scholarly journals Organochlorine Pollutants within a Polythermal Glacier in the Interior Eastern Alaska Range

Author(s):  
Kimberley R. Miner ◽  
Seth Campbell ◽  
Christopher Gerbi ◽  
Anna Lilijedahl ◽  
Therese Anderson ◽  
...  

To assess the presence of organochlorine pollutants (OCP) in Alaskan sub-Arctic latitudes, we analyzed ice core and meltwater samples from Jarvis Glacier, a polythermal glacier in Interior Alaska. Jarvis Glacier is receding as atmospheric warming continues throughout the region, increasing opportunity for OCP transport both englacially and into the proglacial watershed. Across all meltwater and ice core samples we identify the pesticides DDT, DDE and DDD, α- HCH and ϒ-HCH. OCP concentrations in ice core samples were highest at the 7-14 m depth (0.51 ng/L of DDT) and decreased gradually approaching the bedrock at 79m. Meltwater concentrations from the proglacial creek slightly exceeded concentrations found in the ice core, potentially indicating aggregate OCP glacial loss, with peak OCP concentration (1.12 ng/L of DDD) taken in July and potentially associated to peak melt. Ongoing use of DDT to fight Malaria in Asia, and the extended atmospheric range of HCH may account for concentrations in near-surface ice, correlating with use and atmospheric transport. The opportunity for biota bioaccumulation of OCPs, or human uptake of OCPs from glacial meltwater, may increase as glacial melt continues.

1995 ◽  
Vol 21 ◽  
pp. 59-63 ◽  
Author(s):  
Clinton M. Rowe ◽  
Mark R. Anderson ◽  
Thomas L. Mote ◽  
Karl C. Kuivinen

During the summer of 1993, a field program was conducted to collect several shallow firn cores from two locations in the southern region of the Greenland ice sheet. Stratigraphic evidence of melt from these cores was used for comparison with satellite-derived indications of melt. The shallow firn cores were examined for stratigraphic evidence of past melt events and were sampled for oxygen-isotope analysis to delineate the annual accumulation layers in the snowpack. The relative intensity of each year’s summer melt episode was compared to the corresponding melt frequency derived from microwave emissions. This comparison demonstrates that a linkage between the stratigraphic record and microwave data can be established. Both data sets indicate that there was less melt during the late 1970s and early 1980s than during the late 1980s, in general agreement with climate observations.


2021 ◽  
pp. 1-14
Author(s):  
Jānis Karušs ◽  
Kristaps Lamsters ◽  
Ireneusz Sobota ◽  
Jurijs Ješkins ◽  
Pēteris Džeriņš ◽  
...  

Abstract Understanding glacier drainage system behaviour and its response to increased meltwater production faces several challenges in the High Arctic because many glaciers are transitioning from polythermal to almost entirely cold thermal structures. We, therefore, used ground-penetrating radar data to investigate the thermal structure and drainage system of Waldemarbreen in Svalbard: a small High Arctic glacier believed to be undergoing thermal change. We found that Waldemarbreen retains up to 80 m of temperate ice in its upper reaches, but this thickness most likely is a relict from the Little Ice Age when greater ice volumes were insulated from winter cooling and caused greater driving stresses. Since then, negative mass balance and firn loss have prevented latent heat release and allowed near-surface ice temperatures to cool in winter, thus reducing the thickness of the temperate ice. Numerous reflectors that can be traced up-glacier are interpreted as englacial channels formed by hydrofracturing in the crevassed upper region of the glacier. The alternative cut and closure mechanism of conduit initiation only forms conduits in parts of the lower ablation area. Consequently, Waldemarbreen provides evidence that hydrofracturing at higher elevations can play a major role in englacial water drainage through cold ice.


1995 ◽  
Vol 21 ◽  
pp. 59-63 ◽  
Author(s):  
Clinton M. Rowe ◽  
Mark R. Anderson ◽  
Thomas L. Mote ◽  
Karl C. Kuivinen

During the summer of 1993, a field program was conducted to collect several shallow firn cores from two locations in the southern region of the Greenland ice sheet. Stratigraphic evidence of melt from these cores was used for comparison with satellite-derived indications of melt.The shallow firn cores were examined for stratigraphic evidence of past melt events and were sampled for oxygen-isotope analysis to delineate the annual accumulation layers in the snowpack. The relative intensity of each year’s summer melt episode was compared to the corresponding melt frequency derived from microwave emissions. This comparison demonstrates that a linkage between the stratigraphic record and microwave data can be established. Both data sets indicate that there was less melt during the late 1970s and early 1980s than during the late 1980s, in general agreement with climate observations.


2006 ◽  
Vol 43 ◽  
pp. 177-186 ◽  
Author(s):  
Kumiko Goto-Azuma ◽  
Roy M. Koerner ◽  
Michael N. Demuth ◽  
Okitsugu Watanabe

AbstractThree ice cores were recovered on or near Mount Logan, Yukon, Canada, at 3017, 4135 and 5340 ma.s.l. in 2002. Prior to ice-core drilling, we collected snow-pit and shallow core samples from Mount Logan in 2001 to study seasonal and spatial variations of snow chemistry. We dug snow pits at six sites between 2420 and 5340 m a.s.l. before the beginning of the melt season, with the exception of a pit at 3180 m a.s.l., where the melt season had just started but had affected only the near-surface stratigraphy. Three of the pits were extended deeper with a shallow core. The snow-pit and core samples were analyzed for ion chemistry and δ18O. A series of depth profiles of ions and δ18O shows spatial variations, though characteristic peaks can usually be traced across all the profiles. Concentrations and deposition fluxes of Na+ and Cl−, which are mainly of sea-salt origin, decrease with altitude. On the other hand, deposition fluxes of NO3−, SO42–, Ca2+ and NH4+ show a weak positive relationship with elevation below the summit plateau. Stable isotopes (δ18O) decrease with altitude, with a distinctive jump between 3200 and 4500 m a.s.l., as was reported previously. Stable isotopes (δ18O), Cl−, CH3SO3− (MSA), Na+ and Ca2+ show clear seasonal variations, which would enable us to date the cores by annual-layer counting.


2013 ◽  
Vol 164 (1) ◽  
pp. 70-82 ◽  
Author(s):  
Sisinthy Shivaji ◽  
Zareena Begum ◽  
Singireesu Soma Shiva Nageswara Rao ◽  
Puram V. Vishnu Vardhan Reddy ◽  
Poorna Manasa ◽  
...  

2004 ◽  
Vol 39 ◽  
pp. 495-500 ◽  
Author(s):  
Mauro Guglielmin ◽  
Hugh M. French

AbstractThis progress report classifies the different types of ground-ice bodies that occur in the Northern Foothills, northern Victoria Land, Antarctica. Oxygen isotope variations are presented, but interpretation is kept to a minimum pending further investigations. Surface ice, as distinct from moving glacier ice, occurs in the form of widespread buried (‘dead’) glacier ice lying beneath ablation (sublimation) till, together with perennial lake ice, snow banks and icing-blister ice.’Dry’ permafrost is uncommon, and interstitial ice is usually present at the base of the active layer and in the near-surface permafrost. This probably reflects the supply of moisture from the Ross Sea and limited sublimation under today’s climate. Intrusive ice occurs as layers within perennial lake-ice covers and gives rise to small icing blisters. Small ice wedges found beneath the furrows of high-centered polygons appear to agree with the model of sublimation-till development proposed by Marchant and others (2002).


2013 ◽  
Vol 6 (8) ◽  
pp. 2027-2041 ◽  
Author(s):  
P. Sperlich ◽  
C. Buizert ◽  
T. M. Jenk ◽  
C. J. Sapart ◽  
M. Prokopiou ◽  
...  

Abstract. Air bubbles in ice core samples represent the only opportunity to study the mixing ratio and isotopic variability of palaeoatmospheric CH4 and N2O. The highest possible precision in isotope measurements is required to maximize the resolving power for CH4 and N2O sink and source reconstructions. We present a new setup to measure δ13C-CH4, δ15N-N2O and δ18O-N2O isotope ratios in one ice core sample and with one single IRMS instrument, with a precision of 0.09, 0.6 and 0.7‰, respectively, as determined on 0.6–1.6 nmol CH4 and 0.25–0.6 nmol N2O. The isotope ratios are referenced to the VPDB scale (δ13C-CH4), the N2-air scale (δ15N-N2O) and the VSMOW scale (δ18O-N2O). Ice core samples of 200–500 g are melted while the air is constantly extracted to minimize gas dissolution. A helium carrier gas flow transports the sample through the analytical system. We introduce a new gold catalyst to oxidize CO to CO2 in the air sample. CH4 and N2O are then separated from N2, O2, Ar and CO2 before they get pre-concentrated and separated by gas chromatography. A combustion unit is required for δ13C-CH4 analysis, which is equipped with a constant oxygen supply as well as a post-combustion trap and a post-combustion GC column (GC-C-GC-IRMS). The post-combustion trap and the second GC column in the GC-C-GC-IRMS combination prevent Kr and N2O interferences during the isotopic analysis of CH4-derived CO2. These steps increase the time for δ13C-CH4 measurements, which is used to measure δ15N-N2O and δ18O-N2O first and then δ13C-CH4. The analytical time is adjusted to ensure stable conditions in the ion source before each sample gas enters the IRMS, thereby improving the precision achieved for measurements of CH4 and N2O on the same IRMS. The precision of our measurements is comparable to or better than that of recently published systems. Our setup is calibrated by analysing multiple reference gases that were injected over bubble-free ice samples. We show that our measurements of δ13C-CH4 in ice core samples are generally in good agreement with previously published data after the latter have been corrected for krypton interferences.


1980 ◽  
Vol 25 (91) ◽  
pp. 69-84 ◽  
Author(s):  
Lonnie G. Thompson

AbstractGlaciological results of the continuing investigations of the Quelccaya ice cap located at lat. 13° 56’ S., long. 70° 50’ W., in the Cordillera Oriental of southern Peru are presented. Ice cores to a depth of 15 m have been retrieved from the summit dome (5650 m), middle dome (5543 m), and south dome (5480 m) and sampled in detail for microparticle, oxygen-isotope, and total-β-activity measurements. Results of these core analyses indicate that although the summit of this ice cap is only 300 m above the annual snow line and the firn is temperate, an interpretable stratigraphic record is preserved. The marked seasonal ice stratigraphy is produced by the marked seasonal variation in regional precipitation. High concentrations of microparticles and β- radioactive material occur during the dry season (May-August). Microparticles deposited during the rainy season are larger than those deposited during the dry season. On the Quelccaya ice cap the most negative δ18O values occur during the warmer rainy season (the opposite occurs in polar regions). The near-surface mean δ value of – 21‰ is remarkably low for this tropical site where the measured mean annual air temperature is – 3°C The seasonality of the microparticles, total β activity, and isotope ratios offers the prospect of a climatic ice-core record from this tropical ice cap.


2016 ◽  
Vol 62 (234) ◽  
pp. 714-724 ◽  
Author(s):  
SHELLEY MACDONELL ◽  
MARTIN SHARP ◽  
SEAN FITZSIMONS

ABSTRACTCryoconite holes can be important sources and stores of water and nutrients on cold and polythermal glaciers, and they provide a habitat for various forms of biota. Understanding the hydrological connectivity of cryoconite holes may be the key to understanding the transport of nutrients and biological material to the proglacial areas of such glaciers. This paper aims to characterize and explain spatial variability in the connectivity of ice-lidded cryoconite holes on a small, piedmont glacier in the McMurdo Dry Valleys through geochemical analysis of cryoconite hole waters. Solute concentrations in both surface and near-surface ice and cryoconite holes, vary greatly along the glacier centerline, and all sample types displayed similar spatial patterns of variability. Using chloride as a tracer, we estimated variations in cryoconite hole connectivity along the glacier centerline. We found that a previously used mass transfer method did not provide reliable estimates of the time period for which cryoconite hole waters had been isolated from the atmosphere. We attribute this to spatial variability in both the chloride content of the surface ice and surface ablation rates. The approach may, however, be used to qualitatively characterize spatial variations in the hydrological connectivity of the cryoconite holes. These results also suggest that ice-lidded cryoconite holes are never truly isolated from the near-surface drainage system.


2012 ◽  
Vol 58 (207) ◽  
pp. 99-109 ◽  
Author(s):  
Seth Campbell ◽  
Karl Kreutz ◽  
Erich Osterberg ◽  
Steven Arcone ◽  
Cameron Wake ◽  
...  

AbstractWe used ground-penetrating radar (GPR), GPS and glaciochemistry to evaluate melt regimes and ice depths, important variables for mass-balance and ice-volume studies, of Upper Yentna Glacier, Upper Kahiltna Glacier and the Mount Hunter ice divide, Alaska. We show the wet, percolation and dry snow zones located below ~2700ma.s.l., at ~2700 to 3900ma.s.l. and above 3900ma.s.l., respectively. We successfully imaged glacier ice depths upwards of 480 m using 40-100 MHz GPR frequencies. This depth is nearly double previous depth measurements reached using mid-frequency GPR systems on temperate glaciers. Few Holocene-length climate records are available in Alaska, hence we also assess stratigraphy and flow dynamics at each study site as a potential ice-core location. Ice layers in shallow firn cores and attenuated glaciochemical signals or lacking strata in GPR profiles collected on Upper Yentna Glacier suggest that regions below 2800ma.s.l. are inappropriate for paleoclimate studies because of chemical diffusion, through melt. Flow complexities on Kahiltna Glacier preclude ice-core climate studies. Minimal signs of melt or deformation, and depth-age model estimates suggesting ~4815 years of ice on the Mount Hunter ice divide (3912ma.s.l.) make it a suitable Holocene-age ice-core location.


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