Effect of Gamma Radiation on the Adsorption Capacity and Regeneration / Desorption of Sulphate and Phosphate Ions Using Smart Hydrogel.
Abstract Co-polymeric hydrogels containing poly (Acrylamide /Epichlorohydrine) P(AAm/EPI) with different acrylamide and Epichlorohydrine content were fabricated by gamma radiation at different irradiation doses as adsorbent materials for wastewater treatment. The mechanisms of radiation-induced crosslinking of hydrogel in aqueous solution has been evaluated. The gel contents and the swelling/diffusion kinetic parameters were evaluated at different irradiation doses, and the result confirm a non-fichian mechanism. The shape, surface morphology, and porosity of P (AAm/ Epi) hydrogel were characterized by scanning electron microscope (SEM). Adsorption experiments were carried out for the removal of sulphate and phosphate ions from wastewater using P(AAm/EPI) hydrogels as adsorbent materials. The isotherm data were analyzed by Freundlich equation. The equilibrium isotherm results show a better fitting (R2 > 0.9) to the Freundlich model for all anions. The calculated regeneration efficiency (%) values of sulphate and phosphate ions found to be ranged between 63.2 (%) and 46 (%).The relatively higher regeneration efficiency (%) and keeping the hydrogels its shape without any deformation promising to use the same hydrogels further times which decrease the economic cost.