scholarly journals Phenanthrene and Methylphenanthrene Isomers in Maturity Assessment of Biodegraded Crude Oils (Sakhalin, Russia)

2017 ◽  
Vol 4 (3) ◽  
pp. 213
Author(s):  
Ksenija Stojanović ◽  
Branimir Jovančićević ◽  
Anatoly Golovko ◽  
Julia Golovko ◽  
Galina Pevneva ◽  
...  

This paper is aimed at defining two new advantageous maturation parameters based on distribution and abundance of phenanthrene (P) and methylphenanthrene (MP) isomers in the tricyclic fraction of<br />aromatic hydrocarbons: MPI 3+1/PAI 1 and [2(2-MP+3-MP)+P]/1-MP. The applicability of newly proposed parameters was checked by correlation analysis. Depth of the reservoir rock, diasterane maturation parameter, as well as several typical aromatic fraction maturation parameters were used for this purpose. The examined oils (fourteen samples from nine oil fields of Sakhalin Island, Russia), were of Miocene age and from reservoir rocks of relatively wide range of depths (73-2841 m). All samples represented biodegraded, or mixtures of biodegraded and nonbiodegraded oils [1].

2001 ◽  
Vol 66 (5) ◽  
pp. 297-308 ◽  
Author(s):  
B. Jovancicevic ◽  
H. Wehner ◽  
G. Scheeder ◽  
D. Plecas ◽  
M. Ercegovac ◽  
...  

The results of an investigation of crude oils originating from the Sirakovo and Bradarac-Maljurevac localities (southern part of the Pannonian Basin) are reported in this paper. The aim was to estimate the organic geochemical similarity of the crude oils from the Drmno (Kostolac) depression oil fields. The nine selected samples originated from reservoir rocks of various depths. Reliable source and organic geochemical maturation parameters served as the basis for the correlation studies. The similar origin of the investigated Drmno depression crude oils was corroborated, characterized by a significant participation of terrestrial precursor biomass. They were shown to be of relatively low maturity and to have been formed during the earlier stages of the diagenetic-catagenetic sequence of processes leading to the formation of crude oils, most probably in source rocks ofTertiary age, corresponding to vitrinite reflectances between Ro = 0.70 % and Ro = 0.80 %. The crude oils from Bradarac-Maljurevac seemed to be somewhat less homogeneous with respect to organic geochemical parameters compared to Sirakovo crude oils.


1975 ◽  
Vol 15 (1) ◽  
pp. 45
Author(s):  
S. B. Devine ◽  
B. C. Youngs

The Amadeus, Warburton, Officer, Adavale, Arckaringa, Pedirka, Cooper and Great Artesian Basins form a complex system of overlapping basins in central Australia. Cambrian rocks are widespread in the Amadeus, Warburton and possibly the Officer Basins and are marked by the major role of carbonate deposition. Gas and oil shows are known from the Amadeus and Warburton Basins. In South Australia their reservoir potential lies in shoreline clean-up of generally dirty marine sandstones and porosity-permeability associated with archaeocyathid bioherms or dolomitization of limestones.The Ordovician rocks follow the widespread distribution of the Cambrian rocks and are distinctive for thick quartzites and graptolitic shales. In South Australia, the Warburton and Officer Basins may have facies developed which are similar to the Pacoota and Stairway Sandstones, the reservoir rocks for the Amadeus Basin gas and oil fields. Large anticlinal structures have recently been suggested by S.A. Mines Department geophysical work in the Officer Basin which enhances the potential.Red beds are distinctive in the Devonian System. Deposition apparently spilt into the peri-Musgrave Block area and the Adavale Basin to Innamincka area. A thickness of over 3 000 metres of Devonian rocks was drilled in the Officer Basin which contained some reservoir rock lithology. The petroleum potential in South Australia is relatively unattractive.Some 3.4 trillion cu ft of deliverable gas reserves have been established already in the Permian sediments of the Cooper Basin which are up to 900 m thick. The Early Permian sediments of the Pedirka Basin which may be at least 500 m thick may hold similar petroleum potential.


2021 ◽  
Author(s):  
Małgorzata Uliasz

A workover fluid is a type of special liquids used at the end of borehole drilling, i.e. during well operation or during reconstruction works. Such works, carried out at various stages of borehole operation, are aimed at maintaining or increasing the production of a specific well and at maintaining its proper technical condition. They may be carried out only after injecting the workover fluid into the borehole, which should generate counterpressure on the reservoir, preventing the inflow of reservoir media into the borehole, and should enable the maintaining of the hydraulic conductivity of the reservoir rock. To ensure that the basic requirements are satisfied by the workover fluid injected into the borehole, its physical and chemical properties must correspond to the geological and reservoir conditions of the specified level of reservoir rocks. Due to this, the composition of the workover fluid should be determined based on the reservoir pressure gradient, mineralogical composition of reservoir rocks and of their binder, as well as the chemical composition of reservoir waters. These are the basic criteria for selection of the composition and evaluation of the quality of the workover fluid, which enable control of the physicochemical processes occurring within the borehole zone, such as clogging of the porous space of rocks, hydration of clay minerals, capillary effects and changes in the surface tension at the interface, as well as the interaction of fluid with reservoir waters. Limitation of the intensity of occurrence of such processes, which affect the degree of damage to the permeability of the reservoir rocks in horizons featuring normal or reduced reservoir pressure, largely depends on the type of workover fluid used, i.e. brine without a solid phase and brine containing a solid phase or a liquid with density below 1.0 kg/dm3. The composition and technological properties of the workover fluid, properly selected to the specific geological and reservoir conditions, allow one to maintain the productivity of the well to a degree that does not require application of additional treatment, such as acid-treatment, fracturing and reperforations. The aim of the monograph is to show the role of a workover fluid in the conducted reconstruction treatments, as well as the importance of its technological properties in limiting damage to the permeability of reservoir rocks within the borehole zone. The presented issues comprise: • causes and threats to the deterioration of reservoir rock permeability resulting from the application of an improperly selected workover fluid; • tasks of the workover fluid and methods to improve its technological properties in terms of protecting the hydraulic conductivity of reservoir rocks; • types of workover fluids developed, the methodology for determination and assessment of their technological properties, as well as usability under reservoir conditions. The monograph also includes a short description of other special liquids used in the preparation of a well for exploitation. These are: washing and cleaning liquids, packer fluids and those used for perforation, as well as buffers for rope operations and pipe cleaning prior to packer fluid injection. The presented issue is a synthesis of a wide range of research and development works carried out at the INiG - PIB. It has been prepared based on the obtained results of laboratory tests carried out for geological and reservoir conditions existing in the productive horizons of the Carpathian Foredeep, as well as of the Carpathians and the Polish Lowlands. Keywords: borehole reconstruction, geological and reservoir conditions, workover fluid tasks, workover fluid properties, chemicals, blockers, permeability


1997 ◽  
Vol 77 (04) ◽  
pp. 725-729 ◽  
Author(s):  
Mario Colucci ◽  
Silvia Scopece ◽  
Antonio V Gelato ◽  
Donato Dimonte ◽  
Nicola Semeraro

SummaryUsing an in vitro model of clot lysis, the individual response to a pharmacological concentration of recombinant tissue plasminogen activator (rt-PA) and the influence on this response of the physiological variations of blood parameters known to interfere with the fibrinolytic/thrombolytic process were investigated in 103 healthy donors. 125I-fibrin labelled blood clots were submersed in autologous plasma, supplemented with 500 ng/ml of rt-PA or solvent, and the degree of lysis was determined after 3 h of incubation at 37° C. Baseline plasma levels of t-PA, plasminogen activator inhibitor 1 (PAI-1), plasminogen, α2-anti-plasmin, fibrinogen, lipoprotein (a), thrombomodulin and von Willebrand factor as well as platelet and leukocyte count and clot retraction were also determined in each donor. rt-PA-induced clot lysis varied over a wide range (28-75%) and was significantly related to endogenous t-PA, PAI-1, plasminogen (p <0.001) and age (p <0.01). Multivariate analysis indicated that both PAI-1 antigen and plasminogen independently predicted low response to rt-PA. Surprisingly, however, not only PAI-1 but also plasminogen was negatively correlated with rt-PA-ginduced clot lysis. The observation that neutralization of PAI-1 by specific antibodies, both in plasma and within the clot, did not potentiate clot lysis indicates that the inhibitor, including the platelet-derived form, is insufficient to attenuate the thrombolytic activity of a pharmacological concentration of rt-PA and that its elevation, similarly to the elevation of plasminogen, is not the cause of clot resistance but rather a coincident finding. It is concluded that the in vitro response of blood clots to rt-PA is poorly influenced by the physiological variations of the examined parameters and that factors other than those evaluated in this study interfere with clot dissolution by rt-PA. In vitro clot lysis test might help to identify patients who may be resistant to thrombolytic therapy.


1994 ◽  
Vol 13 (2) ◽  
pp. 97-106 ◽  
Author(s):  
Luo Binjie ◽  
Li Xinyu

2020 ◽  
Author(s):  
Pengcheng Chen ◽  
Shadi Fatayer ◽  
Bruno Schuler ◽  
Jordan N. Metz ◽  
Leo Gross ◽  
...  

The initial thermal reactions of aromatic hydrocarbons are relevant to many industrial applications. However, tracking the growing number of heavy polycyclic aromatic hydrocarbon (PAH) products is extremely challenging because many reactions are unfolding in parallel from a mixture of molecules. Herein, we studied the reactions of 2,7-dimethylpyrene (DMPY) to decipher the roles of methyl substituents during mild thermal treatment. We found that the presence of methyl substituents is key for reducing the thermal severity required to initiate chemical reactions in natural molecular mixtures. A complex mixture of thermal products including monomers, dimers, and trimers were characterized by NMR, mass spectrometry and non-contact atomic force microscopy (nc-AFM). A wide range of structural transformations including methyl transfer and polymerization reactions were identified. A detailed mechanistic understanding was obtained on the roles of H radicals during the polymerization of polycyclic aromatic hydrocarbons.


2021 ◽  
Vol 10 (1) ◽  
pp. 20-23
Author(s):  
Marina Magomedovna Arslanova ◽  
Elena Aleksandrovna Shornikova

Assessing the quality of environmental objects, identifying the causes of pollution and predicting the future state is an urgent and important task, since it is the quality of natural objects that largely determines the state of human health. This paper presents results of the statistical analysis of the data of water quality monitoring in the rivers within oil fields of the Khanty-Mansi Autonomous Okrug Yugra during 20182019. The correlation analysis (according to Pearson) was carried out to identify the relationships between the samples of hydrochemical parameters and the number of microorganisms of various ecological-trophic groups. As a result of the correlation analysis of the relationship between the indicators of the chemical composition of water, a direct and inverse correlation was obtained for the following indicators: total iron, anionic surfactants, nickel, phenols, copper, sulfates, ammonium ions, lead, phosphates, manganese. The maximum value of the correlation coefficient is observed for Ni and Cr concentrations. For total iron and manganese, a significant positive correlation is also revealed. The distribution of chemical compounds in the rivers doesnt have a pronounced correlation dependence, which is probably due to the heterogeneity of the composition of the waters, as well as to the increasing impact on the environment of the oil and gas complex.


Sign in / Sign up

Export Citation Format

Share Document