Effect of Fractional Flow Hysteresis on Recovery of Tertiary Oil

1980 ◽  
Vol 20 (06) ◽  
pp. 508-520 ◽  
Author(s):  
Robert E. Gladfelter ◽  
Surendra P. Gupta

Abstract This paper deals with the oil/water bank propagation in a tertiary oil recovery process. Oil/water bank propagation was studied in a series of laboratory micellar floods and simultaneous oil/water flow tests using a microwave scanning apparatus for measuring in-situ dynamic oil saturation. It was observed that a high oil saturation region, or hump, developed at the leading edge of the oil/water bank and grew linearly with distance. A lower steady-state oil saturation region was observed behind the hump. As the hump was produced from the core, high initial oil fractions were observed, as often seen in laboratory micellar floods. This is the result of the observed hysteresis in fractional flow behavior. A graphical method of predicting the occurrence of a hump, its rate of growth, and saturations within an oil/water bank was developed using the observed hysteresis in fractional flow. Using this prediction procedure, it was concluded that in a tertiary oil recovery process, oil breakthrough time or rate of advance of the oil/water bank, oil saturation at the leading edge, and initial produced oil fractions are only functions of the oil-saturation-increasing fractional flow curve and are not necessarily indications of oil recovery efficiency. Introduction During a tertiary oil recovery process, a small slug of displacing fluid (e.g., a micellar fluid) mobilizes residual oil and water and forms an oil/water bank. It is important to understand the propagation behavior of the oil/water bank in a tertiary oil recovery process since it affects the oil breakthrough time and initial oil cuts. This understanding also will aid in the interpretation of oil displacement tests. Moreover, oil breakthrough time and initial oil cuts have been used for judging the efficiency of a tertiary oil recovery process. Oil/water bank propagation was studied in a series of micellar floods and oil/water flow tests using a microwave scanning apparatus for measuring in-situ dynamic oil saturation profiles. Experimental Details The microwave scanning apparatus used is similar to that discussed by Parsons1 and Parsons and Jones.2 Microwaves are transmitted through a core where they are partially absorbed by the water molecules. The measured microwave power attenuation, or degree of absorption of the microwave energy, is a direct measure of the quantity of water and, consequently, of the oil saturation in an oil/water system since the oil does not absorb the microwave energy. The microwave scanning apparatus is capable of measuring the dynamic oil saturation profiles during pressure-monitored laboratory micellar floods and other oil/water flow tests. Fig. 1 is a schematic of the apparatus. Additional experimental details are given in Appendix A. Displacement tests were conducted at room temperature in 120-cm-long rectangular Berea cores (1.91 cm thick×7.62 cm wide). The brine permeability range of these cores was from 418 to 714 md, and pore volumes varied from 377 to 395 cm3. Three tertiary micellar floods were conducted in separate Berea cores with Second Wall Creek crude oil. Table 1 shows the fluid injection sequence and compositions3 for the micellar floods. In addition, simultaneous oil/water injection tests were conducted in separate Berea cores using both Second Wall Creek crude oil and refined oils (see Table 2 for the fluid injection sequence).

SPE Journal ◽  
2012 ◽  
Vol 17 (02) ◽  
pp. 340-351 ◽  
Author(s):  
E.. Ashoori ◽  
W.R.. R. Rossen

Summary Foam is a promising means of increasing sweep in miscible- and immiscible-gas enhanced oil recovery (EOR). Surfactant alternating gas (SAG) is a preferred method of injection. Numerous studies verify that the water relative permeability function krw(Sw) is unaffected by foam. Studies of foam have used a variety of krw functions. This paper shows a connection between the krw(Sw) function and SAG foam effectiveness that is independent of the details of how foam reduces gas mobility. For simplicity, we analyze SAG processes in the absence of mobile oil; success without oil is a precondition to success with oil, and our analysis also applies to a miscible-gas process with oil in 1D in the absence of dispersion. Fractional-flow methods have proved useful and accurate for modeling foam EOR processes. The success of SAG depends on total mobility at a point of tangency to the fractional-flow curve, which defines the shock front at the leading edge of the foam bank. One can determine total mobility directly from the coordinates of this point (Sw, fw) if the function krw(Sw) is known. Geometric constraints limit the region in the fractional-flow diagram in which this point of tangency can occur. For a given krw(Sw) function, this limits the mobility reduction achievable for any possible SAG process. We examine the implications of this limitation for different krw functions. These implications include the following. Increasing nonlinearity of the krw function is advantageous for SAG processes, regardless of how foam reduces gas mobility. SAG is inappropriate for naturally fractured reservoirs if straight-line relative permeabilities apply, even if extremely strong foam can be stabilized in fractures. It is important to measure krw(Sw) separately for any formation for which a SAG process is envisioned.


1981 ◽  
Vol 103 (4) ◽  
pp. 285-290 ◽  
Author(s):  
K. I. Kamath ◽  
S. J. Yan

The theory of enhanced oil recovery by surfactant flooding (micellarpolymer and “low-tension” floods) is based on three premises: that the chemical slug is 1) less mobile than the crude oil, 2) miscible with the reservoir fluids (oil and brine), and 3) stable over long periods of time (years) in the reservoir environment. We report here a rather simple process in which none of these expensive and exacting requirements have to be met. In this process, relatively small amounts of “EOR-active” substances present in certain petroleum-based sulfonates are found to recover 15–20 percent of the residual oil from waterflooded Berea sandstone cores. The chemicals are injected in the form of slugs of their aqueous solutions. If the chemical slugs are followed with similar slugs of additives such as partially hydrolyzed polyacrylamide, acrylamide monomer, urea, EDTA, or anions such as P2O7‴‴‴‴ and PO4‴‴‴, the oil recovery is increased 30–40 percent of the in-place residual oil. The concentrations of the “active” sulfonate and additive in their respective slugs appear to be of the order of 500 ppm or less. Extrapolation of the laboratory data to field conditions indicate that chemical requirements for the recovery of a barrel of tertiary oil are about 0.5–2 lb of sulfonate and a like amount of additive. The main features of the displacement process are: 1) Oil recovery is independent of oil viscosity in the tested range of 0.4–100 cps. 2) The process is essentially an immiscible displacement in which oil recovery depends on the amount of active chemical in the slug and not its concentration. 3) Tertiary oil is produced in the form of a clean “oil bank” and the buildup of a residual oil saturation at the producing end of linear cores occurs during the flood. From the data on hand, it is apparent that the oil recovery mechanism differs basically in character from the conventional Buckley-Leverett-type immiscible displacement. The low level concentrations of sulfonate and additive involved, and the independence of oil recovery with respect to oil viscosity suggest that the recovery mechanism is possibly actuated by certain specific functional groups in the structure of the EOR-active molecule or its anion, and of the additive. The results hold great potential for developing a simple and economical tertiary oil recovery process that can recover, very substantially, more oil (light as well as moderately viscous) than is now considered possible by conventional chemical floods.


2018 ◽  
Vol 40 (2) ◽  
pp. 85-90
Author(s):  
Yani Faozani Alli ◽  
Edward ML Tobing ◽  
Usman Usman

The formation of microemulsion in the injection of surfactant at chemical flooding is crucial for the effectiveness of injection. Microemulsion can be obtained either by mixing the surfactant and oil at the surface or injecting surfactant into the reservoir to form in situ microemulsion. Its translucent homogeneous mixtures of oil and water in the presence of surfactant is believed to displace the remaining oil in the reservoir. Previously, we showed the effect of microemulsion-based surfactant formulation to reduce the interfacial tension (IFT) of oil and water to the ultralow level that suffi cient enough to overcome the capillary pressure in the pore throat and mobilize the residual oil. However, the effectiveness of microemulsion flooding to enhance the oil recovery in the targeted representative core has not been investigated.In this article, the performance of microemulsion-based surfactant formulation to improve the oil recovery in the reservoir condition was investigated in the laboratory scale through the core flooding experiment. Microemulsion-based formulation consist of 2% surfactant A and 0.85% of alkaline sodium carbonate (Na2CO3) were prepared by mixing with synthetic soften brine (SSB) in the presence of various concentration of polymer for improving the mobility control. The viscosity of surfactant-polymer in the presence of alkaline (ASP) and polymer drive that used for chemical injection slug were measured. The tertiary oil recovery experiment was carried out using core flooding apparatus to study the ability of microemulsion-based formulation to recover the oil production. The results showed that polymer at 2200 ppm in the ASP mixtures can generate 12.16 cP solution which is twice higher than the oil viscosity to prevent the fi ngering occurrence. Whereas single polymer drive at 1300 ppm was able to produce 15.15 cP polymer solution due to the absence of alkaline. Core flooding experiment result with design injection of 0.15 PV ASP followed by 1.5 PV polymer showed that the additional oil recovery after waterflood can be obtained as high as 93.41% of remaining oil saturation after waterflood (Sor), or 57.71% of initial oil saturation (Soi). Those results conclude that the microemulsion-based surfactant flooding is the most effective mechanism to achieve the optimum oil recovery in the targeted reservoir.


Author(s):  
Shaoyu Ni ◽  
Wei Qiu ◽  
Anran Zhang ◽  
David Prior

Oil spills can cause severe environmental damage. In-situ burning or chemical dispersant methods can be used in many situations; however these methods are highly toxic and fail in slightly rough seas. In-situ burning also has to begin very quickly before the lighter, flammable components in the oil evaporate. Oil recovery techniques have also been developed to recover oil using skimmer equipment installed in ships. The challenges arise when a vessel is operated in heavy sea and current conditions. An oil skimmer has recently been developed by the Extreme Spill Technology (EST) Inc. for automated oil recovery using a vacuum device installed in a vessel. Initial tests have shown that the prototype vessel is efficient in oil recovery and it can potentially achieve high recovery efficiency in rough seas of both deepwater and shallow water. The paper presents the numerical and experimental studies of the hydrodynamic performance of the vacuum tower installed in the oil skimmer developed by EST. The process of oil recovery by the vacuum mechanism is very complicated and involves multi-phase and multi-scale moving interfaces, including oil, water, atmospheric air and attenuate compressible air on the top part of the vacuum tower, and moving interface of oil slick, oil droplets and air bubbles of different scales. The recovery process was simplified into a three-phase flow problem involving oil, water and air and simulated by using a CFD method. The volume of fluid (VOF) method was employed to capture the moving surfaces between the fluid phases. Model tests were carried out to simulate the oil recovery process. Numerical results were compared with the experimental data. Studies were also extended to optimize the geometry of the tower for maximum oil recovery.


SPE Journal ◽  
2019 ◽  
Vol 24 (06) ◽  
pp. 2758-2775 ◽  
Author(s):  
Martijn T. Janssen ◽  
Pacelli L. Zitha ◽  
Rashidah M. Pilus

Summary Alkaline/surfactant/foam (ASF) flooding is a novel enhanced–oil–recovery (EOR) process that increases oil recovery over waterflooding by combining foaming with a decrease in the oil/water interfacial tension (IFT) by two to three orders of magnitude. We conducted an experimental study regarding the formation of an oil bank and its displacement by foam drives with foam qualities within the range of 57 to 97%. The experiments included bulk phase behavior tests using n–hexadecane and a single internal olefin sulfonate surfactant, and a series of computed–tomography (CT) –scanned coreflood experiments using Bentheimer Sandstone cores. The main goal of this study was to investigate the effect of drive–foam quality on oil–bank displacement. The surfactant formulation was found to lower the oil/water IFT by at least two orders of magnitude. Coreflood results, at under-optimum salinity conditions yielding an oil/water IFT on the order of 10–1 mN/m, showed similar ultimate–oil–recovery factors for the range of drive–foam qualities studied. A more distinct frontal oil–bank displacement was observed at lower drive–foam qualities investigated, yielding an increased oil–production rate. The findings in this study suggested that dispersive characteristics at the leading edge of the generated oil bank in this work were strongly related to the surfactant slug size used, the lowest drive–foam quality assessed yielded the highest apparent foam viscosity (and, thus, the most stable oil–bank displacement), and drive–foam strength increased upon touching the oil bank when using drive–foam qualities of 57 and 77%.


SPE Journal ◽  
2016 ◽  
Vol 21 (02) ◽  
pp. 613-620 ◽  
Author(s):  
Khoa Bui ◽  
I. Yucel Akkutlu ◽  
Andrei Zelenev ◽  
Hasnain Saboowala ◽  
John R. Gillis ◽  
...  

Summary Molecular-dynamics simulation is used to investigate the nature of two-phase (oil/water) flow in organic capillaries. The capillary wall is modeled with graphite to represent kerogen pores in liquid-rich resource shale. We consider that the water carries a nonionic surfactant and a solubilized terpene solvent in the form of a microemulsion, and that it was previously introduced to the capillary during hydraulic-fracturing operation. The water has already displaced a portion of the oil in place mechanically and now occupies the central part of the capillary. The residual oil, on the other hand, stays by the capillary walls as a stagnant film. Equilibrium simulations show that, under the influence of organic walls, the solvent inside the microemulsion droplets enables not only the surfactant but also the complete droplet to adsorb to the interfaces. Hence, delivering the surfactant molecules to the oil/water interface is achieved faster and more effectively in the organic capillaries. After the droplet arrives at the interface, the droplet breaks down and the solvent dissolves into the oil film and diffuses. This process is similar to drug delivery at nanoscale. Using nonequilibrium simulations based on the external force-field approach, we numerically performed steady-state flow measurements to establish that the solvent and the surfactant molecules play separate roles that are both essential in mobilizing the oil film. The surfactant deposited at the oil/water interface reduces the surface tension and acts as a linker that diminishes the slip at the interface. Hence, it effectively enables momentum transfer from the mobile water phase to the stagnant oil film. The solvent penetrating the oil film, on the other hand, modifies flow properties of the oil. In addition, as a result of selective adsorption, the solvent displaces the adsorbed oil molecules and transforms that portion of the oil into the free oil phase. Consequently, the fractional flow of oil is additionally increased in the presence of solvent. The results of this work are important for understanding the effect of microemulsion on flow in organic capillaries and its effect on shale-oil recovery.


1974 ◽  
Vol 14 (05) ◽  
pp. 491-501 ◽  
Author(s):  
Robert N. Healy ◽  
Ronald L. Reed

Abstract Whenever water, an oil, and a surfactant equilibrate at concentrations of surfactant in excess of critical micelle concentrations, one or more microemulsions form.. In view of this, all surfactant flooding processes may involve microemulsions in situ. Ternary diagrams have been constructed for three specific microemulsion systems showing The effects of salinity and cosurfactant on phase behavior, viscosity, resistivity, optical birefringence, and interfacial tension. Using these data, micellar structure maps were prepared for the single-phase region. In this connection, Winsor's concept of intermicellar equilibrium was found consistent with microemulsion systems of interest for tertiary oil recovery. Experimental techniques are described for minimizing the extent of the multiphase region and measuring the low interfacial tensions that obtain there. Introduction GENERAL CONSIDERATIONS It is sometimes difficult to sort out the multiplicity of terminology concerning various kinds of micellar solutions and the structural states in which they exist. For example, Schulman introduced the term "micro emulsion." Winsor objects on the grounds that all emulsions are unstable and a microemulsion must be some kind of an emulsion. Tosch et al. use the phrase "micelle-containing solutions," whereas Shinoda and Kunieda prefer "swollen micellar solution." Nevertheless, the term microemulsion is convenient, is in common use, and it is only necessary to understand precisely what is meant by the term. In this paper a microemulsion is defined to be a stable, translucent micellar-solution of oil, water that may contain electrolytes, and one or more amphiphilic compounds (surfactants, alcohols, etc.). It should be noted that according to this definition a microemulsion is not an emulsion. A microemulsion may have distinct internal and external phases, but in many cases there is no identifiable external phase. phase. Since a microemulsion has at least three components -- oil, water, and surfactant - the compositional state of the system must be specified with at least three numbers. It is therefore convenient and instructive to employ a ternary representation as shown in Fig. 1. The simple situation will involve three pure components, and the multiphase region will be bounded by a continuous binodal curve. Everywhere above the binodal curve a single phase exists that undergoes transitions among various structural states as the compositional point moves about the diagram. These transitions may be gradual, reflecting an equilibrium in which there is significant coexistence of different micellar configurations, as proposed by Winsor. proposed by Winsor. In the multiphase region, the most simple, three-component system involves only two phases throughout; one is oil-external and the other water-external. SPEJ P. 491


2018 ◽  
Vol 126 (2) ◽  
pp. 501-519 ◽  
Author(s):  
M. A. Endo Kokubun ◽  
F. A. Radu ◽  
E. Keilegavlen ◽  
K. Kumar ◽  
K. Spildo

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