Electric Field Assisted DNA Surface Reactions on the Sub-ms Timescale

2008 ◽  
Vol 1092 ◽  
Author(s):  
Ricardo Cabeca ◽  
D. M.F. Prazeres ◽  
V. Chu ◽  
J. P. Conde
Keyword(s):  
Electric Field ◽  
Short Duration ◽  
Applied Electric Field ◽  
Surface Reactions ◽  
Single Stranded Dna ◽  
Sio2 Surface ◽  
Voltage Pulses ◽  
On Chip ◽  
Low Amplitude ◽  
Kinetics Of

AbstractThe on-chip application of single, sub-ms voltage pulses promotes the immobilization of single stranded DNA (ssDNA) probes from a solution to a chemically functionalized SiO2 surface and as well as the hybridization between ssDNA targets from a solution to covalently immobilized ssDNA probes (E-assisted DNA reactions). Compared to diffusion-based surface reactions (in the absence of the applied electric field), an improvement of several orders of magnitude in the kinetics of the immobilization and hybridization reactions is observed with low amplitude (below 2 V) and short duration (100 ns to 1 ms) voltage pulses. E-assisted DNA reactions are demonstrated using mm-size macroelectrodes and then optimized using μm-size microelectrodes.

scholarly journals Electroadsorptive Removal of Gaseous Pollutants

2019 ◽  
Vol 9 (6) ◽  
pp. 1162 ◽  
Author(s):  
Mattia Pierpaoli ◽  
Gabriele Fava ◽  
Maria Ruello
Keyword(s):  
Activated Carbon ◽  
Electric Field ◽  
Adsorption Capacity ◽  
Adsorption Kinetics ◽  
Applied Electric Field ◽  
Carbon Cloth ◽  
Activated Carbon Cloth ◽  
Enhanced Adsorption ◽  
Electrohydrodynamic Force ◽  
Kinetics Of

Adsorption is a consequence of surface energy distribution, and the existence of electrostatic bonding suggests that the presence of an external electric field may affect adsorbate/adsorbent interactions. Nevertheless, this aspect has been poorly studied in the literature, except under non-thermal plasma or corona discharge conditions. After having demonstrated in our previous work that the adsorption kinetics of gaseous organic compounds can be enhanced by the presence of an external applied electric field, in this study, we focus on the influence of the electric field on adsorbent and adsorptive interactions. By using a commercially available activated carbon cloth, in addition to increasing the adsorbent mass transfer coefficient by virtue of the increasing intensity of the applied electric field, the results suggest that adsorbent morphology is only influenced by the formation of new surface functional groups. Moreover, enhanced adsorption kinetics and capacity may result from the electrohydrodynamic force induced by the movement of charged and neutral particles towards the adsorbent, as confirmed by the reversibility of the process. Such enhancement results in a negligible increase, of about 3%, in adsorption capacity (i.e., from 91 mmol m−2 Pa−1 for only adsorption to 94 mmol m−2 Pa−1 in the presence of the applied electric field), but also in a dramatic doubling of adsorption kinetics (i.e., from 0.09 min−1 for only adsorption to 0.19 min−1 in the presence of the applied electric field). In reality, the application of an electric field to an activated carbon cloth leads to faster adsorption kinetics, without substantially altering its adsorption capacity.

Intelligent Gels

1999 ◽  
Vol 604 ◽  
Author(s):  
Yoshihito Osada ◽  
Jian Ping Gong ◽  
Tetsuharu Narita
Keyword(s):  
Electric Field ◽  
Shape Memory ◽  
Cationic Surfactant ◽  
Applied Electric Field ◽  
Molecular Assembly ◽  
Side Chain ◽  
Alkyl Side Chain ◽  
Thermodynamics And Kinetics ◽  
Kinetics Of ◽  
And Diffusion

AbstractWe reported an electro-driven chemomechanical hydrogel showing quick responses with worm-like motility. The principle of the motion is based on the molecular assembly reaction of cationic surfactant and negatively charged hydrogel. And direction of complexation accompanying gel contraction is controlled by changing the polarity of the applied electric field. Both thermodynamics and kinetics of surfactant binding and diffusion are investigated experimentally and theoretically. We also reported shape memory hydrogel by order-disorder transition of alkyl side chain, and some examples od friction of hydrogels showing that frictional behaviors of hydorgels do not conform to Amonton's law.

LIQUID CRYSTLASLIGHT SCATTERING BY FLUCTUATIONS INDUCED BY AN APPLIED ELECTRIC FIELD IN A NEMATIC LIQUID CRYSTAL (APAPA)

1972 ◽  
Vol 33 (C1) ◽  
pp. C1-63-C1-67 ◽  
Author(s):  
M. BERTOLOTTI ◽  
B. DAINO ◽  
P. Di PORTO ◽  
F. SCUDIERI ◽  
D. SETTE
Keyword(s):  
Liquid Crystal ◽  
Electric Field ◽  
Nematic Liquid Crystal ◽  
Applied Electric Field

Improved technique for measuring mechanical deformations induced by an applied electric field to an organic insulator

2012 ◽  
Vol 15 (2-3) ◽  
pp. 127-139
Author(s):  
Tung Tran Anh ◽  
Laurent Berquez ◽  
Laurent Boudou ◽  
Juan Martinez-Vega ◽  
Alain Lacarnoy
Keyword(s):  
Electric Field ◽  
Applied Electric Field ◽  
Mechanical Deformations ◽  
Improved Technique

Solution for a Semi-Permeable Interface Crack in Elastic Dielectric/Piezoelectric Bimaterials

2008 ◽  
Vol 75 (1) ◽  
Author(s):  
Q. Li ◽  
Y. H. Chen
Keyword(s):  
Electric Field ◽  
Mechanical Loading ◽  
Interface Crack ◽  
Applied Electric Field ◽  
Crack Tip ◽  
Crack Model ◽  
Permeable Crack ◽  
Impermeable Crack ◽  
Silicon Oil ◽  
Elastic Dielectric

A semi-permeable interface crack in infinite elastic dielectric/piezoelectric bimaterials under combined electric and mechanical loading is studied by using the Stroh complex variable theory. Attention is focused on the influence induced from the permittivity of the medium inside the crack gap on the near-tip singularity and on the energy release rate (ERR). Thirty five kinds of such bimaterials are considered, which are constructed by five kinds of elastic dielectrics and seven kinds of piezoelectrics, respectively. Numerical results for the interface crack tip singularities are calculated. We demonstrate that, whatever the dielectric phase is much softer or much harder than the piezoelectric phase, the structure of the singular field near the semi-permeable interface crack tip in such bimaterials always consists of the singularity r−1∕2 and a pair of oscillatory singularities r−1∕2±iε. Calculated values of the oscillatory index ε for the 35 kinds of bimaterials are presented in tables, which are always within the range between 0.046 and 0.088. Energy analyses for five kinds of such bimaterials constructed by PZT-4 and the five kinds of elastic dielectrics are studied in more detail under four different cases: (i) the crack is electrically conducting, (ii) the crack gap is filled with air/vacuum, (iii) the crack gap is filled with silicon oil, and (iv) the crack is electrically impermeable. Detailed comparisons on the variable tendencies of the crack tip ERR against the applied electric field are given under some practical electromechanical loading levels. We conclude that the different values of the permittivity have no influence on the crack tip singularity but have significant influences on the crack tip ERR. We also conclude that the previous investigations under the impermeable crack model are incorrect since the results of the ERR for the impermeable crack show significant discrepancies from those for the semi-permeable crack, whereas the previous investigations under the conducting crack model may be accepted in a tolerant way since the results of the ERR show very small discrepancies from those for the semi-permeable crack, especially when the crack gap is filled with silicon oil. In all cases under consideration the curves of the ERR for silicon oil are more likely tending to those for the conducting crack rather than to those for air or vacuum. Finally, we conclude that the variable tendencies of the ERR against the applied electric field have an interesting load-dependent feature when the applied mechanical loading increases. This feature is due to the nonlinear relation between the normal electric displacement component and the applied electromechanical loadings from a quadratic equation.

Sign in / Sign up

Export Citation Format

Share Document