A Review Process and a Database for Waste-Package Documents

1990 ◽  
Vol 212 ◽  
Author(s):  
Charles G. Interrante ◽  
Carla A. Messina ◽  
Anna C. Fraker
Keyword(s):  
Information Needs ◽  
Review Process ◽  
Nuclear Regulatory Commission ◽  
Waste Package ◽  
Long Term Storage ◽  
High Level Nuclear Waste ◽  
Regulatory Commission ◽  
High Level ◽  
Term Storage

ABSTRACTThe work reported here is part of a program conducted by the Nuclear Regulatory Commission on the efficacy of proposed plans for radionuclide containment for long-term storage of high-level nuclear waste (HLW). An important element of that program is the review and evaluation of available literature on components of a waste package. A review process and a database have been developed and tailored to provide information quickly to an individual who has a question about a particular material or component of a waste package. The database is uniquely suited to serve as a guide to indicate special areas where data and information needs exist on questions related to radionuclide containment. Additions to the database are made as information becomes available, and this source is as current as the published literature. A description of the review process and the database is given.

Comparison of Granite, Tuff, and Basalt as Geologic Media for Long-Term Storage of High-Level Nuclear Waste

1990 ◽  
Vol 212 ◽  
Author(s):  
D. E. Grandstaff ◽  
V. J. Grassi ◽  
A. C. Lee ◽  
G. C. Ulmer
Keyword(s):  
Nuclear Waste ◽  
Nuclear Waste Repository ◽  
Long Term Storage ◽  
Hydrothermal Experiments ◽  
Ion Activity ◽  
Activity Ratios ◽  
High Level Nuclear Waste ◽  
High Level ◽  
Term Storage

ABSTRACTSystematic differences in pH, cation/proton ion activity ratios, and redox have been observed between solutions produced in rock-water hydrothermal experiments with tuff, granite, and basalt. Stable pH values in tuff-water experiments may be as much as 1.5 pH units more acidic than basalt-water experiments at the same temperature and ionic strength. Redox (log fO2) values in 300°C tuff experiments are 4–7 orders of magnitude more oxidizing than basalt experiments and ca. 4 log units more oxidizing than the magnetite-hematite buffer. Such fluid differences could significantly affect the performance of a high-level nuclear waste repository and should be considered in repository design and siting.

Modelling the Kinetics of Hydrogen Evolution on Metals for Nuclear Applications

2006 ◽  
Author(s):  
Kenneth R. Trethewey
Keyword(s):  
Hydrogen Evolution ◽  
Nuclear Materials ◽  
Electrochemical Tests ◽  
Long Term Storage ◽  
High Level Nuclear Waste ◽  
High Level ◽  
Kinetics Of ◽  
Term Storage ◽  
Nuclear Applications

It is well known that some metals suffer damage caused by the evolution of hydrogen in certain conditions in nuclear applications. Of particular current interest is the use of alloys for use in containers for the long-term storage of high level nuclear waste. Calculations for the rates of corrosion of metals where hydrogen evolution is possible rely upon measurements of the reaction kinetics, but it is difficult to obtain reliable and accurate values for the kinetic constants. Standard electrochemical tests can be used, but the analysis of the results is complex because of the need to deconvolute the curves. This paper presents a computer model for the analysis of the data that is checked by its use on experimental data from a number of nuclear materials.

scholarly journals Functions of the Materials Review Board

1984 ◽  
Vol 44 ◽  
Author(s):  
M. J. Steindler ◽  
W. B. Seefeldt
Keyword(s):  
Nuclear Waste ◽  
Environmental Protection Agency ◽  
Nuclear Regulatory Commission ◽  
Department Of Energy ◽  
Waste Package ◽  
Performance Predictions ◽  
High Level Nuclear Waste ◽  
Regulatory Commission ◽  
High Level ◽  
Nuclear Waste Policy

Some nuclear waste is destined for disposal in deep geological formations. The disposal system for wastes from commercial nuclear activities, and perhaps also for high-level wastes from defense-related activities, is to be designed and operated by the Department of Energy (DOE) and licensed by the Nuclear Regulatory Commission (NRC). The Nuclear Waste Policy Act [1] outlines some of the procedures and schedules that are to be followed by DOE in carrying out its assignment in the disposal of high-level nuclear waste (HLW). The regulations of the NRC that deal with HLW [2] are only partly in place, and amendments (e.g., related to the unsaturated zone) are yet to be approved and issued. The Environmental Protection Agency (EPA) has issued only draft versions of the regulations pertaining to HLW disposal [3], but key features of these drafts are at present in adequate agreement with NRC documents. On the basis of the trends that have become evident in the last few years, the DOE will be required to substantiate performance predictions for all pertinent aspects of a repository, especially the performance of the engineered waste package. The basis for demonstrating that the waste package performance in the repository will be in concert with the requirements is data on the waste package materials. These key materials data must clearly be highly reliable, and DOE will be required to assure this reliability. This paper addresses the organization and functions that have been assembled to aid in establishing the quality of materials data that are important in the licensing of a waste repository.

Prediction of Long Term Corrosion Behaviour in Nuclear Waste Systems

2006 ◽  
Vol 932 ◽  
Author(s):  
Damien Féron ◽  
Digby D. Macdonald
Keyword(s):  
Nuclear Waste ◽  
Corrosion Behaviour ◽  
Lessons Learned ◽  
Long Term Storage ◽  
Experimental Approaches ◽  
High Level Nuclear Waste ◽  
High Level ◽  
Interim Storage ◽  
Term Storage

ABSTRACTThe corrosion resistance of container materials in underground repositories is an important issue for the safe disposal of High Level Nuclear Waste (HLNW). The reliable prediction of container degradation rate and engineering barrier integrity over extended periods, up to several thousands years or even several hundreds of thousands of years, represents one of the greatest scientific and technical challenges. The first and the second International Workshops on Prediction of Long Term Corrosion Behaviour in Nuclear Waste Systems, which were held in 2001 (Cadarache) and 2004 (Nice), sought to compare the scientific and experimental approaches that are being developed in various organisations worldwide for predicting long term corrosion phenomena, including corrosion strategies for interim storage and geological disposal. The lessons learned during these Workshops, include the necessity of developing two approaches based on semi-empiricism and determinism in a complementary manner for effective prediction. The use of archaeological artefacts to demonstrate the feasibility of long term storage and to provide a database for testing and validating modelling work was also emphasized.

scholarly journals Long-Term Storage and Use of Artificially Immobilized Anaerobic Sludge as a Powerful Biocatalyst for Conversion of Various Wastes Including Those Containing Xenobiotics to Biogas

Catalysts ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 326 ◽  
Author(s):  
Olga Senko ◽  
Marina Gladchenko ◽  
Olga Maslova ◽  
Elena Efremenko
Keyword(s):  
Clostridium Acetobutylicum ◽  
Immobilized Cells ◽  
Poly Vinyl Alcohol ◽  
Anaerobic Sludge ◽  
Lignocellulosic Waste ◽  
Long Term Storage ◽  
Anaerobic Consortium ◽  
High Level ◽  
Term Storage

The aim of this paper is to demonstrate the possibilities of anaerobic sludge cells immobilized into poly(vinyl alcohol) cryogel for the methanogenic conversion of various lignocellulosic waste and other media containing antibiotics (ampicillin, kanamycin, benzylpenicillin) or pesticides (chlorpyrifos or methiocarb and its derivatives). It was established that the immobilized cells of the anaerobic consortium can be stored frozen for at least three years while preserving a high level of metabolic activity. The cells after the long-term storage in an immobilized and frozen state were applied for the methanogenesis of a wide number of wastes, and an increase in both methane yield and methane portion in the produced biogas as compared to the conventionally used suspended anaerobic sludge cells, was ensured. It was shown that the “additional” introduction of bacterial Clostridium acetobutylicum, Pseudomonas sp., Enterococcus faecalis cells (also immobilized using same support) improves characteristics of methanogenesis catalyzed by immobilized anaerobic sludge.

Corrosion Model Validation in High Level Nuclear Waste Package Research

1992 ◽  
Vol 294 ◽  
Author(s):  
M. B. Mcneil ◽  
J.B. Moody
Keyword(s):  
Site Specific ◽  
Waste Package ◽  
Naturally Occurring ◽  
Widespread Acceptance ◽  
Natural Analogues ◽  
High Level Nuclear Waste ◽  
Mineral Alteration ◽  
High Level ◽  
Performance Validation

ABSTRACTThe strategies for waste package (WP) performance validation will be based on site specific geologic and hydrogeochemical information plus models which can be used to predict potential WP lifetimes. The development and application of such models will include the evaluation of natural analogues (NA). These analogues are needed to resolve issues related to the validation of models. Natural analogues have not had extensive use or widespread acceptance in the area of waste package failure prediction. This lack of acceptance is due to the anticipated choice of alloys for waste package containers. Few of these alloys are similar to naturally occurring metals, and the proposed HLW repositories are in general in geologic settings not very similar to those in which naturally occurring metals are generally found.Natural and archaeological analogues can be used, however, in analysis of possible waste package failures as a means of testing proposed models for failure. In fact, the analogues are the only available mechanisms for testing models of long-term waste package behavior. A strategy is outlined for incorporating natural and archaeological analogue studies into waste package research, and examples are discussed. The natural/archaeological analogues approach which appears most promising is to use archaeological and mineral samples to develop an understanding of the identities and rates of the mineral alteration reactions at or near the surface of the package, improving present capability for estmating the lifetimes of metallic waste package containers.

scholarly journals Microscopic and spectroscopic bioassociation study of uranium(VI) with an archaeal Halobacterium isolate

PLoS ONE ◽  
2022 ◽  
Vol 17 (1) ◽  
pp. e0262275
Author(s):  
Stephan Hilpmann ◽  
Miriam Bader ◽  
Robin Steudtner ◽  
Katharina Müller ◽  
Thorsten Stumpf ◽  
...  
Keyword(s):  
Radioactive Waste ◽  
Rock Salt ◽  
Luminescence Spectroscopy ◽  
Spectroscopic Techniques ◽  
High Level Radioactive Waste ◽  
Long Term Storage ◽  
High Level ◽  
The Impact ◽  
Term Storage

The safe disposal of high-level radioactive waste in a deep geological repository is a huge social and technical challenge. So far, one of the less considered factors needed for a long-term risk assessment, is the impact of microorganisms occurring in the different host rocks. Even under the harsh conditions of salt formations different bacterial and archaeal species were found, e. g. Halobacterium sp. GP5 1–1, which has been isolated from a German rock salt sample. The interactions of this archaeon with uranium(VI), one of the radionuclides of major concern for the long-term storage of high-level radioactive waste, were investigated. Different spectroscopic techniques, as well as microscopy, were used to examine the occurring mechanisms on a molecular level leading to a more profound process understanding. Batch experiments with different uranium(VI) concentrations showed that the interaction is not only a simple, but a more complex combination of different processes. With the help of in situ attenuated total reflection Fourier-transform infrared spectroscopy the association of uranium(VI) onto carboxylate groups was verified. In addition, time-resolved laser-induced luminescence spectroscopy revealed the formation of phosphate and carboxylate species within the cell pellets as a function of the uranium(VI) concentration and incubation time. The association behavior differs from another very closely related halophilic archaeon, especially with regard to uranium(VI) concentrations. This clearly demonstrates the importance of studying the interactions of different, at first sight very similar, microorganisms with uranium(VI). This work provides new insights into the microbe-uranium(VI) interactions at highly saline conditions relevant to the long-term storage of radioactive waste in rock salt.

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