scholarly journals Adaptive technology for constructing the kinetic equations of reduction reactions under conditions of a priori uncertainty

Author(s):  
Dmitriy Demin ◽  
Oleh Domin

The object of research is the process of oxide reduction in a reaction system of mass m due to the reaction on a contact surface with an area of S. An adaptive technology is proposed that allows one to construct the kinetic equation of the process in which the oxide is reduced from the initial product under conditions of a priori uncertainty. A priori uncertainty regarding the behavior of a physicochemical system is understood as the fact that the following information is not available to the researcher: – about the change in the mass of the reaction system and the area of the contact surface; – about the rate of accumulation of the finished product; – about the time of withdrawal of the finished product from the system. The proposed adaptive technology includes five sequential stages to eliminate a priori uncertainty. This is ensured through the use of an adaptive algorithm, which allows obtaining the maximum accuracy in estimating the output variable by selecting the optimal parameter of the adaptive algorithm, and the subsequent canonical transformation. The introduced concept "canonical transformation of the kinetic equation" has the following meaning: having received some adequate description of the kinetic equation in a Cartesian coordinate system, a transformation is carried out that allow representing the equation in a new Cartesian coordinate system in such a way that its structure corresponds to the canonical form. The basic postulate of chemical kinetics can be such a canonical type.

2020 ◽  
pp. 65-72
Author(s):  
V. V. Savchenko ◽  
A. V. Savchenko

This paper is devoted to the presence of distortions in a speech signal transmitted over a communication channel to a biometric system during voice-based remote identification. We propose to preliminary correct the frequency spectrum of the received signal based on the pre-distortion principle. Taking into account a priori uncertainty, a new information indicator of speech signal distortions and a method for measuring it in conditions of small samples of observations are proposed. An example of fast practical implementation of the method based on a parametric spectral analysis algorithm is considered. Experimental results of our approach are provided for three different versions of communication channel. It is shown that the usage of the proposed method makes it possible to transform the initially distorted speech signal into compliance on the registered voice template by using acceptable information discrimination criterion. It is demonstrated that our approach may be used in existing biometric systems and technologies of speaker identification.


1999 ◽  
Vol 53 (9-10) ◽  
pp. 1-10
Author(s):  
V. A. Omel'chenko ◽  
V. V. Balabanov ◽  
B. M. Bezruk ◽  
Yu. N. Goloborod'ko

Author(s):  
Iryna Kononova

The article evaluates the reliability indicators of telecommunication system equipment, which can be represented by multi-mode objects of continuous and episodic use with a time reserve operating under conditions of a priori uncertainty. Particular attention is paid to consideration of the process of functioning of the system with a replenished time reserve. The telecommunication system includes an object represented by one structural element and used in different modes of operation. In each mode, the object can be used continuously or episodically (the object performs tasks that occur at random times), herewith only a certain part of its equipment is operating. The restoration of the facility's operation in each mode is based on the "quick" recovery scheme ("quick" recovery means that the repair time is much less than the average working time of the element between failures). Also, some cases of the transition of an object from one mode to another are considered, and the control system operates according to the method of sequential control of parameters. In this case, the system, after waiting mode, begins to analyze the first parameter of the monitored complex, then the second and so on. After analyzing the parameters, the system enters the waiting mode. These calculated ratios allow for a comprehensive assessment of the reliability of telecommunication equipment, taking into account the totality of the main factors that significantly affect the reliability of the equipment in real conditions of operation, make it possible to solve important practical problems which arise from the improvement of existing equipment and development of existing equipment.


Author(s):  
M. E. Shevchenko ◽  
A. V. Gorovoy ◽  
S. N. Solovyov

The paper considers the spatial filtering methods of signals with spectrum overlapping under conditions of a priori uncertainty of the directions of arrival from radio sources. The estimates of the directions of signals arrival obtained by ESPRIT or MUSIC are used in order to build a spatial filter. It is shown that when using ESPRIT, unlike MUSIC, an additional calculations of filter coefficients based on estimates of the directions of signals arrival are not required, and the quadrature components of the signals are formed simultaneously with estimates of the direction of their arrival. The probability of error performances of minimum shift keying signals which were divided by spatial filtering on the basis of ESPRIT and MUSIC using seven-element circular and angular antenna arrays are given.


1993 ◽  
Vol 60 (2) ◽  
pp. 498-505 ◽  
Author(s):  
Z. Tan ◽  
J. A. Witz

This paper discusses the large-displacement flexural-torsional behavior of a straight elastic beam with uniform circular cross-section subject to arbitrary terminal bending and twisting moments. The beam is assumed to be free from any kinematic constraints at both ends. The equilibrium equation is solved analytically with the full expression for curvature to obtain the deformed configuration in a three-dimensional Cartesian coordinate system. The results show the influence of the terminal moments on the beam’s deflected configuration.


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