for plutonium metal is shown to be consistent with recent magnetic measurements that suggest anti-ferromagnetism in Pu-Ga alloys at low temperatures. The theoretical model predicts a stabilization of the face-centered-cubic (fcc, δ) form of plutonium in an anti-ferromagnetic configuration when alloyed with gallium. The ordered magnetic phase occurs because Ga removes the mechanical instability that exists for unalloyed δ-Pu. The cause of the Ga-induced stabilization is a combination of a lowering of the band (kinetic) and electrostatic (Coulomb) energies for the cubic relative to the tetragonal phase.
2016 ◽
Vol 113
(40)
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pp. 11143-11147
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2019 ◽
Vol 25
(61)
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pp. 13977-13986
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Keyword(s):
2021 ◽
2014 ◽
Vol 1082
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pp. 475-479