Cis-dioxo-bis [3-methoxy-2,2-dimethylpropanediamine] Molybdenum/Surfactant-Modified Electrode for Simultaneous Sensing of Ascorbic Acid and Dopamine

In this work the determination of ascorbic acid (AA) at glassy carbon electrode (GCE) modified with a perforated film produced by reduction of diazonium generated in situ from p-phenylenediamine (PD) is reported. Holes were intentionally created in the modifier film by stripping a pre-deposited gold nanoparticles. The modified electrodes were electrochemically characterized by common redox probes: hydroquinone, ferrocyanide and hexamineruthenium(III). The cyclic voltammetric and amperometric response of AA using the modified electrodes was compared with that of bare GCE. The bare GCE showed a linear response to AA in the concentration range of 5 mM to 45 mM with detection limit of 1.656 mM and the modified GCE showed a linear response to AA in the concentration range of 5 ?M to 45 ?M with detection limit of 0.123 ?M. The effect of potential intereferents on amperometric signal of AA at the modified GCE was examined and found to be minimal. The inter-electrode reproducibility, stability, and accuracy were determined. The modified electrode showed excellent inter-electrode reproducibility, accuracy and stability. The modified electrode reported is a promising candidate for use in electroanalysis of AA.

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Electrochemical Sensing of Ascorbic Acid, Hydrogen Peroxide and Glucose by Bimetallic (Fe, Ni)−CNTs Composite Modified Electrode

Electroanalysis ◽

10.1002/elan.201800768 ◽

2019 ◽

Vol 31 (5) ◽

pp. 851-857 ◽

Cited By ~ 4

Author(s):

Sayed Tayyab Raza Naqvi ◽

Bahareh Shirinfar ◽

Dilshad Hussain ◽

Saadat Majeed ◽

Muhammad Naeem Ashiq ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Ascorbic Acid ◽

Modified Electrode ◽

Electrochemical Sensing

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Simultaneous determination of ascorbic acid, dopamine and uric acid using poly(l-leucine)/DNA composite film modified electrode

Sensors and Actuators B Chemical ◽

10.1016/j.snb.2015.02.044 ◽

2015 ◽

Vol 213 ◽

pp. 188-194 ◽

Cited By ~ 35

Author(s):

Xinyu Zheng ◽

Yuheng Guo ◽

Jinshuai Zheng ◽

Xuechou Zhou ◽

Qinglu Li ◽

...

Keyword(s):

Ascorbic Acid ◽

Uric Acid ◽

Composite Film ◽

Simultaneous Determination ◽

Modified Electrode

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Nitrogen doped lignocellulose/binary metal sulfide modified electrode: Preparation and application for non-enzymatic ascorbic acid, dopamine and nitrite sensing

Journal of Electroanalytical Chemistry ◽

10.1016/j.jelechem.2017.10.066 ◽

2017 ◽

Vol 806 ◽

pp. 150-157 ◽

Cited By ~ 10

Author(s):

Ya Zhang ◽

Fangfang Wen ◽

Zhihai Huang ◽

Jing Tan ◽

Zhifeng Zhou ◽

...

Keyword(s):

Ascorbic Acid ◽

Modified Electrode ◽

Metal Sulfide ◽

Nitrogen Doped ◽

Binary Metal

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Selective Determination of Dopamine in Presence of Ascorbic Acid Using Nafion Coated Methylene Blue Functionalized Graphite Electrode

Asian Journal of Chemistry ◽

10.14233/ajchem.2019.22078 ◽

2019 ◽

Vol 31 (10) ◽

pp. 2185-2190

Author(s):

G. Sivasankari ◽

K. Sivasankari ◽

T. Nalini ◽

P. Padmapriya ◽

M. Nadhiya

Keyword(s):

Methylene Blue ◽

Ascorbic Acid ◽

Modified Electrode ◽

Electrode Surface ◽

Graphite Electrode ◽

Low Cost ◽

Differential Pulse ◽

Selective Determination ◽

The Stability

An electrochemical sensor has been developed using methylene blue (MB) unctionalized graphite for the selective determination of dopamine in the presence of ascorbic acid. The immobilization of methylene blue on graphite was done by carbodiimide coupling method. The methylene blue functionalized graphite was characterized by SEM, FTIR spectroscopy and UV-visible spectroscopy. The immobilization of methylene blue functionalized graphite (MB-G) on the electrode surface was made by drop casting a small volume of MB-G dispersed methanol solution on the electrode surface. About 5 L of 0.5 % Nafion solution was also dropcasted for the stability and selectivity. The MB-G modified electrode was characterized by cyclic voltammetry. The modified electrode promotes the electrocatalytic oxidation of dopamine at a lower potential of 160 mV. The selective determination of dopamine in the presence of 100 times higher concentration of ascorbic acid was achieved by differential pulse voltammetry. The modified electrode offered a simple, selective and sensitive determination of low levels of dopamine. Also the oxidation over potential was reduced to an extent of 360 mV comparing with the bare graphite electrode. The proposed sensor has the advantage of easy fabrication, low cost, good sensitivity, reproducibility and stability.

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