The Impact of Interfacial Tension and Pore Size Distribution/Capillary Pressure Character on CO2 Relative Permeability at Reservoir Conditions in CO2-Brine Systems

Author(s):  
Douglas Brant Bennion ◽  
Stefan Bachu
2022 ◽  
Vol 933 ◽  
Author(s):  
Fanli Liu ◽  
Moran Wang

We investigate the impact of wettability distribution, pore size distribution and pore geometry on the statistical behaviour of trapping in pore-throat networks during capillary displacement. Through theoretical analyses and numerical simulations, we propose and prove that the trapping patterns, defined as the percentage and distribution of trapped elements, are determined by four dimensionless control parameters. The range of all possible trapping patterns and how the patterns are dependent on the four parameters are obtained. The results help us to understand the impact of wettability and structure on trapping behaviour in disordered media.


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2247
Author(s):  
Claire Delaroa ◽  
René Fulchiron ◽  
Eric Lintingre ◽  
Zoé Buniazet ◽  
Philippe Cassagnau

The impact of polypropylene and high-density polyethylene backbone binders on the structure of organic matrix, feedstock, and ceramic parts is investigated in terms of morphology in this paper. The miscibility of wax with polyethylene and polypropylene is investigated in the molten state via a rheological study, revealing wax full miscibility with high-density polyethylene and restricted miscibility with polypropylene. Mercury porosimetry measurements realized after wax extraction allow the characterization of wax dispersion in both neat organic blends and zirconia filled feedstocks. Miscibility differences in the molten state highly impact wax dispersion in backbone polymers after cooling: wax is preferentially located in polyethylene phase, while it is easily segregated from polypropylene phase, leading to the creation of large cracks during solvent debinding. The use of a polyethylene/polypropylene ratio higher than 70/30 hinders wax segregation and favors its homogeneous dispersion in organic binder. As zirconia is added to organic blends containing polyethylene, polypropylene, and wax, the pore size distribution created by wax extraction is shifted towards smaller pores. Above zirconia percolation at 40 vol%, the pore size distribution becomes sharp attesting of wax homogeneous dispersion. As the PP content in the organic binder decreases from 100% to 0%, the pore size distribution is reduced of 30%, leading to higher densification ability. In order to ensure a maximal densification of the final ceramic, polyethylene/polypropylene ratios with a minimum content of 70% of high-density polyethylene should be employed.


Author(s):  
Sean Reilly ◽  
Ivan Catton

Biporous wicks are an effective means for facilitating evaporation in heat pipes used for electronics cooling. They facilitate boiling within the wick by having two distinct size distributions of pores; the smaller pores provide high capillary pressure to pump liquid to the surface while the larger pores maintain high vapor permeability. The wicks investigated in this study were sintered copper biporous material. The authors previously presented a validated statistical model, based on work by Kovalev, which could predict the performance of biporous wicks tested at UCLA with reasonable accuracy [1]. Using this model, the author was able to gain new insight into the effect that the numerical estimate of liquid saturation of the wick has on dry out. The pore size distribution allows the determination of the capillary pressure available inside the wick and the Kovalev model provides the required pressure drop to supply liquid water to the heater surface. This led to a method of predicting dry out by comparing the capillary pressure in the wick to the required pressure drop from the model to estimate when the wick was dried out. When the required pressure drop determined by code exceeds the peak effective capillary pressure provided by the wick, the large pores of the wick are considered to be dry. These values are correlated to the input heat flux to determine what at what input power the wick begins to dry out. While the wick will not fail in this mode, the overall heat transfer coefficient will have peaked. In this work, this method of determining dry out will be validated against wicks tested at UCLA by comparing the input powers at which this dry out phenomenon occurs. Accurate predictions of dry out and the role of the pore size distribution are critical in developing methods to delay dry out of biporous wicks. By comparing the relative dry out points of various wick geometries to each other, augmented wick geometries can be suggested for future work. This modeling tool can lay the foundation for future tailoring of biporous evaporator wicks to specific tasks.


2014 ◽  
Author(s):  
Kegang Ling ◽  
Guoqing Han ◽  
Zheng Shen ◽  
Ali Ghalambor ◽  
Jun He ◽  
...  

2017 ◽  
Vol 31 (1) ◽  
pp. 73-82 ◽  
Author(s):  
Milena Kercheva ◽  
Zofia Sokołowska ◽  
Mieczysław Hajnos ◽  
Kamil Skic ◽  
Toma Shishkov

Abstract The heterogeneity of soil physical properties of Fluvisols, lack of large pristine areas, and different moisture regimes on non-flooded and flooded terraces impede the possibility to find a soil profile which can serve as a baseline for estimating the impact of natural or anthropogenic factors on soil evolution. The aim of this study is to compare the pore size distribution of pristine Fluvisols on flooded and non-flooded terraces using the method of the soil water retention curve, mercury intrusion porosimetry, nitrogen adsorption isotherms, and water vapour sorption. The pore size distribution of humic horizons of pristine Fluvisols on the non-flooded terrace differs from pore size distribution of Fluvisols on the flooded terrace. The peaks of textural and structural pores are higher in the humic horizons under more humid conditions. The structural characteristics of subsoil horizons depend on soil texture and evolution stage. The peaks of textural pores at about 1 mm diminish with lowering of the soil organic content. Structureless horizons are characterized by uni-modal pore size distribution. Although the content of structural pores of the subsoil horizons of Fluvisols on the non-flooded terrace is low, these pores are represented by biopores, as the coefficient of filtration is moderately high. The difference between non-flooded and flooded profiles is well expressed by the available water storage, volume and mean radius of pores, obtained by mercury intrusion porosimetry and water desorption, which are higher in the surface horizons of frequently flooded Fluvisols.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rui Shen ◽  
Xiaoyi Zhang ◽  
Yubin Ke ◽  
Wei Xiong ◽  
Hekun Guo ◽  
...  

AbstractSmall-angle neutron scattering and high-pressure mercury intrusion capillary pressure testing are integrated to analyze the pore size distribution of the broad sense shale oil reservoir samples of the Permian Lucaogou Formation in the Jimsar Sag, Junggar Basin, China. The results show that, compared with the measurement method integrating gas adsorption and mercury intrusion, combination of small-angle neutron scattering and mercury intrusion can more accurately characterize full-scale pore size distribution. The full-scale pore size distribution curve of the rock samples in the study area includes two types: the declining type and submicron pore-dominated type. The declining type is mainly found with silty mudstone and dolomitic mudstone, and most of its pores are smaller than 80 nm. Silt-fine sandstones and dolarenite are mostly of the submicron pores-dominated type, with most pores smaller than 500 nm. They also present large specific pore volumes and average pore diameters of macropores and are the favorable lithogenous facies for development of high-quality reservoirs.


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