Numerical Modeling Study on Mineral Alteration and Sealing Performance for CO2 Geological Sequestration with Enhancing Water Recovery in Hydraulic Fractured Shale Reservoirs

Recently, CO2 geological sequestration combined with enhancing deep saline water/brine recovery is regarded as a potential strategic choice for reduction of CO2 emissions. This technology not only achieves the relatively secure storage of CO2 which was captured during industrial processes but also can enhance the recovery of water for drinking, industrial, and agricultural utilization. However, the impact of CO2-water-rock reactions on the shale reservoir in the system is unclear and the sealing performance of mudstone caprock has not been investigated. For analyzing the mechanism of mineral alteration in the shale reservoir, a three-dimensional injection-production model in the double-fractured horizontal well pattern is established according to actual parameters of shale and mudstone layers. In addition, mineral alteration was characterized and caprock sealing performance was also assessed. Numerical results showed that the presence of CO2 can lead to the dissolution of k-feldspar, oligoclase, chlorite, and dolomite and the precipitation of clay minerals such as kaolinite, illite, and smectite (Ca-smectite and Na-smectite). Due to positive ion released by dissolved primary minerals, the precipitation of secondary carbonate occurs including ankerite and dawsonite, which induces the mineral sequestration capacity of the shale reservoir. The amount of CO2 sequestration by mineral is 51430.96 t after 200 years, which equals 23.47% of the total injection (219145.34 t). Besides, the height of the sealing gas column is used for evaluating the sealing performance of the shale-mudstone interface. Results show that the height of the sealing gas column at the interface above the injection well is lower but the maximum value of CO2 gas saturation is only 0.00037 after 200 years. The height of the sealing gas column at the interface is greater than 800 m, which can be classified as level II and guarantee the security of the CO2 storage. The analysis results provide reliable guidance and reference for the site selection of CO2 geological sequestration.

Processes controlling volcanic and epiclastic reservoir formation in a buried polygenetic stratocone

Understanding the formation of volcanic and epiclastic reservoirs is pivotal for exploring geoenergy resources such as geothermal energy, hydrocarbons, and new CO2 sequestration and hydrogen storage opportunities. This paper examines the processes controlling the quality of pyroclastic and epiclastic reservoirs of the Kora volcano, an extinct stratocone presently buried in the offshore Taranaki Basin, New Zealand. We conduct detailed seismic reflection interpretation, drillcore lithofacies and wireline-log description, petrographic analysis, and analytical tests to generate a unified framework that explains the formation of volcaniclastic reservoirs from basin to pore-scale.Each stage of construction and degradation of the Kora volcano is associated with particular processes that increase or reduce reservoir quality. Primary processes include quench fragmentation, deuteric mineral dissolution, and epiclastic sedimentation. Secondary processes comprise mineral alteration (mainly meteoric; minor hydrothermal and diagenetic), mechanical stress fracturing (mainly tectonic; minor magmatic and burial deformation), and pervasive biogenic cementation. Epiclastic conglomerates present the highest reservoir quality (average 23% porosity and up to 997 mD permeability), followed by lapilli-tuffs and tuff-breccias. In contrast, bioclastic epiclastic sandstones are typically cemented by carbonates and pyrite. Our models and interpretations will increase understanding of the formation of volcaniclastic reservoirs and aid exploration of geoenergy resources in volcanic terrains.

A Streamlined Workflow From Experimental Analyses to Dynamic Geochemical Modelling

Dynamic-geochemical model is a powerful instrument to evaluate the geochemical effects on CO2storage capacity, injectivity and long-term containment. The study objective is to apply an integrated multi-step workflow to a carbon capture and storage (CCS) candidate field (offshore), namely hereinafter H field. From experimental analyses, a comprehensive real data-tailored reactive transport model (RTM) has been built to capture the dynamics and the geochemical phenomena (e.g., water vaporization, CO2solubility, mineral alteration) occurring during and after the CO2injection in sedimentary formations. The proposed integrated workflow couples lab activities and numerical simulations and it is developed according to the following steps: Mineralogical-chemical characterization (XRD, XRF and SEM-EDX experimental techniques) of field core samples; Data elaboration and integration to define the conceptual geochemical model; Synthetic brine reconstruction by means of 0D geochemical models; Numerical geochemical modelling at different complexity levels. Field rocks chosen for CO2injection have been experimentally characterized, showing a high content of Fe in clayey, micaceous and carbonate mineralogical phases. New-defined, site-specific minerals have been characterized, starting from real XRD, XRF and SEM-EDX data and by calculation of their thermochemical parameters with a proprietary procedure. They are used to reconstruct synthetic formation water chemical composition (at equilibrium with both rock mineralogy and gas phase), subsequently used in RTM. CO2injection is simulated using 2D radial reactive transport model(s) built in a commercial compositional reservoir simulator. The simulations follow a step-increase in the complexity of the model by adding CO2solubility, water vaporization and geochemical reactions. Geochemical processes impact on CO2storage capacity and injectivity is quantitatively analyzed. The results show that neglecting the CO2solubility in formation water may underestimate the max CO2storage capacity in H field by around 1%, maintaining the same pressure build-up profile. Sensitivities on the impact of formation water salinity on the CO2solubility are presented. In a one thousand years’ time-scale, changes in reservoir porosity due to mineral alteration, triggered by CO2-brine-rock interactions, seem to be minimal in the near wellbore and far field. However, it has been seen that water vaporization with the associated halite precipitation inclusion in the simulation models is recommended, especially at high-level of formation brine salinity, for a reliable evaluation of CO2injectivity related risks. The proposed workflow provides a new perspective in geochemical application for CCS studies, which relies on novel labs techniques (analyses automation), data digitalization, unification and integration with a direct connection to the numerical models. The presented procedure can be followed to assess the geochemical short-and long-term risks in carbon storage projects.

Mixed-Layer Illite-Smectite in Pennsylvanian-Aged Paleosols: Assessing Sources of Illitization in the Illinois Basin

Mixed-layer illite-smectite (I-S) from a new set of Pennsylvanian-aged Illinois Basin underclays, identified as paleosols, are investigated to assess the impact of (1) regional diagenesis across the basin and (2) the extent to which ancient environments promoted illitization during episodes of soil formation. Interpretations from Reichweite Ordering and Δ° 2θ metrics applied to X-ray diffraction patterns suggest that most I-S in Illinois Basin paleosols are likely the product of burial diagenetic processes and not ancient soil formation processes. Acid leaching from abundant coal units and hydrothermal brines are likely diagenetic mechanisms that may have impacted I-S in Pennsylvanian paleosols. These findings also suggest that shallowly buried basins (<3 km) such as the Illinois Basin may still promote clay mineral alteration through illitization pathways if maximum burial occurred in the deep past and remained within the diagenetic window for extended periods of time. More importantly, since many pedogenic clay minerals may have been geochemically reset during illitization, sources of diagenetic alteration in the Illinois Basin should be better understood if Pennsylvanian paleosol minerals are to be utilized for paleoclimate reconstructions.

Textural Implications in Assessment of Physico-Mechanical behaviour of Metavolcanic Rocks from Dir Upper, north western Pakistan

The Dir-Utror meta-volcanics from the south western portion of the Kohistan arc in northern Pakistan areanalyzed in term of their petrography, physico-mechanical properties. Field observations and petrography show thecollected representative samples to be fine-grained meta-andesites (FMA), coarse-grained meta-andesites (CMA) andagglomerate (AG). The relationship between petrography and physico-mechanical properties has been investigatedwhich inferred the grain size to be the major factor, alongside grains’ shape, arrangement and size distribution as wellas degree of mineral alteration significantly affecting the mechanical behavior of rocks. The CMA yield more strength(98 MPa) than FMA (93 MPa) due to its lesser degree of mineral alteration, inequigranular texture, lack of preferredmineral alignment, relatively low porosity and water absorption. The lower strength of agglomerate (57 MPa)corresponds to abundance of soft minerals (calcite), exotic rock fragments and coarse-grained texture. Based onphysico-mechanical properties including specific gravity, bulk density, aggregate impact value, Los Angeles abrasionvalue and unconfined compressive strength (UCS), these rocks fall within permissible range to be utilized for multipleengineering purposes including dimension stones and foundation materials for other civil structures. However,petrographic investigations reveal excessive amount of reactive silica in these rocks making them prone to alkali-silicareactivity in concrete works with ordinary Portland cement (OPC). Hence these rocks are not recommended for use assole aggregate material or low-alkali cement is recommended, if used.

A Review of Asbestos Bioweathering by Siderophore-Producing Pseudomonas: A Potential Strategy of Bioremediation

Asbestos, silicate minerals present in soil and used for building constructions for many years, are highly toxic due primarily to the presence of high concentrations of the transition metal iron. Microbial weathering of asbestos occurs through various alteration mechanisms. Siderophores, complex agents specialized in metal chelation, are common mechanisms described in mineral alteration. Solubilized metals from the fiber can serve as micronutrients for telluric microorganisms. The review focuses on the bioweathering of asbestos fibers, found in soil or manufactured by humans with gypsum (asbestos flocking) or cement, by siderophore-producing Pseudomonas. A better understanding of the interactions between asbestos and bacteria will give a perspective of a detoxification process inhibiting asbestos toxicity.

Cation-Exchange Capacity Distribution within Hydrothermal Systems and Its Relation to the Alteration Mineralogy and Electrical Resistivity

Cation-exchange capacity (CEC) measurements are widely used to quantify the smectite content in altered rocks. Within this study, we measure the CEC of drill cuttings in four wells from three different high-temperature geothermal areas in Iceland. The CEC measurements in all four wells show similar depth/temperature related pattern, and when comparing the CEC with electrical resistivity logs, we could show that the low resistivity zone coincides with CEC values >5 meq/100 g. The measurements show, in general, an exponential decrease of the CEC with increasing depth. At the facies boundary between the mixed-layer clay and epidote-chlorite zone, the CEC reaches a steady state at about 5 meq/100 g and below that it only decreases slightly within a linear trend with increasing depth. The facies boundary overlaps with the transition where the electrical resistivity logs show an increase in resistivity. It is shown that the measured CEC can be related to the clay mineral alteration within the geothermal system and the CEC reflects the smectite component within the interstratified chlorite/smectite minerals for similar alteration degree. Furthermore, CEC was measured in seven core samples from different alteration zones that had previously been studied in detail with respect to petrophysical and conductivity properties. The results show a clear correlation between CEC and the iso-electrical point, which describes the value of the pore fluid conductivity where transition from surface conductivity to pore fluid conductivity occurs. The presented study shows that the CEC within hydrothermal altered basaltic systems mimics the expandable clay mineral alteration zones and coincides with electrical logs. The presented method can, therefore, be an easy tool to quantify alteration facies within geothermal exploration and drilling projects.

Application of PRISMA satellite hyperspectral imagery to mineral alteration mapping at Cuprite, Nevada, USA

The PRISMA hyperspectral imaging satellite of the Italian Space Agency was launched into orbit on March 22, 2019. The PRISMA is a pushbroom sensor that records 250 hyperspectral bands in the 0.4-2.5 μm wavelength region at a spatial resolution of 30 m. The swath of the hyperspectral imagery is 30 km. This study evaluates the application of the PRISMA hyperspectral imagery to mineral exploration. The study area is the Cuprite in Nevada, USA. Cuprite has served as test-site for a number of airborne and spaceborne remote sensing imaging systems. The Cuprite PRISMA hyperspectral data were analyzed with the Advanced Coherence Estimator algorithm. The analysis of the hyperspectral imagery accurately mapped the spatial distribution of alunite, kaolinite, hydrated silica, muscovite and buddingtonite. The study shows that the PRISMA hyperspectral imagery is a useful tool for mineral exploration projects in arid and semi-arid environments.