scholarly journals Migration of Natural Hydrogen from Deep-seated Sources in the São Francisco Basin, Brazil

2020 ◽  
Author(s):  
Frederic Victor Donze ◽  
Laurent Truche ◽  
Parisa Sheraki Namin ◽  
Nicolas Lefeuvre ◽  
Elena Bazarkina
Keyword(s):  
Geothermal Gradient ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Production Model ◽  
Fault System ◽  
Short Time Scale ◽  
Seismic Profiles ◽  
Deep Faults ◽  
Measurement Methodology ◽  
High Geothermal Gradient

Hydrogen gas is seeping from the sedimentary basin of São Franciso, Brazil. The seepages of H2 are accompanied by helium whose isotopes reveal a strong crustal signature. Geophysical data indicates that this intra-cratonic basin is characterized by i) a relatively high geothermal gradient, ii) deep faults delineating a horst and graben structure and affecting the entire sedimentary sequence, iii) an archean to paleoproterozoïc basements enriched in radiogenic elements and displaying mafic and ultramafic units, and iv) a possible karstic reservoir located 400 m below the surface. The high geothermal gradient could be due to a thin lithosphere enriched in radiogenic elements, which can also contribute to a massive radiolysis process of water at depth, releasing an important amount of H2. Alternatively, ultramafic rocks that may have generated H2 during their serpentinization are also documented in the basement. The seismic profiles show that the faults seen at the surface are deeply rooted in the basement, and can drain deep fluids to shallow depths in a short time scale. The carbonate reservoirs within the Bambuí group which forms the main part of the sedimentary layers are crossed by the fault system and represent good candidates for temporary H2 accumulation zones. The formation by chemical dissolution of sinkholes located at 400 m depth might explain the presence of sub-circular depressions seen at the surface. These sinkholes might control the migration of gas from temporary storage reservoirs in the upper layer of the Bambuí formation to the surface. The very high fluxes of H2 escaping out of these structures which have been recently documented are, however, in disagreement with the newly developed H2 production model in the Precambrian continental crust. They either question the validity of these models or the measurement methodology.

scholarly journals Migration of Natural Hydrogen from Deep-Seated Sources in the São Francisco Basin, Brazil

Geosciences ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 346 ◽  
Author(s):  
Frédéric-Victor Donzé ◽  
Laurent Truche ◽  
Parisa Shekari Namin ◽  
Nicolas Lefeuvre ◽  
Elena F. Bazarkina
Keyword(s):  
Geothermal Gradient ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Production Model ◽  
Fault System ◽  
Short Time Scale ◽  
Seismic Profiles ◽  
Deep Faults ◽  
Short Time ◽  
High Geothermal Gradient

Hydrogen gas is seeping from the sedimentary basin of São Franciso, Brazil. The seepages of H2 are accompanied by helium, whose isotopes reveal a strong crustal signature. Geophysical data indicates that this intra-cratonic basin is characterized by (i) a relatively high geothermal gradient, (ii) deep faults delineating a horst and graben structure and affecting the entire sedimentary sequence, (iii) archean to paleoproterozoïc basements enriched in radiogenic elements and displaying mafic and ultramafic units, and (iv) a possible karstic reservoir located 400 m below the surface. The high geothermal gradient could be due to a thin lithosphere enriched in radiogenic elements, which can also contribute to a massive radiolysis process of water at depth, releasing a significant amount of H2. Alternatively, ultramafic rocks that may have generated H2 during their serpentinization are also documented in the basement. The seismic profiles show that the faults seen at the surface are deeply rooted in the basement, and can drain deep fluids to shallow depths in a short time scale. The carbonate reservoirs within the Bambuí group which forms the main part of the sedimentary layers, are crossed by the fault system and represent good candidates for temporary H2 accumulation zones. The formation by chemical dissolution of sinkholes located at 400 m depth might explain the presence of sub-circular depressions seen at the surface. These sinkholes might control the migration of gas from temporary storage reservoirs in the upper layer of the Bambuí formation to the surface. The fluxes of H2 escaping out of these structures, which have been recently documented, are discussed in light of the newly developed H2 production model in the Precambrian continental crust.

PERLAKUAN ETHYL METHANE SULFONATE (EMS) PADA ENTEROBACTER AEROGENES AY-2 DARI LIMBAH METAN FERMENTASI UNTUK PENINGKATAN PRODUKSI GAS HIDROGEN

2018 ◽  
Vol 5 (1) ◽  
Author(s):  
Mahyudin Abdul Rachman
Keyword(s):  
Metabolic Pathway ◽  
Acid Production ◽  
Double Mutant ◽  
Enterobacter Aerogenes ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Survival Ratio ◽  
Ethyl Methane Sulfonate ◽  
Methane Sulfonate ◽  
Ethyl Methane

Enterobacter aerogenes AY-2 mutant is known for hydrogen gas producer which ws obtained from the sludge of methane fermentation and the yield is 1.5 fold higher than wildtype. Hydrogen gas production can be gain via NADH oxidation in anaerobic metabolic pathway by blocking organic acid production. Metabolic pathway can be changed by mutagenesis. Enterobacter aerogenes AY-2 mutated with ethyl methane sulfonate in logarithmic phase with consentration 10, 11, 12, 13, 14 and 15 μl/ml cell suspention during 120 minute. Mutation that result lowest survival ratio (0,01%) was 14 μl EMS/ml cell suspention is repeated with variation incubation time, 30, 60, 90 and 120 minute. 166 double mutant colony has been collected and choosen randomly. The choosen 43 colony was fermented in glycerol complex medium for determining ten double mutant with the highest H2 production. Double mutant AD-H43 is a highest H2 producer that increase 20% H2 production from AY-2 and has a decrease lactid acid production, 31% less from AY-2. Increasing H2 production in double mutant AD-H43 is caused by lactate dehydrogenase deffi cient.Keywords: Enterobacter aerogenes AY-2, ethyl methane sulfonate (EMS), H2 and methane sludge

Generation of high-pH groundwaters and H2 gas by groundwater–kimberlite interaction, northeastern Ontario, Canada

2021 ◽  
Vol 59 (5) ◽  
pp. 1261-1276
Author(s):  
Jamil A. Sader ◽  
Anna L. Harrison ◽  
M. Beth McClenaghan ◽  
Stewart M. Hamilton ◽  
Ian D. Clark ◽  
...  
Keyword(s):  
Inorganic Carbon ◽  
Meteoric Water ◽  
Dissolved Inorganic Carbon ◽  
Carbon Sink ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Isotopic Data ◽  
Northern Ontario ◽  
Ch4 Production ◽  
High K

ABSTRACT We report new isotopic data for H2 and CH4 gases and Sr for groundwater collected from Jurassic Kirkland Lake kimberlites in northern Ontario, Canada. Groundwaters interacting with kimberlites have elevated pH (up to 12.4), are reducing (Eh as low as the H2-H2O couple), are dominated by OH− alkalinity, and have non-radiogenic (mantle) 87Sr/86Sr values (∼0.706–0.707). Most significantly, the highest pH groundwaters have low Mg, high K/Mg, and are associated with abundant reduced gases (H2 ± CH4). Open system conditions favor higher dissolved inorganic carbon and CH4 production, whereas under closed system conditions low DIC, elevated OH− alkalinity, and H2 production are enhanced. Hydrogen gas is isotopically depleted (δ2HH2 = −771 to −801‰), which, combined with δ2HH2O, yields geothermometry temperatures of serpentinization of 5–25 °C. Deviation of H2-rich groundwaters (by up to 10‰) from the meteoric water line is consistent with Rayleigh fractionation during reduction of water to H2. Methane is characterized by δ13CCH4 = −35.8 to −68‰ and δ2HCH4 = −434‰. The origin of CH4 is inconclusive and there is evidence to support both biogenic and abiogenic origins. The modeled groundwater–kimberlite reactions and production of elevated concentrations of H2 gas suggest uses for diamond-production tailings, as a source of H2 for fuel cells and as a carbon sink.

scholarly journals Audiomagnetotelluric survey at the Bañitos-Gollete geothermal area, main Andes Cordillera of San Juan, Argentina.

2019 ◽  
Author(s):  
H. BARCELONA ◽  
G. PERI ◽  
D. WINOCUR ◽  
A. FAVETTO
Keyword(s):  
Geothermal Gradient ◽  
Geothermal Field ◽  
Flow Path ◽  
Fault System ◽  
Conductive Heat ◽  
Exploration Process ◽  
Tectonic Environment ◽  
Geothermal Potential ◽  
Geologic Setting ◽  
Andes Cordillera

The present research explores the Bañitos-Gollete geothermal field located in the Frontal Andes Cordillera over the Pampean flat-slab. We carried out an audiomagnetotelluric survey in order to define the underground geoelectrical structure and to understand the link between the geothermal fluid flow path and the main geological structures. 2-D audiomagnetotelluric models suggest that the deep-rooted N-S fault system controls the geothermal flow path. We propose a conductive heat-driven system, taking into consideration the geologic setting and the supposed low geothermal gradient of this tectonic environment. The mature Na-Cl waters from Gollete and an estimated reservoir temperature of ~140ºC are consistent with this conceptual model. Further investigations are required to assess the geothermal potential of the study area, and the present work likely represents only the first but necessary step in the exploration process.

Hydrogen-rich water-alleviated ultraviolet-B-triggered oxidative damage is partially associated with the manipulation of the metabolism of (iso)flavonoids and antioxidant defence in Medicago sativa

2015 ◽  
Vol 42 (12) ◽  
pp. 1141 ◽  
Author(s):  
Yanjie Xie ◽  
Wei Zhang ◽  
Xingliang Duan ◽  
Chen Dai ◽  
Yihua Zhang ◽  
...  
Keyword(s):  
Oxidative Damage ◽  
Medicago Sativa ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Ultraviolet B ◽  
In Vitro Tests ◽  
Antioxidant Defence ◽  
Experimental Conditions ◽  
Uvb Irradiation

External administration of hydrogen gas (H2) benefits plants from multiple environmental stimuli. However, the physiological significance and molecular mechanism of H2 in ultraviolet-B (UVB) irradiation are largely unexplored. Here, the biological function of H2 in the regulation of plant UVB-tolerance was investigated by using hydrogen-rich water (HRW). Results showed that the exposure of alfalfa seedlings to UVB irradiation increased endogenous H2 production. Pretreatment with HRW mimicked the UVB-induced endogenous H2 production. Corresponding UVB-triggered toxic symptoms, in terms of lipid peroxidation and overproduction of reactive oxygen species (ROS), as well as the subsequent growth inhibition, were markedly mitigated. Metabolic profiling analysis by using ultra performance liquid chromatography-mass spectrometric (UPLC-MS), identified 40 (iso)flavonoids in UVB-treated alfalfa plants, with 22 kinds was increased by HRW. These changes resulted in the alternation of (iso)flavonoids profile, with the effective promotion of isoflavone and flavanone subfamilies in particular. These compounds included afromosin, afromosin 7-O-β-D-glucoside-malonate, daidzein, formononetin 7-O-β-D-glucoside-6ʹʹ-O-malonate, garbanzol, matteucin and naringenin. In vitro tests further showed that the HRW-modulated (iso)flavonoids profile upon UVB stress possessed advanced ROS-quenching and antioxidant capacities under our experimental conditions. Meanwhile, UVB-triggered upregulation in the transcription levels of (iso)flavonoids biosynthetic-related genes were substantially strengthened by HRW. The activities and related transcripts of representative antioxidant enzymes were also induced. Taken together, our findings indicate that HRW confers tolerance to UVB-induced oxidative damage partially by the manipulation of (iso)flavonoids metabolism and antioxidant defence in Medicago sativa L.

Integrated Geophysical Interpretation of Kerio Valley Basin Stratigraphy, Kenya Rift

2016 ◽  
Author(s):  
Godfred Osukuku ◽  
Abiud Masinde ◽  
Bernard Adero ◽  
Edmond Wanjala ◽  
John Ego
Keyword(s):  
Gravity Data ◽  
Gravity Anomalies ◽  
Fault System ◽  
Magnetic Data ◽  
Data Sets ◽  
Seismic Profiles ◽  
The West ◽  
Seismic Reflection Data ◽  
Basement Rocks ◽  
Western Side

Abstract This research work attempts to map out the stratigraphic sequence of the Kerio Valley Basin using magnetic, gravity and seismic data sets. Regional gravity data consisting of isotactic, free-air and Bouguer anomaly grids were obtained from the International Gravity Bureau (BGI). Magnetic data sets were sourced from the Earth Magnetic Anomaly grid (EMAG2). The seismic reflection data was acquired in 1989 using a vibrating source shot into inline geophones. Gravity Isostacy data shows low gravity anomalies that depict a deeper basement. Magnetic tilt and seismic profiles show sediment thickness of 2.5-3.5 Km above the basement. The Kerio Valley Basin towards the western side is underlain by a deeper basement which are overlain by succession of sandstones/shales and volcanoes. At the very top are the mid Miocene phonolites (Uasin Gishu) underlain by mid Miocene sandstones/shales (Tambach Formation). There are high gravity anomalies in the western and southern parts of the basin with the sedimentation being constrained by two normal faults. The Kerio Valley Basin is bounded to the west by the North-South easterly dipping fault system. Gravity data was significantly of help in delineating the basement, scanning the lithosphere and the upper mantle according to the relative densities. The basement rocks as well as the upper cover of volcanoes have distinctively higher densities than the infilled sedimentary sections within the basin. From the seismic profiles, the frequency of the shaley rocks and compact sandstones increases with depths. The western side of the basin is characterized by the absence of reflections and relatively higher frequency content. The termination of reflectors and the westward dip of reflectors represent a fault (Elgeyo fault). The reflectors dip towards the west, marking the basin as an asymmetrical syncline, indicating that the extension was towards the east. The basin floor is characterized by a nearly vertical fault which runs parallel to the Elgeyo fault. The seismic reflectors show marked discontinuities which may be due to lava flows. The deepest reflector shows deep sedimentation in the basin and is in reasonable agreement with basement depths delineated from potential methods (gravity and magnetic). Basement rocks are deeper at the top of the uplift footwall of the Elgeyo Escarpment. The sediments are likely of a thickness of about 800 M which is an interbed of sandstones and shales above the basement.

scholarly journals Workflow of Digital Field Mapping and Drone-Aided Survey for the Identification and Characterization of Capable Faults: The Case of a Normal Fault System in the Monte Nerone Area (Northern Apennines, Italy)

2020 ◽  
Vol 9 (11) ◽  
pp. 616
Author(s):  
Mauro De Donatis ◽  
Mauro Alberti ◽  
Mattia Cipicchia ◽  
Nelson Muñoz Guerrero ◽  
Giulio F. Pappafico ◽  
...  
Keyword(s):  
Central Italy ◽  
Three Dimensional ◽  
Normal Fault ◽  
Field Work ◽  
Digital Data ◽  
Fault System ◽  
Seismic Profiles ◽  
Postgraduate Students ◽  
Recent Earthquakes

Field work on the search and characterization of ground effects of a historical earthquake (i.e., the Cagli earthquake in 1781) was carried out using terrestrial and aerial digital tools. The method of capturing, organizing, storing, and elaborating digital data is described herein, proposing a possible workflow starting from pre-field project organization, through reiteration of field and intermediate laboratory work, to final interpretation and synthesis. The case of one of the most important seismic events in the area of the northern Umbria–Marche Apennines provided the opportunity to test the method with both postgraduate students and researchers. The main result of this work was the mapping of a capable normal fault system with a great number of observations, as well as a large amount of data, from difficult outcrop areas. A GIS map and a three-dimensional (3D) model, with the integration of subsurface data (i.e., seismic profiles and recent earthquake distribution information), allowed for a new interpretation of an extensional tectonic regime of this Apennines sector, similar to one of the southernmost areas of central Italy where recent earthquakes occurred on 2016.

Origin of grain-coating chlorite by smectite transformation: an example from Miocene sandstones, North Sumatra back-arc basin, Indonesia

Clay Minerals ◽  
1994 ◽  
Vol 29 (4) ◽  
pp. 681-692 ◽  
Author(s):  
B. Humphreys ◽  
S. J. Kemp ◽  
G. K. Lott ◽  
Bermanto ◽  
D.A. Dharmayanti ◽  
...  
Keyword(s):  
Geothermal Gradient ◽  
Upper Miocene ◽  
The North ◽  
Direct Precipitation ◽  
Back Arc ◽  
North Sumatra ◽  
Textural Evidence ◽  
High Geothermal Gradient

AbstractGrain-coating chlorite cements commonly occur within sandstones of late Middle and Upper Miocene age deposited in the North Sumatra back-arc basin. Chlorites from the Lower Keutapang Member contain Ca (maximum 0.75 wt% oxide) and show textural evidence for direct precipitation on grains. However, crystals are subhedral, showing curved faces and often ragged edges, and show a tendency to merge together. In overlying beds of the Upper Keutapang Member, grain-coating chlorite-smectite (20% smectite) cements display an identical morphology but are more siliceous, have a lower octahedral occupancy and contain higher total (Na + Ca + K). It is proposed that chlorite cements in the Keutapang Formation originated as smectite-rich cement rims whose initial precipitation was related to the breakdown of volcanic detritus in the sediments. Transformation to chlorite occurred subsequently during burial, facilitated by a high geothermal gradient in the back-arc basin.

Roles of hydrogen gas in plants: a review

2018 ◽  
Vol 45 (8) ◽  
pp. 783 ◽  
Author(s):  
Changxia Li ◽  
Tingyu Gong ◽  
Biting Bian ◽  
Weibiao Liao
Keyword(s):  
Anthocyanin Biosynthesis ◽  
Stomatal Closure ◽  
Adventitious Rooting ◽  
H2 Production ◽  
Hydrogen Gas ◽  
Anthocyanin Synthesis ◽  
Signalling Molecules ◽  
Positive Effects ◽  
Antioxidant Defence System ◽  
Future Work

Hydrogen gas (H2) was first identified as a unique molecular messenger in animals. Since H2 was reported as a novel antioxidant, it has been proven effective in treating many diseases. However, the studies concerning H2 in plants are just beginning to emerge. Here, two paths of H2 production in plants have been reported, namely, hydrogenase and nitrogenase. H2 has positive effects on seed germination, seedling growth, adventitious rooting, root elongation, harvest freshness, stomatal closure and anthocyanin synthesis. H2 also can enhance plant symbiotic stress resistance commonly through the enhancement of antioxidant defence system. Moreover, H2 shows cross talk with nitric oxide, carbon monoxide and other signalling molecules (for example, abscisic acid, ethylene and jasmonate acid). H2 can regulate the expression of responsive genes under abiotic stress and during adventitious roots formation and anthocyanin biosynthesis. Future work will need to focus on the molecular mechanism of H2 and its crosstalk with other signalling molecules in plants. With its promising application in agriculture, hydrogen agriculture will be welcomed in the near future.

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