scholarly journals Boron Removal Using Li-Al-OH Layered Double Hydroxide Prepared by One-Step Mechanochemical Approach

2018 ◽  
Author(s):  
Jingjing Tian ◽  
Jun Qu ◽  
Lei Wan ◽  
Qiwu Zhang ◽  
Huimin Gao
Keyword(s):  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Physical Adsorption ◽  
Molar Ratio ◽  
Mechanochemical Reaction ◽  
Boron Uptake ◽  
Dry Grinding ◽  
One Step ◽  
Double Hydroxide ◽  
Boron Adsorption

In this study, Li-Al-OH layered double hydroxide (LDH), which was prepared by solvent-free one-step mechanochemical reaction of LiOH and Al(OH)3, was applied to remove boron from aqueous solution. Dry-grinding for 3 h at a rotational speed of 500 rpm, Li/Al molar 1/2 was the optimum condition to prepare highly crystalline of Li-Al LDH phase with no evident impure phases. Two milling products with Li/Al molar ratio at 1/2 and 2/2 were evaluated for boron adsorption. The results confirmed that Li/Al molar ratio 2/2 sample showed high boron adsorption capacity due to the physical adsorption of Li-Al-OH LDH and chemical synergism of phase gel Al(OH)3. The adsorption isotherms, described by the Langmuir model, indicated maximum monolayer boron uptake capacity 45.45 mg/g, implying competitive adsorption capacity of the material in our experiment.

scholarly journals Mg-Cr Layered Double Hydroxide Intercalated Oxalic Anion to Remove Cationic Dye Solutions: Rhodamine B and Methylene Blue

2020 ◽  
Vol 9 (2) ◽  
pp. 383-391
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Rhodamine B ◽  
Physical Adsorption ◽  
Dye Adsorption ◽  
Kinetic Studies ◽  
Economic Feasibility ◽  
Order Kinetic ◽  
Double Hydroxide

A MgCr-based layered double hydroxide (LDH) was synthesized by a coprecipitation method, followed by an intercalation process using an oxalic anion. The materials were characterized using X-ray diffraction analysis, FT-IR spectroscopy, and pH pzc measurement. The materials were then applied as adsorbents for removal of methylene blue (MB) and rhodamine B (RhB) from aqueous solution. Pristine Mg/Cr LDH exhibited RhB adsorption capacity of 32.154 mg g⁻1, whereas the use of intercalated Mg/Cr LDH caused an increase in the capacity (139.526 mg g⁻1). Kinetic studies indicated that the dye adsorption using both LDHs followed a pseudo-second-order kinetic model; the K2 values of pristine and modified Mg/Cr LDH for RhB and MB were 6.970, 0.001, 0.426, and 2.056 g mg⁻1 min⁻1, respectively. The thermodynamic study identified that the adsorption of both dyes onto the LDHs was a spontaneous process and can be classified as physical adsorption with adsorption energies of <40 kJ/mol. Moreover, the desorption and regeneration experiments indicated the high economic feasibility and reusability of the LDHs. By using HCl as the optimal solvent, the LDHs could desorb as much as 98% of the dye and could be used as adsorbents with high adsorption capacity over three cycles.

scholarly journals Mg-Cr Layered Double Hydroxide with Intercalated Oxalic Anion for Removal Cationic Dyes Rhodamine B and Methylene Blue

2020 ◽  
Vol 9 (1) ◽  
pp. 85-94
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Rhodamine B ◽  
Physical Adsorption ◽  
Dye Adsorption ◽  
Kinetic Studies ◽  
Economic Feasibility ◽  
Order Kinetic ◽  
Double Hydroxide

A MgCr-based layered double hydroxide (LDH) was synthesized by a coprecipitation method, followed by an intercalation process using an oxalic anion. The materials were characterized using X-ray diffraction analysis, FT-IR spectroscopy, and pH pzc measurement. The materials were then applied as adsorbents for removal of methylene blue (MB) and rhodamine B (RhB) from aqueous solution. Pristine Mg/Cr LDH exhibited RhB adsorption capacity of 32.154 mg g⁻1, whereas the use of intercalated Mg/Cr LDH caused an increase in the capacity (139.526 mg g⁻1). Kinetic studies indicated that the dye adsorption using both LDHs followed a pseudo-second-order kinetic model; the K2 values of pristine and modified Mg/Cr LDH for RhB and MB were 6.970, 0.001, 0.426, and 2.056 g mg⁻1 min⁻1, respectively. The thermodynamic study identified that the adsorption of both dyes onto the LDHs was a spontaneous process and can be classified as physical adsorption with adsorption energies of <40 kJ/mol. Moreover, the desorption and regeneration experiments indicated the high economic feasibility and reusability of the LDHs. By using HCl as the optimal solvent, the LDHs could desorb as much as 98% of the dye and could be used as adsorbents with high adsorption capacity over three cycles.

scholarly journals Ni/Cr-[α-SiW12O40] Layered Double Hydroxide as Effective Adsorbent of Iron(II) From Aqueous Solution

2021 ◽  
Vol 23 (2) ◽  
pp. 103
Author(s):  
A. Lesbani ◽  
M.F. Azmi ◽  
N.R. Palapa ◽  
T. Taher ◽  
R. Andreas ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Interlayer Space ◽  
Physical Adsorption ◽  
High Surface ◽  
High Surface Area ◽  
X Ray ◽  
Endothermic Process ◽  
Double Hydroxide

Layered double hydroxide (LDH) Ni/Cr intercalated [α-SiW12O40]4- has been prepared using the coprecipitation method. Materials were characterized by X-ray, FTIR, BET, and pHpzc analyses. Material Ni/Cr-[α-SiW12O40] LDHs exhibited a high surface area 98.986 m2 g-1 from 11.030 m2 g-1 for Ni/Cr LDH where the interlayer space was an increase from 7.99 to 10.87 Å with indicated that high crystallinity. Ni/Cr-[α-SiW12O40] LDHs showed higher adsorption capacity for iron(II) is up to 250 mg g-1. Adsorption of iron(II) on LDHs has an endothermic process and classify as physical adsorption.

Removal of C. I. Reactive Red 2 from Aqueous Solution by Ni-Al Layered Double Hydroxide

2011 ◽  
Vol 148-149 ◽  
pp. 1276-1279 ◽  
Author(s):  
Li Fang Zhang
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data ◽  
Double Hydroxide ◽  
Reactive Red 2

In this study, the adsorption of C. I. Reactive Red 2 from aqueous solution on Ni-Al layered double hydroxide (LDH) was investigated in a batch system. The effect of Ni-Al molar ratio, pH, temperature and initial dye concentration on adsorption of the dye was carried out. The results showed that Ni-Al layered double hydroxide had higher capacity of removal of the dye. Ni-Al LDH with Ni-Al molar ratio of 3 exhibited the maximum dye removal at pH 4.0. Adsorption capacity of dye increased with increasing temperature or initial dye concentration. It was found that the adsorption equilibrium data followed the Langmuir adsorption model. The maximum adsorption capacity obtained from the Langmuir equation at temperature of 30°C was 333.3mg/g (R2=0.991) for the dye.

Adsorption of Dye from Aqueous Solution by Zn-Al Calcined Layered Double Hydroxide

2011 ◽  
Vol 287-290 ◽  
pp. 390-393
Author(s):  
Li Fang Zhang ◽  
Ying Ying Chen
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Equilibrium Data ◽  
Calcined Layered Double Hydroxide ◽  
Ph Range ◽  
Double Hydroxide

The adsorption of C. I. Reactive Red 2 from aqueous solution on Zn-Al calcined layered double hydroxide (CLDH) was investigated. Experiments were carried out as a function of Zn-Al molar ratio, contact time, pH, temperature and initial dye concentration. The results showed that Zn-Al calcined layered double hydroxide had higher capacity of removal of the dye. Zn-Al CLDH with Zn-Al molar ratio of 3 and with pH range of 4.0-8.0 was found to be optimal for dye removal. Adsorption capacity of dye decreased with increasing temperature and increased with increasing initial dye concentration. It was found that the adsorption equilibrium data followed the Langmuir adsorption model. The maximum adsorption capacity obtained from the Langmuir equation at temperature of 30°C was 116.28mg/g (R2=0.9992) for the dye.

Hierarchically porous FeNi3@FeNi layered double hydroxide nanostructures: One-step fast electrodeposition and highly efficient electrocatalytic performances for overall water splitting

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hierarchically Porous ◽  
One Step ◽  
Double Hydroxide

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...

scholarly journals One-step synthesis of nitrogen-grafted copper-gallic acid for enhanced methylene blue removal

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Shella Permatasari Santoso ◽  
Vania Bundjaja ◽  
Artik Elisa Angkawijaya ◽  
Chintya Gunarto ◽  
Alchris Woo Go ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Adsorption Capacity ◽  
Gallic Acid ◽  
Synthesis Method ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
One Step ◽  
Detailed Assessment ◽  
Higher Temperature

AbstractNitrogen-grafting through the addition of glycine (Gly) was performed on a metal- phenolic network (MPN) of copper (Cu2+) and gallic acid (GA) to increase its adsorption capacity. Herein, we reported a one-step synthesis method of MPN, which was developed according to the metal–ligand complexation principle. The nitrogen grafted CuGA (Ng-CuGA) MPN was obtained by reacting Cu2+, GA, and Gly in an aqueous solution at a molar ratio of 1:1:1 and a pH of 8. Several physicochemical measurements, such as Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), N2 sorption, X-ray diffraction (XRD), and thermal gravimetry analysis (TGA), were done on Ng-CuGA to elucidate its characteristics. The analysis revealed that the Ng-CuGA has non-uniform spherical shaped morphology with a pore volume of 0.56 cc/g, a pore size of 23.25 nm, and thermal stability up to 205 °C. The applicational potential of the Ng-CuGA was determined based on its adsorption capacity against methylene blue (MB). The Ng-CuGA was able to adsorb 190.81 mg MB per g adsorbent at a pH of 6 and temperature of 30 °C, which is 1.53 times higher than the non-grafted CuGA. Detailed assessment of Ng-CuGA adsorption properties revealed their pH- and temperature-dependent nature. The adsorption capacity and affinity were found to decrease at a higher temperature, demonstrating the exothermic adsorption behavior.

One-Step Synthesis of Shelled PbS Nanoparticles in a Layered Double Hydroxide Matrix.

ChemInform ◽  
2004 ◽  
Vol 35 (51) ◽  
Author(s):  
Alexey V. Lukashin ◽  
Andrei A. Eliseev ◽  
Natalya G. Zhuravleva ◽  
Alexey A. Vertegel ◽  
Yuri D. Tretyakov ◽  
...  
Keyword(s):  
Layered Double Hydroxide ◽  
Pbs Nanoparticles ◽  
One Step ◽  
Double Hydroxide
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