Organic, Organometallic and Polymeric Materials with Nonlinear Optical Properties

1989 ◽  
Vol 175 ◽  
Author(s):  
S. R. Marder ◽  
J. W. Perry ◽  
W. P. Schaefer ◽  
E. J. Ginsburg ◽  
C. B. Gorman ◽  
...  
Keyword(s):  
Ring Opening ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Polymeric Materials ◽  
Optical Nonlinearities ◽  
Third Order ◽  
Organic Salts ◽  
Molecular Hyperpolarizability ◽  
Scattering Losses ◽  
Derivatives Of

AbstractNew approaches to both second-order and third-order nonlinear optical materials are presented. A series of organometallic and organic salts, in which the cation has been designed to have a large molecular hyperpolarizability, has been prepared and the SHG efficiencies were measured. Partially substituted derivatives of polyacetylene are synthesized via the ring-opening metathesis polymerization (ROMP) of cyclooctatetraene (COT) and its derivatives. Certain poly-COT derivatives afford soluble, highly conjugated polyacetylenes. These materials exhibit large third-order optical nonlinearities and low scattering losses.

Doped Polymers as Third-Order Nonlinear-Optical Materials

1990 ◽  
Vol 214 ◽  
Author(s):  
Mark. G. Kuzyk ◽  
U. C. Paek ◽  
Carl W. Dirk ◽  
Mark P. Andrews
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Polymeric Materials ◽  
Optical Nonlinearity ◽  
Third Order ◽  
Optical Device ◽  
Optical Fiber Devices ◽  
The Status ◽  
Device Applications ◽  
Doped Polymers

ABSTRACTRecently, there has been much interest in doped polymeric materials owing to their suitability for optical device applications.[1] While most of this effort has been centered on poled polymers and their applications to electrooptics, doped polymers are beginning to emerge as a promising material class for all-optical device applications. In this contribution, we discuss the status of doped polymers as third-order optical materials. Particular attention is focused on those properties that make doped polymers attractive as device materials such as optical nonlinearity and loss and their suitability for nonlinear-optical fiber devices.

scholarly journals Electronic properties and third-order optical nonlinearities in tetragonal chalcopyrite AgInS2, AgInS2/ZnS and cubic spinel AgIn5S8, AgIn5S8/ZnS quantum dots

2017 ◽  
Vol 5 (1) ◽  
pp. 149-158 ◽  
Author(s):  
Bartłomiej Cichy ◽  
Dominika Wawrzynczyk ◽  
Marek Samoc ◽  
Wiesław Stręk
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Electronic Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Optical Nonlinearities ◽  
Third Order

Electronic as well as third-order nonlinear optical properties of chalcopyrite AgInS2 and non-stoichiometric spinel AgIn5S8 quantum dots compared with corresponding Zn2+ alloyed compounds are presented in this work.

Theoretical and Experimental Studies of Third-Order Nonlinear Optical Susceptibilities of New p-N,N'-Diamethylaniline Tetrathiafulvalene Derivatives

2000 ◽  
Vol 660 ◽  
Author(s):  
B. Sahraoui ◽  
K.J. Pluciński ◽  
M. Makowaska-Janusik ◽  
I. V. Kityk ◽  
M. Salle ◽  
...  
Keyword(s):  
Quantum Chemical Calculations ◽  
Quantum Chemical ◽  
Nonlinear Optical ◽  
Experimental Studies ◽  
Physical Nature ◽  
Four Wave Mixing ◽  
Wave Mixing ◽  
Electronic Contribution ◽  
Optical Nonlinearities ◽  
Third Order

ABSTRACTA study was made of third-order nonlinear optical susceptibilities of new tetrathiafulvalene (TTF) derivatives, using the degenerate four wave mixing (DFWM) method, as well as complex quantum chemical calculations. To understand the physical nature of the optical nonlinearities, we separated their electronic and nuclear contributions. We found that the electronic contribution to these nonlinearities predominated. Our investigations suggest that TTF may be a highly promising material for nonlinear optics (NLO).

Second- and Third- Order Nonlinear Optical Materials

2006 ◽  
pp. 7-1-7-126
Author(s):  
Larry Dalton ◽  
Philip Sullivan ◽  
Alex Jen
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Nonlinear Optical Materials ◽  
Third Order

Novel third-order nonlinear optical materials composed of ionic polymers and chromophores

1990 ◽  
Author(s):  
Hiromitsu Tomiyama ◽  
Shuji Okada ◽  
Hiro Matsuda ◽  
Hachiro Nakanishi
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Nonlinear Optical Materials ◽  
Ionic Polymers ◽  
Third Order

scholarly journals Application of Near-IR Absorption Porphyrin Dyes Derived from Click Chemistry as Third-Order Nonlinear Optical Materials

ChemistryOpen ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 71-77 ◽  
Author(s):  
Yongsheng Mi ◽  
Pengxia Liang ◽  
Zhou Yang ◽  
Dong Wang ◽  
Hui Cao ◽  
...  
Keyword(s):  
Click Chemistry ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Nonlinear Optical Materials ◽  
Ir Absorption ◽  
Third Order ◽  
Near Ir
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