scholarly journals A study on the variation of zeta potential with mineral composition of rocks and types of electrolyte

2018 ◽  
Vol 40 (2) ◽  
pp. 109-116
Author(s):  
Luong Duy Thanh ◽  
Rudolf Sprik
Keyword(s):  
Porous Media ◽  
Zeta Potential ◽  
Streaming Potential ◽  
Physical Review ◽  
Surface Site ◽  
Porous Rocks ◽  
Geophysical Research ◽  
Potential Coefficient ◽  
Electrokinetic Phenomena ◽  
Site Density

Streaming potential in rocks is the electrical potential developing when an ionic fluid flows through the pores of rocks. The zeta potential is a key parameter of streaming potential and it depends on many parameters such as the mineral composition of rocks, fluid properties, temperature etc. Therefore, the zeta potential is different for various rocks and liquids. In this work, streaming potential measurements are performed for five rock samples saturated with six different monovalent electrolytes. From streaming potential coefficients, the zeta potential is deduced. The experimental results are then explained by a theoretical model. From the model, the surface site density for different rocks and the binding constant for different cations are found and they are in good agreement with those reported in literature. The result also shows that (1) the surface site density of Bentheim sandstone mostly composed of silica is the largest of five rock samples; (2) the binding constant is almost the same for a given cation but it increases in the order KMe(Na+) < KMe(K+) < KMe(Cs+) for a given rock.References Corwin R. F., Hoovert D.B., 1979. The self-potential method in geothermal exploration. Geophysics 44, 226-245. Dove P.M., Rimstidt J.D., 1994. Silica-Water Interactions. Reviews in Mineralogy and Geochemistry 29, 259-308. Glover P.W.J., Walker E., Jackson M., 2012. Streaming-potential coefficient of reservoir rock: A theoretical model. Geophysics, 77, D17-D43. Ishido T. and Mizutani H., 1981. Experimental and theoretical basis of electrokinetic phenomena in rock-water systems and its applications to geophysics. Journal of Geophysical Research, 86, 1763-1775. Jackson M., Butler A., Vinogradov J., 2012. Measurements of spontaneous potential in chalk with application to aquifer characterization in the southern UK: Quarterly Journal of Engineering Geology & Hydrogeology, 45, 457-471. Jouniaux L. and T. Ishido, 2012. International Journal of Geophysics. Article ID 286107, 16p. Doi:10.1155/2012/286107. Kim S.S., Kim H.S., Kim S.G., Kim W.S., 2004. Effect of electrolyte additives on sol-precipitated nano silica particles. Ceramics International 30, 171-175. Kirby B.J. and Hasselbrink E.F., 2004. Zeta potential of microfluidic substrates: 1. Theory, experimental techniques, and effects on separations. Electrophoresis, 25, 187-202. Kosmulski M., and Dahlsten D., 2006. High ionic strength electrokinetics of clay minerals. Colloids and Surfaces, A: Physicocemical and Engineering Aspects, 291, 212-218. Lide D.R., 2009, Handbook of chemistry and physics, 90th edition: CRC Press. Luong Duy Thanh, 2014. Electrokinetics in porous media, Ph.D. Thesis, University of Amsterdam, the Netherlands. Luong Duy Thanh and Sprik R., 2016a. Zeta potential in porous rocks in contact with monovalent and divalent electrolyte aqueous solutions, Geophysics, 81, D303-D314. Luong Duy Thanh and Sprik R., 2016b. Permeability dependence of streaming potential coefficient in porous media. Geophysical Prospecting, 64, 714-725. Luong Duy Thanh and Sprik R., 2016c. Laboratory Measurement of Microstructure Parameters of Porous Rocks. VNU Journal of Science: Mathematics-Physics 32, 22-33. Mizutani H., Ishido T., Yokokura T., Ohnishi S., 1976. Electrokinetic phenomena associated with earthquakes. Geophysical Research Letters, 3, 365-368. Ogilvy A.A., Ayed M.A., Bogoslovsky V.A., 1969. Geophysical studies of water leakage from reservoirs. Geophysical Prospecting, 17, 36-62. Onsager L., 1931. Reciprocal relations in irreversible processes. I. Physical Review, 37, 405-426. Revil A. and Glover P.W.J., 1997. Theory of ionic-surface electrical conduction in porous media. Physical Review B, 55, 1757-1773. Scales P.J., 1990. Electrokinetics of the muscovite mica-aqueous solution interface. Langmuir, 6, 582-589. Behrens S.H. and Grier D.G., 2001. The charge of glass and silica surfaces. The Journal of Chemical Physics, 115, 6716-6721. Stern O., 1924. Zurtheorieder electrolytischendoppelschist. Z. Elektrochem, 30, 508-516. Tchistiakov A.A., 2000. Physico-chemical aspects of clay migration and injectivity decrease of geothermal clastic reservoirs: Proceedings World Geothermal Congress, 3087-3095. Wurmstich B., Morgan F.D., 1994. Modeling of streaming potential responses caused by oil well pumping. Geophysics, 59, 46-56. 

Zeta potential in porous rocks in contact with monovalent and divalent electrolyte aqueous solutions

Geophysics ◽  
2016 ◽  
Vol 81 (4) ◽  
pp. D303-D314 ◽  
Author(s):  
Luong Duy Thanh ◽  
Rudolf Sprik
Keyword(s):  
Zeta Potential ◽  
Streaming Potential ◽  
Shear Plane ◽  
Theoretical Models ◽  
Porous Rocks ◽  
Electrokinetic Phenomena ◽  
Reservoir Rocks ◽  
Partially Saturated ◽  
Different Types ◽  
Stern Potential

Electrokinetic phenomena are the result of a coupling between a fluid flow and an electric current flow in porous rocks. The zeta potential is an important parameter that influences the electrokinetic coupling. Most reservoir rocks are saturated or partially saturated by natural water containing various types of ions. Therefore, it is important to understand how the zeta potential and therefore the electric double layer (EDL) behave for different types of ions or electrolytes. Types of electrolytes influence the zeta potential most by affecting the surface charge — by changing the thickness of the EDL and the exact location of the shear plane. To study the dependence of the zeta potential on various electrolytes, we have carried out streaming potential measurements for consolidated rock samples saturated by monovalent and divalent electrolytes. From streaming potential coefficients, the zeta potential is obtained for different systems of electrolytes and rocks. The experimental results of silica-based rocks are then compared with theoretical models. For 1:1 or 1:2 electrolytes, a theoretical model for the zeta potential that has been available in literature is used. For 2:2 or 2:1 electrolytes, we have developed a new model to calculate the Stern potential and the zeta potential. The comparison found that the theoretical models can explain the main behavior of the zeta potential against types of electrolytes and types of silica-based rocks. The results show that the zeta potential for monovalent electrolytes is higher than that for divalent electrolytes. The zeta potential of the silica-based samples is higher than that of the nonsilica-based samples when they are saturated by the same types of electrolyte.

scholarly journals Examination of the fractal model for streaming potential coefficient in porous media

2019 ◽  
Vol 35 (1) ◽  
Author(s):  
Luong Duy Thanh
Keyword(s):  
Experimental Data ◽  
Porous Media ◽  
Zeta Potential ◽  
Streaming Potential ◽  
Fractal Model ◽  
Potential Coefficient ◽  
Proposed Model ◽  
Alternative Approach ◽  
High Fluid ◽  
Good Agreement

In this work, the fractal model for the streaming potential coefficient in porous media recently published has been examined by calculating the zeta potential from the measured streaming potential coefficient. Obtained values of the zeta potential are then compared with experimental data. Additionally, the variation of the streaming potential coefficient with fluid electrical conductivity is predicted from the model. The results show that the model predictions are in good agreement with the experimental data available in literature. The comparison between the proposed model and the Helmholtz-Smoluchowski (HS) equation is also carried out. It is seen that that the prediction from the proposed model is quite close to what is expected from the HS equation, in particularly at the high fluid conductivity or large grain diameters. Therefore, the model can be an alternative approach to obtain the zeta potential from the streaming potential measurements.

Seismo-electric Conversion in Sandstones and Shales using 2 Different Experimental Approaches, Modelling and Theory

2020 ◽  
Author(s):  
Paul Glover ◽  
Rong Peng ◽  
Piroska Lorinczi ◽  
Bangrang Di
Keyword(s):  
Zeta Potential ◽  
Numerical Modelling ◽  
Clay Minerals ◽  
Shale Gas ◽  
Streaming Potential ◽  
Oil Reservoirs ◽  
Low Permeability ◽  
Experimental Measurements ◽  
Frequency Range ◽  
Potential Coefficient

&lt;p&gt;The development of seismo-electric (SE) exploration techniques relies significantly upon being able to understand and quantify the strength of frequency-dependent SE conversion. However, there have been very few SE measurements or modelling carried out. In this paper we present two experimental methods for making such measurements, and examine how the strength of SE conversion depends on frequency, porosity, permeability, and why it is unusual in shales. The first is based on an electromagnetic shaker and can be used in the 1 Hz to 2 kHz frequency range. The second is a piezo-electric water-bath apparatus which can be used in the 1kHz to 500 kHz frequency range.&lt;/p&gt;&lt;p&gt;The first apparatus has been tested on samples of Berea sandstone. Both the in-phase and in-quadrature components of the streaming potential coefficient have been measured with an uncertainty of better than &amp;#177;4%. The experimental measurements show the critical frequency at which the quadrature component is maximal, and the frequency of this component is shown to agree very well with both permeability and grain size. The experimental measurements have been modelled using several different methods.&lt;/p&gt;&lt;p&gt;The second apparatus was used to measure SE coupling as a function of porosity and permeability, interpreting the results using a micro-capillary model and current theory. We found a general agreement between the theoretical curves and the test data, indicating that SE conversion is enhanced by increases in porosity over a range of different frequencies. However, SE conversion has a complex relationship with rock permeability, which changes with frequency, and which is more sensitive to changes in the petrophysical properties of low-permeability samples. This observation suggests that seismic conversion may have advantages in characterizing low permeability reservoirs such as tight gas and tight oil reservoirs as well as shale gas reservoirs.&lt;/p&gt;&lt;p&gt;We have also carried out SE measurements on Sichuan Basin shales (permeability 1.47 &amp;#8211; 107 nD), together with some comparative measurements on sandstones (0.2 &amp;#8211; 60 mD). Experimental results show that SE conversion in shales is comparable to that exhibited by sandstones, and is approximately independent of frequency in the seismic frequency range (&lt;1 kHz). Anisotropy which arises from bedding in the shales results in anisotropy in the streaming potential coefficient. Numerical modelling has been used to examine the effects of varying zeta potential, porosity, tortuosity, dimensionless number and permeability. It was found that SE conversion is highly sensitive to changes in porosity, tortuosity and zeta potential in shales. Numerical modelling suggests that the cause of the SE conversion in shales is enhanced zeta potentials caused by clay minerals, which are highly frequency dependent. This is supported by a comparison of our experimental data with numerical modelling as a function of clay mineral composition from XRD measurements. Consequently, the sensitivity of SE coupling to the clay minerals suggests that SE exploration may have potential for the characterization of clay minerals in shale gas and shale oil reservoirs.&lt;/p&gt;

scholarly journals Frequency-Dependent Streaming Potential of Porous Media—Part 1: Experimental Approaches and Apparatus Design

2012 ◽  
Vol 2012 ◽  
pp. 1-15 ◽  
Author(s):  
P. W. J. Glover ◽  
J. Ruel ◽  
E. Tardif ◽  
E. Walker
Keyword(s):  
Streaming Potential ◽  
Electrical Current ◽  
Potential Coefficient ◽  
Frequency Dependent ◽  
Electrokinetic Phenomena ◽  
High Frequencies ◽  
Design Build ◽  
Experimental Approaches ◽  
Electro Magnetic ◽  
Piezoelectric Drive

Electrokinetic phenomena link fluid flow and electrical flow in porous and fractured media such that a hydraulic flow will generate an electrical current andvice versa. Such a link is likely to be extremely useful, especially in the development of the electroseismic method. However, surprisingly few experimental measurements have been carried out, particularly as a function of frequency because of their difficulty. Here we have considered six different approaches to make laboratory determinations of the frequency-dependent streaming potential coefficient. In each case, we have analyzed the mechanical, electrical, and other technical difficulties involved in each method. We conclude that the electromagnetic drive is currently the only approach that is practicable, while the piezoelectric drive may be useful for low permeability samples and at specified high frequencies. We have used the electro-magnetic drive approach to design, build, and test an apparatus for measuring the streaming potential coefficient of unconsolidated and disaggregated samples such as sands, gravels, and soils with a diameter of 25.4 mm and lengths between 50 mm and 300 mm.

scholarly journals Streaming Potential Measurements on the Binary Mixture Triethylamine-Water Near the Demixing Phase Transition

2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Luong Duy Thanh ◽  
Rudolf Sprik
Keyword(s):  
Phase Transition ◽  
Zeta Potential ◽  
Binary Mixture ◽  
Transition Point ◽  
Streaming Potential ◽  
Density Fluctuations ◽  
Phase Transition Point ◽  
Physical Parameters ◽  
Potential Coefficient ◽  
Critical Composition

Large density fluctuations developing near the phase transition point of the binary mixture affect physical parameters directly related to the electrokinetic coupling coefficient. Here the first electrokinetic measurements for a porous rock sample are carried out with a critical binary mixture of triethylamine-water, especially around the phase transition point. From the measured streaming potential coefficient, the zeta potential is obtained for the critical composition. The results show that there is no anomaly in the streaming potential coefficient as the temperature approaches the demixing temperature. It is also seen that the streaming potential coefficient and the zeta potential in magnitude decreases with increasing temperature. This observation is opposite to what has been observed in literature. It means that the properties of the electric double layer for the mixtures are different from those for aqueous electrolytes. Additionally, the zeta potential for the critical composition is predicted to fluctuate around the critical point.

Streaming potential in porous media: 1. Theory of the zeta potential

1999 ◽  
Vol 104 (B9) ◽  
pp. 20021-20031 ◽  
Author(s):  
A. Revil ◽  
P. A. Pezard ◽  
P. W. J. Glover
Keyword(s):  
Porous Media ◽  
Zeta Potential ◽  
Streaming Potential

Electrokinetic Phenomena in Porous Media

1995 ◽  
Vol 407 ◽  
Author(s):  
David B. Pengra ◽  
Po-Zen Wong
Keyword(s):  
Porous Media ◽  
Electric Fields ◽  
Transport Coefficients ◽  
Applied Pressure ◽  
Streaming Potential ◽  
High Sensitivity ◽  
Saturated Porous Media ◽  
Ac Electroosmosis ◽  
Throat Radius ◽  
Electrokinetic Phenomena

ABSTRACTElectrokinetic phenomena, such as electroosmosis (fluid-flow induced by applied electric fields) and streaming potential (the complementary process) are known to exist in brine-saturated porous media, but are very difficult to measure. With modern instrumentation and an ac method, we can now determine these transport coefficients accurately, and use them to characterize the permeability k1, the effective throat radius Re, and the electric potential at the slip-plane, or ζ-potential. Our study shows that permeability can be determined by two different means: by combining the dc values of the streaming potential, electroosmotic pressure and conductivity; or from the frequency response of ac electroosmosis alone. The high sensitivity of the method allows us to measure k over the 0.1–10,000 millidarcy range with less than lOkPa applied pressure. This article reviews some of the basics of electrokinetics and describes our methods. We also discuss effects of brine salinity and possible effects due to the fractal nature of the pore surface.

A fractal model for streaming potential coefficient in porous media

2017 ◽  
Vol 66 (4) ◽  
pp. 753-766 ◽  
Author(s):  
Luong Duy Thanh ◽  
Phan Van Do ◽  
Nguyen Van Nghia ◽  
Nguyen Xuan Ca
Keyword(s):  
Porous Media ◽  
Streaming Potential ◽  
Fractal Model ◽  
Potential Coefficient

scholarly journals Experimental Measurement of Frequency-Dependent Permeability and Streaming Potential of Sandstones

2019 ◽  
Vol 131 (2) ◽  
pp. 333-361 ◽  
Author(s):  
P. W. J. Glover ◽  
R. Peng ◽  
P. Lorinczi ◽  
B. Di
Keyword(s):  
Porous Media ◽  
Elastic Waves ◽  
Fluid Pressure ◽  
Streaming Potential ◽  
Transition Frequency ◽  
High Porosity ◽  
Critical Transition ◽  
Potential Coefficient ◽  
Frequency Dependent ◽  
Dynamic Permeability

Abstract Hydraulic flow, electrical flow and the passage of elastic waves through porous media are all linked by electrokinetic processes. In its simplest form, the passage of elastic waves through the porous medium causes fluid to flow through that medium and that flow gives rise to an electrical streaming potential and electrical counter-current. These processes are frequency-dependent and governed by coupling coefficients which are themselves frequency-dependent. The link between fluid pressure and fluid flow is described by dynamic permeability, which is characterised by the hydraulic coupling coefficient (Chp). The link between fluid pressure and electrical streaming potential is characterised by the streaming potential coefficient (Csp). While the steady-state values of such coefficients are well studied and understood, their frequency dependence is not. Previous work has been confined to unconsolidated and disaggregated materials such as sands, gravels and soils. In this work, we present an apparatus for measuring the hydraulic and streaming potential coefficients of high porosity, high permeability consolidated porous media as a function of frequency. The apparatus operates in the range 1 Hz to 2 kHz with a sample of 10 mm diameter and 5–30 mm in length. The full design and validation of the apparatus are described together with the experimental protocol it uses. Initial data are presented for three samples of Boise sandstone, which present as dispersive media with the critical transition frequency of 918.3 ± 99.4 Hz. The in-phase and in-quadrature components of the measured hydraulic and streaming potential coefficients have been compared to the Debye-type dispersion model as well as theoretical models based on bundles of capillary tubes and porous media. Initial results indicate that the dynamic permeability data present an extremely good fit to the capillary bundle and Debye-type dispersion models, while the streaming potential coefficient presents an extremely good fit to all of the models up to the critical transition frequency, but diverges at higher frequencies. The streaming potential coefficient data are best fitted by the Pride model and its Walker and Glover simplification. Characteristic pore size values calculated from the measured critical transition frequency fell within 1.73% of independent measures of this parameter, while the values calculated directly from the Packard model showed an underestimation by about 12%.

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