Mechanism of Degradation of Methyl Bromide and Propargyl Bromide in Soil

2000 ◽  
Vol 29 (4) ◽  
pp. 1322-1328 ◽  
Author(s):  
Sharon K. Papiernik ◽  
Jianying Gan ◽  
Scott R. Yates
HortScience ◽  
2007 ◽  
Vol 42 (5) ◽  
pp. 1212-1216 ◽  
Author(s):  
Inga A. Zasada ◽  
Clyde L. Elmore ◽  
Lani E. Yakabe ◽  
James D. MacDonald

The cut flower and bulb industry in California is an important part of the state's agricultural economy and it has relied heavily upon the use of methyl bromide as a treatment to control soil-borne pests. With the phase out of methyl bromide, it is important to develop alternatives that will maintain crop productivity. This report describes research testing the efficacy of propargyl bromide against selected nematode, fungal, and weed species. Three sites were selected in California to represent different soil types and environments. Propargyl bromide was applied to soil in large, buried containers at rates ranging from 28 to 168 kg·ha−1 and compared with standard soil fumigants. The citrus nematode (Tylenchulus semipenetrans Cobb) and an isolate of Fusarium oxysporum Schlechtend:Fr were both controlled at the lowest rate of propargyl bromide tested: 28 kg·ha−1. Weed species varied greatly in their sensitivity to propargyl bromide. A 100% reduction in common purslane (Portulaca oleracea L.) and pigweed (Amaranthus retroflexus L.) germination occurred at 112 kg·ha−1 propargyl bromide, regardless of geographical location. Results for annual bluegrass (Poa annua L.) control were more variable across locations and years, but more than 90% control was consistently achieved with 168 kg·ha−1 propargyl bromide. Cheeseweed (Malva parviflora L.) and field bindweed (Convolvulus arvensis L.) were never consistently controlled by propargyl bromide. When compared with the soil fumigants methyl bromide, iodomethane, and metam sodium, propargyl bromide provided comparable control of all soil-borne pests, but at much lower rates. Although higher rates of propargyl bromide, more than 112 kg·ha−1, were needed to control weeds, these rates still were almost half that required of the other standard fumigants.


HortScience ◽  
2008 ◽  
Vol 43 (6) ◽  
pp. 1826-1832 ◽  
Author(s):  
Sally M. Schneider ◽  
Husein A. Ajwa ◽  
Thomas J. Trout ◽  
Suduan Gao

Field studies were conducted to evaluate potential alternatives to methyl bromide (MBr) for the control of plant parasitic nematodes in shallow-rooted, bedded cropping systems such as strawberry and in perennial nursery cropping systems in central California. Chloropicrin (Pic), 1,3-dichloropropene (1,3-D or Telone), combinations of 1,3-D + Pic, iodomethane (IM) + Pic, propargyl bromide (PBr), and metam sodium (MS) were compared with untreated controls and industry standard MBr/Pic treatments. Materials were applied by both shank-injection and drip-application, except MS and PBr, which were applied only by drip. The efficacy on citrus nematode (Tylenchulus semipenetrans Cobb) and/or root-knot nematode (Meloidogyne spp. Chitwood) control was investigated in three trials conducted on soils ranging from sandy loam to silty clay loam. All treatments controlled nematodes near the injection point (center of bed and moderate depths) comparable to MBr/Pic. Drip-applied Pic provided somewhat less control than MBr/Pic at the shoulder of the bed when delivered in 25 mm of water and MS provided no control at the bed shoulder. IM + Pic, both shank-injected and drip-applied, provided nematode control to a depth of 150 cm comparable to MBr/Pic. Telone EC applied to a dry field in 75 mm water did not control nematodes well at either 90- or 150-cm depths, whereas PBr controlled nematodes as effectively as MBr/Pic at the 90-cm depth, but not at the 150-cm depth. Propargyl bromide at 67 kg·ha−1 was effective at killing the nematodes up to 30 cm deep in a strawberry plant bed. The dosage exposure values (within 96 h after fumigation) observed for greater than 99% control of nematodes were much lower for PBr (≈1 mg·L−1·h) than those for 1,3-D + Pic (17 mg·L−1·h when applied at 61:35 1,3-D:Pic mass ratio), Pic alone (10 mg·L−1·h), and IM + Pic (19 mg·L−1·h when applied at 50:50 mass ratio). Drip application technology showed promise for effective alternatives to MBr/Pic. Consistent delivery of an effective dosage of a material throughout the target soil profile is necessary for consideration as an acceptable alternative to MBr for high-value crops.


2018 ◽  
Author(s):  
Axel Horst ◽  
Magali Bonifacie ◽  
Gérard Bardoux ◽  
Hans-Hermann Richnow

In this study we investigated the isotope fractionation of the abiotic sink (hydrolysis, halide exchange) of methyl halides in water.<br>


HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 525b-525 ◽  
Author(s):  
S.J. Locascio ◽  
D.W. Dickson

In past work, dichloropropene + 17% Pic (1,3-D + Pic) at 327 L·ha–1 plus pebulate provided good control of nematode, soil fungi, and nutsedge in mulched tomato (Lycopersicon esculentum Mill.) and is considered the best alternative for methyl bromide (MBr) + chloropicrin (Pic), which is scheduled for phase-out in the United States by Jan. 2001. Metam-sodium did not provide acceptable pest control. In the present study, metam-Na (295 L·ha–1 combined with Pic (168 kg·ha–1) + 4.5 kg·ha–1 pebulate, and 1,3-D + 35% Pic at 168 and 225 L·ha–1 + pebulate were compared to MBr-Pic (98-2% at 345 kg·ha–1 and 67-33% at 505 kg·ha–1). Fumigants were injected into the bed except metam-Na and pebulate were surface-applied and incorporated and drip tubing and mulch were applied. Marketable yields with MBr-Pic, 225 L·ha–1 1,3-D + Pic, and metam-Na + Pic were higher than with the check. Yields with metam-Na alone or with additional water before transplanting were similar to the check. Nutsedge was controlled with MBr-Pic and all treatments with pebulate. Nematode root-gall ratings were high on tomato grown without fumigants (8.9 rating on a scale of 0 to 10 with 0 = no galling), low with MBr-Pic (0.33), and intermediate with all other treatments (2.2 to 5.5) except with 168 L·ha–1 1-3-D + Pic (8.3). This study indicates that metam-Na + Pic + pebulate also is a possible alternative to MBr-Pic for tomato.


2020 ◽  
Vol 17 (6) ◽  
pp. 438-442
Author(s):  
Xiaofang Ma ◽  
Shunxi Li ◽  
Samrat Devaramani ◽  
Guohu Zhao ◽  
Daqian Xu

The elimination of volatile organic solvents in organic synthesis is the most important goal in “Green” chemistry. We report a simple, efficient and facile method for the addition of progargyl bromide to carbonyl compounds using Mg metal as a mediator under solvent-free conditions which could regioselectively generate homopropargyl alcohols efficiently in good to excellent yields. The procedure has advantages such as short reaction time, operationally simple, excellent product yields, high regioselectivity and organic solvent-free.


1992 ◽  
Vol 57 (10) ◽  
pp. 2151-2156 ◽  
Author(s):  
Peter Chabreček ◽  
Ladislav Šoltés ◽  
Hynek Hradec ◽  
Jiří Filip ◽  
Eduard Orviský

Two methods for the preparation of high molecular weight [3H]hyaluronic acid were investigated. In the first one, hydrogen atoms in the molecule were replaced by tritium. This isotopic substitution was performed in aqueous solution using Pd/CaCO3 as the catalyst. In the second method, the high molecular weight hyaluronic acid was alkylated with [3H]methyl bromide in liquid ammonia at a temperature of -33.5 °C. High-performance gel permeation chromatographic separation method was used for the isolation and characterization of the high molecular weight [3H]hyaluronic acid. Molecular weight parameters for the labelled biopolymers were Mw = 128 kDa, Mw/Mn = 1.88 (first method) and Mw = 268 kDa, Mw/Mn = 1.55 (second method). The high molecular weight [3H]hyaluronic acid having Mw = 268 kDa was degraded further by specific hyaluronidase. Products of the enzymatic depolymerization were observed to be identical for both, labelled and cold biopolymer. This finding indicates that the described labelling procedure using [3H]methyl bromide does not induce any major structural rearrangements in the molecule.


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