Kinetic Description of Nonequilibrium Transfer Processes

Author(s):  
A.N. Morozov

The paper uses the example of the Brownian motion to kinetically describe the process of entropy increment in a nonequilibrium medium. The study shows that depending on the degree of nonequilibrium, the convergence to an equilibrium state occurs according to different laws. In the case of a strongly nonequilibrium medium, the entropy increment is described mathematically by the weakest logarithmic law, and in the case of a close-to-equilibrium medium, the entropy seeks a maximum value according to the strongest mathematical law --- the exponential law. The obtained expressions describing the Brownian motion can be extended to all other nonequilibrium processes. Mathematical modeling made it possible to calculate the process of entropy increment for an arbitrary degree of nonequilibrium and establish the parameters at which the transition from logarithmic to exponential law of entropy increment occurs when the thermodynamic system seeks an equilibrium state

Author(s):  
Yu. I. Voitenko

The article continues the author’s series of works on the application of synergetic theory to understand and describe the processes and phenomena that accompany the search and development of mineral resources. The research results show that the synergetic theory is universal and allows to understand and describe a wide range of phenomena and processes that occur in geological exploration and mining: dynamic phenomena in mines (outbursts of rocks and coal), spontaneous сombustion of сoal in coal mines, emergency outbursts of oil and gas from exploration wells, destruction of high-pressure pipelines, geodynamic phenomena in quaternary deposits, sedimentary rocks, and in the geological structures of the crystalline basement. One of the signs of processes and phenomena that have a synergistic nature is the nonlinear nature of the system’s response to weak perturbations. Minor disturbances slightly change the structure of geological material, in some cases change the mechanical and physical properties of formation fiuids. This creates the conditions for disturbing the unstable equilibrium of the system at the bifurcation points and its transition to another equilibrium state with other thermodynamic parameters that characterize the new state of the system. Such transitions are characterized by kinetic and phase transitions. In particular, in the reservoir rock, in coal, micro- and macrocrack systems are formed and developed. The shape of dissipative structures is described using fractal theory. The duration of self-organization of dissipative structures and the transition of the system to a new equilibrium state depends on the type of dissipative structures, the properties of the environment in which they are formed, and the speed of physicochemical processes. The article considers the behavior of the system “well – rock formation” as an open thermodynamic system. The internal energy of the formation is compared with the energy of external explosive action from the well. Specific examples show that the behavior of such a system is subject to the laws of synergetics and as a result of weak action on the formation from the well there are significant nonlinear effects of productivity growth due to the internal energy of the formation. This energy is generated by reservoir and rock pressures.


Entropy ◽  
2018 ◽  
Vol 21 (1) ◽  
pp. 9
Author(s):  
Andrey Morozov

This paper presents a description of the fluctuations in transfer processes in a locally nonequilibrium medium. We obtained equations which allow the fluctuations range to be determined for a transferred physical value. It was shown that the general method of describing fluctuations for the processes of diffusion, heat transfer, and viscous fluid flow can be applied. It was established that the fluctuation spectrum during the transfer processes has the character of flicker noise in the low-frequency spectral range.


Author(s):  
A.N. Morozov

The study statistically describes Brownian motion in a locally nonequilibrium medium, taking into account the production of entropy, and proposes to describe the nonequilibrium fluctuations of the velocity of a Brownian particle using a linear integro-differential equation. The characteristic functions of fluctuations of the Brownian particle velocity are obtained, which make it possible to carry out a complete statistical description of Brownian motion in a medium with the production of entropy. Findings of research show that the variance of these fluctuations increases with time according to the logarithmic law. The correlation function of fluctuations of the Brownian particle velocity is calculated and it is shown that it consists of two terms. The first term, which has a power-law dependence, describes equilibrium fluctuations, and the second, which has a logarithmic dependence, describes nonequilibrium fluctuations


2006 ◽  
Vol 20 (09) ◽  
pp. 495-500
Author(s):  
CHANGMING XIAO ◽  
LIXIN HUANG

For a closed thermodynamic system of ideal gas, the entropic force is studied in this paper. The results show that the entropic force arises when the entropy is deviated from its equilibrium maximum value by an external force. This entropic force resists the entropy deviation enlarging, and will drive the entropy back to its maximum value if the external forces disappear.


2007 ◽  
Vol 44 (02) ◽  
pp. 393-408 ◽  
Author(s):  
Allan Sly

Multifractional Brownian motion is a Gaussian process which has changing scaling properties generated by varying the local Hölder exponent. We show that multifractional Brownian motion is very sensitive to changes in the selected Hölder exponent and has extreme changes in magnitude. We suggest an alternative stochastic process, called integrated fractional white noise, which retains the important local properties but avoids the undesirable oscillations in magnitude. We also show how the Hölder exponent can be estimated locally from discrete data in this model.


1986 ◽  
Vol 23 (04) ◽  
pp. 893-903 ◽  
Author(s):  
Michael L. Wenocur

Brownian motion subject to a quadratic killing rate and its connection with the Weibull distribution is analyzed. The distribution obtained for the process killing time significantly generalizes the Weibull. The derivation involves the use of the Karhunen–Loève expansion for Brownian motion, special function theory, and the calculus of residues.


Author(s):  
M. Arif Hayat

Although it is recognized that niacin (pyridine-3-carboxylic acid), incorporated as the amide in nicotinamide adenine dinucleotide (NAD) or in nicotinamide adenine dinucleotide phosphate (NADP), is a cofactor in hydrogen transfer in numerous enzyme reactions in all organisms studied, virtually no information is available on the effect of this vitamin on a cell at the submicroscopic level. Since mitochondria act as sites for many hydrogen transfer processes, the possible response of mitochondria to niacin treatment is, therefore, of critical interest.Onion bulbs were placed on vials filled with double distilled water in the dark at 25°C. After two days the bulbs and newly developed root system were transferred to vials containing 0.1% niacin. Root tips were collected at ¼, ½, 1, 2, 4, and 8 hr. intervals after treatment. The tissues were fixed in glutaraldehyde-OsO4 as well as in 2% KMnO4 according to standard procedures. In both cases, the tissues were dehydrated in an acetone series and embedded in Reynolds' lead citrate for 3-10 minutes.


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