Pulsed Laser Deposition of SrBi2Ta2O9 Thin Films for Nonvolatile Memory Applications

1995 ◽  
Vol 397 ◽  
Author(s):  
S. Werner ◽  
D. Thomas ◽  
S.K. Streiffer ◽  
O. Auciello ◽  
Angus I. Kingon

ABSTRACTFerroelectric SrBi2Ta2U9 (SBT) thin films were synthesized by pulsed laser deposition (PLD) on platinized silicon substrates held at different substrate temperatures, from targets with different compositions. It was necessary to anneal films deposited at low temperature (525°C) at elevated temperatures in an oxygen atmosphere in order to achieve properties comparable to SBT thin films grown by the sol-gel technique. Polarization – electric field hysteresis loops showed saturation in the 2-5 V range with a remnant polarization 2Pr = 8-13 µC/cm2. Capacitors showed negligible fatigue up to 1010 switching cycles.

2000 ◽  
Vol 375 (1-2) ◽  
pp. 200-204 ◽  
Author(s):  
Xinhua Zhu ◽  
Yiming Liu ◽  
Zhenghua An ◽  
Tao Zhu ◽  
Zhuangchun Wu ◽  
...  

1998 ◽  
Vol 72 (10) ◽  
pp. 1179-1181 ◽  
Author(s):  
S. C. Purandare ◽  
V. R. Palkar ◽  
J. John ◽  
M. S. Multani ◽  
R. Pinto

1999 ◽  
Vol 596 ◽  
Author(s):  
Minoru Noda ◽  
Toshiyuki Nakaiso ◽  
Hideki Sugiyama ◽  
Masanori Okuyama

AbstractPreferentially (151)-oriented Sr2(Ta1-x, Nbx)2O7 (STN) thin films on Pt have been prepared at temperatures as low as 550 and 600°C, in O2 and N2O atmospheres, respectively, by pulsed laser deposition (PLD). The temperatures are significantly lower than those prepared by sol-gel methods, where 950°C was reported. These are the lowest growth temperatures of crystalline STN thin films. Composition ratio (x) in the target material was determined to be around 0.3 from measurement of the Curie temperature and ferroelectric properties. Active oxygen generated by laser irradiation in ambient O2 or N2O atmosphere is found to be very effective for chemical reaction, and decreases the growth temperature of crystalline STN films. It is also confirmed by surface AFM and cross-sectional SEM observations that the film has a columnar-shaped structure with grain size ranging from 50 to 100 nm. Remanent polarization (Pr) and coercive field (Ec) are 0.4μ C/cm2 and 30 kV/cm, respectively. Finally, we expect the low temperature STN film prepared by PLD to be a promising ferroelectric for the application in ferroelectric memory FETs.


2003 ◽  
Vol 42 (Part 1, No. 9B) ◽  
pp. 5936-5940 ◽  
Author(s):  
Zhan Jie Wang ◽  
Li Jun Yan ◽  
Yuki Aoki ◽  
Hiroyuki Kokawa ◽  
Ryutaro Maeda

Author(s):  
A. A. El-Aziem ◽  
Y. Badr ◽  
K. M. El-Khatib ◽  
M. A. Hafez

2007 ◽  
Vol 1034 ◽  
Author(s):  
Seiji Nakashima ◽  
Yoshitaka Nakamura ◽  
Masanori Okuyama

AbstractBi-layer-structured mutiferroic Bi5Ti3FeO15 (BTFO15) (m = 4) and natural-superlattice-structured Bi4Ti3O12- Bi5Ti3FeO15 (BIT-BTFO15) (m = 3-4) thin films have been prepared on (001) and (110) oriented SrTiO3 (STO) single crystal substrates by using pulsed laser deposition. X-ray diffraction patterns of these thin films on (00l) STO single crystals shows the obtained thin films were (00l)-oriented layer-perovskite single phase, and BIT-BTFO15 (m = 3-4) natural-superlattice-structure has also obtained. On (110) STO single crystal, layer perovskite (11l) oriented thin films have been also obtained. For characterizing ferroelectric properties, these thin films have been prepared on (001) and (110) oriented La-doped (3.73 wt%) STO single crystal substrates. From ferroelectric D-E hysteresis loops measurements, BTFO15 (m = 4) and BIT-BTFO (m = 3-4) thin films on (110) La-doped STO single crystals shows good ferroelectric hysteresis loops and their double remanent polarizations (2Pr) were 47 μC/cm2 and 44 μC/cm2, respectively. However, these thin films on (001) La-doped STO single crystals do not show ferroelectric characteristics.


2020 ◽  
Vol 384 (11) ◽  
pp. 126232
Author(s):  
Peng Shi ◽  
Yan Yang ◽  
Huisen Li ◽  
Zhiqiu Zou ◽  
Benpeng Zhu ◽  
...  

1997 ◽  
Vol 505 ◽  
Author(s):  
W. F. Brock ◽  
J. E. Krzanowski ◽  
R. E. Leuchtner ◽  
L. J. Legore ◽  
D. J. Frankel

ABSTRACTA study has been conducted on ZrC/VC alloy thin films prepared by both pulsed laser deposition (PLD) and RF magnetron sputtering. The phase formation, wear properties, and hardness of these thin films were examined. An alloy target comprised of 36% VC and 64% ZrC (atomic %) was used to deposit films at 200°, 2000°, and 400° C. The nominal film thickness was 0.6 μm. X-ray diffraction (XRD) analysis revealed these films were solid-solution alloys and showed a preference for (100) orientation for sputter-deposited films and a (110) orientation for laser deposition. More highly oriented films were obtained at elevated temperatures as evidenced by rocking curve measurements on the PLD films. The FWHM of the peaks ranged from 2.2° to 8.3° for films deposited at 400° C and 20° C, respectively.Using time-of-flight quadmpole mass spectrometry (TOFQMS), we performed plume diagnostics to measure particle energies and the thermalization effects of the background gas. In vacuum, typical ion energies ranged from ˜5–100 eV while the neutral atoms had kinetic energies from ˜1–5 eV. Our measurements show that the background gas can be used to selectively thermalize low mass components in the plume. From measured kinetic energies and collision effects of the gas, the changes in crystallographic structure of the alloy with pressure appear to result from collision-induced effects from condensation of the Zr atoms. This ‘heavy’ atom effect may be an important new processing parameter with which to adjust film morphology and crystal texture.


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