Accounting For Corrosion Of Hlw Glasses By Humid Air In TSPA

2002 ◽  
Vol 757 ◽  
Author(s):  
W. L. Ebert ◽  
J. C. Cunnane ◽  
N. L. Dietz
Keyword(s):  
Rate Equation ◽  
Ph Dependence ◽  
Yucca Mountain ◽  
Total System ◽  
Humid Air ◽  
Determine Parameter ◽  
Glass Dissolution ◽  
A Value ◽  
License Application ◽  
Parameter Values

ABSTRACTThis paper describes how the results of vapor hydration tests (VHTs) are used to model the corrosion of waste glasses exposed to humid air in the glass degradation model for total system performance assessment (TSPA) calculations for the proposed Yucca Mountain disposal system. Corrosion rates measured in VHTs conducted at 125, 150, 175, and 200°C are compared with the rate equation for aqueous dissolution to determine parameter values that are applicable to glass degradation in humid air. These will be used to determine the minimum for the range and distribution of parameter values in calculations for the Yucca Mountain disposal system license application (TSPA-LA). The rate equation for glass dissolution is rate = kE • 10 η • pH • exp(–Ea/RT). Uncertainties in the calculated rate due to the range of waste glass compositions and water exposure conditions are taken into account by using a range of values for the rate coefficient kE. The parameter values for the pH dependence (η) and temperature dependence (Ea) and the upper limit for kE are being determined with other tests. Using the values of η and Ea from the site recommendation model, the VHT results described in this paper provide a value of log kE = 5.1 as the minimum value for the rate expression. This value will change slightly if different pH-and temperature-dependencies are used for the TSPA-LA model.

Effects of Iron and pH on Glass Dissolution Rate

2002 ◽  
Vol 757 ◽  
Author(s):  
Seung-Young Jeong ◽  
William L. Ebert
Keyword(s):  
Dissolution Rate ◽  
Ph Dependence ◽  
High Level Waste ◽  
Total System ◽  
Degradation Model ◽  
Static Tests ◽  
Dissolved Iron ◽  
Glass Dissolution ◽  
License Application ◽  
High Level

ABSTRACTShort-term static tests were conducted with a surrogate high-level waste glass to measure the effects of pH and dissolved iron on the glass dissolution rate. The tests were conducted to determine if a term to account for the effects of dissolved iron is needed in the glass degradation model developed for Total System Performance Assessment (TSPA) calculations for the Yucca Mountain disposal system license application. The glass degradation model includes terms for dependencies on temperature, pH, and chemical affinity. A series of tests was conducted at 90 °C in various pH solutions without iron and with added FeCl3, Fe2O3, Fe3O4, and FeOOH. Tests were conducted at glass surface area/solution volume (S/V) ratios about 2 and 10 m-1for between 2 and 21 days. Solution concentrations of boron were used to measure the extent of reaction and calculate the glass dissolution rates. Similar rates were measured in tests conducted with and without iron at each pH. Both the results of the tests with and without iron showed V-shaped pH dependence curves with minima at near-neutral pH values. The pH dependencies (η) are about 0.44 in basic solutions and –0.49 in acidic solutions, based on the combined results of tests with and without iron. These are within the range of values for the pH dependence in the TSPA model for site recommendation.

Proceeding Toward a License Application for U.S. Nuclear Waste Repository: Total System Performance Assessment Approach

2003 ◽  
Author(s):  
Jerry McNeish ◽  
Peter Swift ◽  
Rob Howard ◽  
David Sevougian ◽  
Donald Kalinich ◽  
...  
Keyword(s):  
Performance Assessment ◽  
System Performance ◽  
Nuclear Regulatory Commission ◽  
The United States ◽  
Yucca Mountain ◽  
Nuclear Waste Repository ◽  
Total System ◽  
License Application ◽  
Regulatory Commission ◽  
The U.S

The development of a deep geologic repository system in the United States has progressed to the preparation of an application for a license from the U.S. Nuclear Regulatory Commission. The project received site recommendation approval from the U.S. President in early 2002. The next phase of the project involves development of the license application (LA) utilizing the vast body of information accumulated in study of the site at Yucca Mountain, Nevada. Development of the license application involves analyses of the total system performance assessment (TSPA) of the repository, the TSPA-LA. The TSPA includes the available relevant information and model analyses from the various components of the system (e.g., unsaturated geologic zone, engineered system (waste packaging and drift design), and saturated geologic zone) (see Fig. 1 for nominal condition components), and unites that information into a single computer model used for evaluating the potential future performance or degradation of the repository system. The primary regulatory guidance for the repository system is found in 10 CFR 63, which indicates the acceptable risk to future populations from the repository system. The performance analysis must be traceable and transparent, with a defensible basis. The TSPA-LA is being developed utilizing state-of-the-art modeling software and visualization techniques, building on a decade of experience with such analyses. The documentation of the model and the analyses will be developed with transparency and traceability concepts to provide an integrated package for reviewers. The analysis relies on 1000’s of pages of supporting information, and multiple software and process model analyses. The computational environment represents the significant advances in the last 10 years in computer workstations. The overall approach will provide a thorough, transparent compliance analysis for consideration by the U.S. Nuclear Regulatory Commission in evaluating the Yucca Mountain repository.

Lessons Learned from the Yucca Mountain and WIPP Projects

2010 ◽  
Vol 73 ◽  
pp. 194-202 ◽  
Author(s):  
Evaristo J. Bonano ◽  
David S. Kessel ◽  
Lori J. Dotson
Keyword(s):  
System Analysis ◽  
The United States ◽  
Yucca Mountain ◽  
Lessons Learned ◽  
Total System ◽  
Waste Isolation Pilot Plant ◽  
License Application ◽  
Long Term Performance ◽  
Term Performance

For more than 30 years Sandia National Laboratories (SNL) has played a key role in the development and implementation of total system analyses of waste management systems in the United States. Two very important applications have been the total system analysis of long term performance that supported (1) the Compliance Certification Application (CCA) for the Waste Isolation Pilot Plant (WIPP) in 1996 and (2) the License Application (LA) for the Yucca Mountain (YM) Repository in 2008.

Multi-Scale Near-Field Thermohydrologic Analysis of Alternative Designs for the Potential Repository at Yucca Mountain

1999 ◽  
Vol 556 ◽  
Author(s):  
T. A. Buscheck ◽  
J. Gansemer ◽  
J. J. Nitao ◽  
T. H. Delorenzo
Keyword(s):  
Near Field ◽  
High Heat ◽  
Yucca Mountain ◽  
Point Load ◽  
Scale Model ◽  
Heat Output ◽  
Total System ◽  
Line Load ◽  
Multi Scale ◽  
License Application

AbstractA multi-scale, thermohydrologic (TH) modeling methodology has been developed that integrates the results from 1-, 2-, and 3-D drift-scale models and a 3-D mountain-scale model to calculate the near-field TH variables affecting the performance of the engineered barrier system (EBS) of the potential repository at Yucca Mountain. This information was used by Total System Performance Assessment—Viability Assessment (TSPA-VA) and is being used by the ongoing TSPA, supporting the License Application Design Selection, to assess waste-package (WP) corrosion, waste-form dissolution, and radionuclide transport in the EBS. Line-load WP spacing, which places WPs nearly end to end in widely spaced drifts, results in more locally intensive and uniform heating along drifts, causing hotter, drier, and more uniform conditions on WPs than point-load spacing, which is used in the VA design. Backfilling drifts with a granular material with coarse, well-sorted, nonporous grains (e.g., a coarse quartz sand) results in a large, persistent reduction in RH on WPs; point-load spacing allows only the medium-to-high-heat-output WPs to benefit from RH reduction, but line-load spacing enables all WPs to benefit.

scholarly journals The fate of Si and Fe while nuclear glass alters with steel and clay

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
C. Carriere ◽  
P. Dillmann ◽  
S. Gin ◽  
D. Neff ◽  
L. Gentaz ◽  
...  
Keyword(s):  
Dissolution Rate ◽  
Protective Layer ◽  
Glass Dissolution ◽  
A Value ◽  
Waste Forms ◽  
Controlling Mechanism ◽  
Geological Repository ◽  
The Mean ◽  
High Level ◽  
Initial Dissolution Rate

AbstractThe French concept developed to dispose high-level radioactive waste in geological repository relies on glassy waste forms, isolated from the claystone host rock by steel containers. Understanding interactions between glass and surrounding materials is key for assessing the performance of a such system. Here, isotopically tagged SON68 glass, steel and claystone were studied through an integrated mockup conducted at 50 °C for 2.5 years. Post-mortem analyses were performed from nanometric to millimetric scales using TEM, STXM, ToF-SIMS and SEM techniques. The glass alteration layer consisted of a crystallized Fe-rich smectite mineral, close to nontronite, supporting a dissolution/reprecipitation controlling mechanism for glass alteration. The mean glass dissolution rate ranged between 1.6 × 10−2 g m−2 d−1 to 3.0 × 10−2 g m−2 d−1, a value only 3–5 times lower than the initial dissolution rate. Thermodynamic calculations highlighted a competition between nontronite and protective gel, explaining why in the present conditions the formation of a protective layer is prevented.

pH Effects in trypsin catalysis

1969 ◽  
Vol 47 (21) ◽  
pp. 4021-4029 ◽  
Author(s):  
H. P. Kasserra ◽  
K. J. Laidler
Keyword(s):  
Complex Formation ◽  
Ph Dependence ◽  
Specific Rotation ◽  
Ph Effects ◽  
Ph Values ◽  
A Value ◽  
Available Information ◽  
Hydrolysis Of ◽  
Substrate Concentrations ◽  
Covalent Complex

A kinetic study has been made of the trypsin-catalyzed hydrolysis of N-benzoyl-L-alanine methyl ester, at pH values ranging from 6 to 10. The substrate concentrations varied from 1.7 × 10−3 to 4.3 × 10−2 M. From the rates were calculated, at each pH, values of [Formula: see text] (corresponding to [Formula: see text]), [Formula: see text] (corresponding to [Formula: see text]) and [Formula: see text] The specific levorotation of trypsin was measured and found to vary with pH in the pH region 5–11, the change in specific rotation following the ionization of a single group with pK(app) of 9.4. At pH 11 the specific rotation of trypsin, its zymogen, and its phosphorylated derivative were approximately the same, suggesting similar conformations for all three forms of the protein.The kinetic results on the acid side were very similar to those obtained by other investigators for chymotrypsin; they imply that there is a group of [Formula: see text] in the free enzyme, presumably the imidazole function of a histidine residue, and that this group is involved in acylation and deacylation, which can only occur if it is unprotonated. The behavior on the basic side was found to be different from that with chymotrypsin revealing a decrease in [Formula: see text] at high pH corresponding to a value of [Formula: see text] whereas [Formula: see text] showed sigmoid pH-dependence. An interpretation of these results that is consistent with all available information is that a group of [Formula: see text] (presumably the —NH3+ function of the terminal isoleucine) controls the conformation and thereby the activity of the enzyme at different stages of complex formation. In contrast to chymotrypsin, the pK of this ionizing group appears to be generally lowered by covalent complex formation between trypsin and its substrates.

scholarly journals Archie's law – a reappraisal

Solid Earth ◽  
2016 ◽  
Vol 7 (4) ◽  
pp. 1157-1169 ◽  
Author(s):  
Paul W. J. Glover
Keyword(s):  
Systematic Errors ◽  
Apparent Paradox ◽  
Archie’S Law ◽  
A Value ◽  
The Difference ◽  
Reservoir Parameter ◽  
Parameter Values ◽  
Electrical Data ◽  
Extra Parameter ◽  
Better Than

Abstract. When scientists apply Archie's first law they often include an extra parameter a, which was introduced about 10 years after the equation's first publication by Winsauer et al. (1952), and which is sometimes called the “tortuosity” or “lithology” parameter. This parameter is not, however, theoretically justified. Paradoxically, the Winsauer et al. (1952) form of Archie's law often performs better than the original, more theoretically correct version. The difference in the cementation exponent calculated from these two forms of Archie's law is important, and can lead to a misestimation of reserves by at least 20 % for typical reservoir parameter values. We have examined the apparent paradox, and conclude that while the theoretical form of the law is correct, the data that we have been analysing with Archie's law have been in error. There are at least three types of systematic error that are present in most measurements: (i) a porosity error, (ii) a pore fluid salinity error, and (iii) a temperature error. Each of these systematic errors is sufficient to ensure that a non-unity value of the parameter a is required in order to fit the electrical data well. Fortunately, the inclusion of this parameter in the fit has compensated for the presence of the systematic errors in the electrical and porosity data, leading to a value of cementation exponent that is correct. The exceptions are those cementation exponents that have been calculated for individual core plugs. We make a number of recommendations for reducing the systematic errors that contribute to the problem and suggest that the value of the parameter a may now be used as an indication of data quality.

scholarly journals PENGARUH PERUBAHAN NILAI PARAMETER TERHADAP NILAI ERROR PADA METODE RUNGE-KUTTA ORDE 3

2017 ◽  
Vol 3 (2) ◽  
Author(s):  
Tornados P Silaban ◽  
Faiz . Ahyaningsih
Keyword(s):  
Linear Equations ◽  
Research Process ◽  
Kutta Method ◽  
System Of Linear Equations ◽  
Runge Kutta Method ◽  
A Value ◽  
Fixed Parameter ◽  
Higher Derivatives ◽  
Runge Kutta ◽  
Parameter Values

ABSTRACTRunge-Kutta method is a numerical method used to find the solution of an equation. This method seeks to obtain a higher degree of precision, and at the same time seeking to avoid the need of higher derivatives by evaluating the function f (x, y) at the selected point in each interval step. In this paper discussed the effect of changes in the value of the parameter (h) to the value of the error in the Runge-Kutta method Order-3. The equation to be discussed is a linear ordinary differential equation of the two levels that have been changed into a system of linear equations. In the research process was not found fixed parameter values to get the minimum error value, because each parameter has a value of error varied for each equation.Keywords: Runge-Kutta, parameters, error.

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