A Novel and Comprehensive Study of Polymeric and Traditional Phosphonate Inhibitors for High-Temperature Scale Control

SPE Journal ◽  
2013 ◽  
Vol 18 (03) ◽  
pp. 575-582 ◽  
Author(s):  
Wei Wang ◽  
Amy T. Kan ◽  
Mason B. Tomson

Summary A novel barite-inhibition assay based on the nucleation and inhibition model has been proposed and used to evaluate the thermal stability of phosphonates and polymeric scale inhibitors with regard to their potential application in high-temperature wells. Systematic experiments have been conducted to investigate the time (minutes to days) and temperature (up to 200°C) dependence of inhibitor thermal degradation, the impact of stainless steel and iron on the degradation of inhibitors at high temperatures, and the difference between aging tests with inhibitors in solution and with those inhibitors adsorbed on core materials. The results not only enable a more accurate understanding of the thermal degradation of scale inhibitors but also facilitate the selection and placement of scale inhibitors for high-temperature oil and gas production.

SPE Journal ◽  
2012 ◽  
Vol 17 (01) ◽  
pp. 177-186 ◽  
Author(s):  
C.. Fan ◽  
W.. Shi ◽  
P.. Zhang ◽  
H.. Lu ◽  
N.. Zhang ◽  
...  

Summary Scale control in deepwater oil and gas production is often challenging not only because of the geological and mechanical limitations associated with deepwater wells, but also because of the high-temperature (>150°C) and high-pressure (>10,000 psi) (HT/HP) environment, which may be associated with brine containing high total dissolved solids (TDSs) (>300,000 mg/L). These extreme conditions make scale prediction, control, and testing difficult because of the requirements for special alloys, pumps, and control equipment that are not readily available. Therefore, few reliable ultrahigh-temperature/ultrahigh-pressure (ultra-HT/HP) data are available. To overcome such challenges, an efficient flow-loop method has been established to study both the equilibrium and the kinetics of scale formation and inhibition at ultra-HT/HP conditions. This paper will discuss (1) an efficient flow-loop method to study the solubility of scale minerals at ultra-HT/HP conditions, (2) solubility of barite at temperature up to 200°C and pressure up to 20,000 psi, and (3) scale control and inhibitor selection for deepwater oil and gas production at ultra-HT/HP conditions. Specifically, the performance and thermal stability of some common scale inhibitors at the high-temperature conditions were studied in terms of barite-scale inhibition. The results to date indicated that (1) the solubility of barite at up to 200°C and 24,000 psi can be measured precisely by this newly developed flow-loop apparatus, (2) the rate of mineral scale formation at HT/HP may be considerably faster than previously projected from low-temperature studies and, hence, difficult to inhibit, (3) different scale inhibitors have shown considerably different thermal stability. The results and findings from these studies validate a new HT/HP apparatus for scale and inhibitor testing and information for better scale control at HT/HP conditions.


SPE Journal ◽  
2014 ◽  
Vol 19 (06) ◽  
pp. 1169-1176 ◽  
Author(s):  
Wei Wang ◽  
Amy T. Kan ◽  
Fangfu Zhang ◽  
Chao Yan ◽  
Mason B. Tomson

Summary As the oil and gas industry is making firm strides in deepwater and shale exploration and development, possible thermal degradation of scale-inhibitor molecules poses a great challenge for scaling control and flow assurance for high-temperature reservoirs. Although extensive research has been conducted to test thermal stability of scale inhibitors, little work has been devoted to study the thermodynamics/kinetics of thermal degradation of scale inhibitors. In this work, a novel and efficient testing approach based on inhibition kinetics has been developed and successfully applied to determine the fraction of the active inhibitor molecules in preheated samples of scale inhibitors with various generic chemistries. Moreover, for the first time, we have modeled the kinetics of inhibitor thermal degradation on the basis of the integrated first-order rate equation and Arrhenius equation, with good agreements between the model predictions and experimental data. The preheated scale inhibitors have been analyzed by nuclear-magnetic-resonance (NMR) spectroscopy for organic-compound characterization. Our results and predictions based on inhibition testing assay are consistent with the 31P/1H NMR analyses. This work has enabled an in-depth understanding of the time and temperature dependence of thermal degradation of scale inhibitors, and facilitates the rational selection and deployment of scale inhibitors for high-temperature oil and gas production.


Author(s):  
Trond G. Gru¨ner ◽  
Lars E. Bakken

The development of wet gas compressors will enable increased oil and gas production rates and enhanced profitable operation by subsea well-stream boosting. A more fundamental knowledge of the impact of liquid is essential with regard to the understanding of thermodynamic and fluid dynamic compressor behavior. An open-loop impeller test facility was designed to investigate the wet gas performance, aerodynamic stability, and operation range. The facility was made adaptable for different impeller and diffuser geometries. In this paper, the wet gas test facility and experimental work concerning the impact of wet gas on a representative full-scale industrial impeller are presented. The centrifugal compressor performance was examined at high gas volume fractions and atmospheric inlet conditions. Air and water were used as experimental fluids. Dry and wet gas performance was experimentally verified and analyzed. The results were in accordance with previous test data and indicated a stringent influence of the liquid phase. Air/water tests at atmospheric conditions were capable of reproducing the general performance trend of hydrocarbon wet gas compressor tests at high pressure.


Author(s):  
Kumarswamy Karpanan ◽  
Craig Hamilton-Smith

Subsea oil and gas production involves assemblies such as trees, manifolds, and pipelines that are installed on sea floor. Each of these components is exposed to severe working conditions throughout its operational life and is difficult and expensive to repair or retrieve installed. During installation and operation, a rig/platform and several supply vessels are stationed on the waterline directly above the well and installed equipment below. If any object is to be dropped overboard, it presents a hazard to the installed equipment. A subsea tree comprises of a number of critical components such as valves and hydraulic actuators, in addition to several electrical components such as the subsea control module and pressure/temperature gauges. Their ability to operate correctly is vital to the safe production of oil and gas. If an object were to impact and damage these components, resulting in their inability to operate as intended, the consequences could be severe. In this paper, a typical subsea tree frame is analyzed to ensure its ability to withstand the impact from an object accidentally dropped overboard. This was accomplished using nonlinear dynamic Finite Element Analysis (FEA). In this study, the framework was struck by a rigid body at terminal velocity, resulting in a given impact energy. Displacements and resultant strain values at critical locations were then compared to allowable limits to ensure compliance to the design requirements.


2019 ◽  
Vol 12 (3) ◽  
pp. 46-57 ◽  
Author(s):  
S. V. Kazantsev

The article presents the results of the author’s research of the impact of a wide range of restrictions and prohibitions applied to theRussian Federation, used by a number of countries for their geopolitical purposes and as a means of competition. The object of study was the impact of anti-Russian sanctions on the development of Oil & Gas industry and defence industry complex ofRussiain 2014–2016. The purpose of the analysis was to assess the impact of sanctions on the volume of oil and gas production, the dynamics of foreign earnings from the export of oil and gas, and of foreign earnings from the sale abroad of military and civilian products of the Russian defence industry complex (DIC). As the research method, the author used the economic analysis of the time series of statistical data presented in open statistics and literature. The author showed that some countries use the anti-Russian sanctions as a means of political, financial, economic, scientific, and technological struggle with the leadership ofRussiaand Russian economic entities. It is noteworthy that their introduction in 2014 coincided with the readiness of theUSto export gas and oil, which required a niche in the international energy market. The imposed sanctions have affected the volume of oil production inRussia, which was one of the factors of reduction of foreign earnings from the country’s oil and gas exports. However, the Russian defence industry complex has relatively well experienced the negative impact of sanctions and other non-market instruments of competition


2021 ◽  
Author(s):  
D. Nathan Meehan

Abstract Is this the end of petroleum engineering as we know it? This prescient question led to the most downloaded paper from onepetro.org in 2019. The events of 2020 resulted in massive layoffs, decreased hiring and many fewer students studying petroleum engineering. In the 2019 paper the authors claimed that the future would hold fewer petroleum engineering jobs and very different types of jobs. This paper incorporates a broader range of data and proposes some specific ways to improve prospects for the discipline of petroleum engineering. The opportunity for a near-term recovery is very high as the world overcomes COVID-19 issues, oil demand recovers and the impact of chronic underinvestment in oil and gas production looms. The world's largest producers have very different abilities to respond to a near-term uptick in demand. Energy transition pressures continue to cap growth in demand; however, demand for petroleum engineers is expected to grow under almost every scenario, but not to pre-2015 levels. Increased demand in CCUS and jobs that improve sustainability of oil and gas will continue to outpace conventional jobs. Data analytics will play an increasingly large role in engineering activities. The "Is it the end?" paper started with a question, a question that I first heard asked in 1977 at the SPE Annual Fall Technical Conference and Exhibition in Denver to 1972 SPE President M. Scott Kraemer. I have heard it many times since then and asked it many times. "Would you recommend that your son or daughter study petroleum engineering?" The answer to that question was pretty easy and unanimously positive in 1977. Keep this question in mind as we review what has happened since the prior paper came out.


Author(s):  
Ikenna A. Okaro ◽  
Longbin Tao

This paper describes how the operation of deep, subsea oil wells can be analyzed and optimized using artificial lift systems. A modest explanation was offered about an enhanced Hubbert model for determining production targets at pre-feed phase of project. In addition, the impact of artificial lifts on the economics of subsea wells facing hyperbolic production decline was illustrated. The principle of Nodal analysis was highlighted and applied to optimize a proposed subsea oil production case. Configurations of a nominally rated rod pump, a multiphase pump and an electrical submersible pump were modelled in a steady-state flow using Pipesim software and the simulated results which were functions of liquid flow rate and pressure distribution across the production system exposed the behavior of the system. The results showed that over 100% volumetric efficiency was achieved using a combination of electrical submersible pump at the bottom hole and a multiphase pump at riser base. A guide is presented on how to predict, analyze and enhance the recovery curve of subsea oil production using artificial lifts and nodal-system analysis. The benefit of this work is an enabling cost-effective approach for ensuring production assurance in deep water oil and gas production.


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