scholarly journals The Characteristics of Material DSSC (Dye-Sensitized Solar Cell) Solar Cell from Extraction of Teak Leaves

2017 ◽  
Vol 2 (1) ◽  
pp. 117
Author(s):  
Hamdan Hadi Kusuma

<p style="text-align: justify;">The research of solar cell with using dye from natural materials as a sensitizer in a dye-sensitized solar cell (DSSC) continues to grow. One advantage of the DSSC is does not require a material with high purity so that the production cost is relatively low. This research aims to analyze the characteristics of the absorption band of teak leaf extract. Extraction of teak leaves dissolved in a mixture of ethanol and acetic acid with a variation ratio of 1: 0, 1: 1 and 5.66: 1, resulting in a solution of each color reddish yellow, reddish brown and dark red. Absropsi test results with UV-Vis spectrometer showed that there are peaks in the absorbance in the visible region, ie at wavelengths between 500 nm to 560 nm. This shows that the dye material of teak leaf extract may work or absorb the green color. While absobption other peaks are also found in pektrum wavelength of 580 nm, 600 nm and 660 nm, each of which can absorb the green color yellow, orange and red. ©2016 JNSMR UIN Walisongo. All rights reserved.</p>

2013 ◽  
Vol 678 ◽  
pp. 349-360 ◽  
Author(s):  
S. Cross Guevara Kiruba Daniel ◽  
N. Mahalakshmi ◽  
J. Sandhiya ◽  
Nehru Kasi ◽  
Sivakumar Muthusamy

We have synthesized silver nanoparticles using the leaf extract of Henna (Lawsonia inermis). The synthesized silver nanoparticles were characterized using UV – visible spectroscopy, Atomic Force Microscopy and FTIR. Effect of leaf extract concentration, pH and reaction temperature on the formation of silver nanoparticles has been analysed by studying the variations in absorbance and wavelength of SPR of silver nanoparticles. The silver nanoparticle increases photoabsorption due to Localized Surface Plasmon Resonance. In this current study, we have fabricated Photo Enhanced Dye Sensitized Solar Cell (PE – DSSC) using the Henna dye reduced silver nanoparticles as sensitizer to improve photocurrent. We have obtained photocurrent output of Henna reduced silver nanoparticle dye sensitized solar cell.


2003 ◽  
Vol 07 (02) ◽  
pp. 131-136 ◽  
Author(s):  
Tasuku Komori ◽  
Yutaka Amao

The dye-sensitized solar cell (DSSC) using visible and near-infrared sensitization of nanocrystalline TiO 2 films using a series of four aluminum phthalocyanines was developed and its photoelectrochemical properties were investigated. By using aluminum 2,9,16,23-tetrakis(phenyl-thio)-29H,31H-phthalocyanine chloride adsorbed on a nanocrystalline TiO 2 film electrode, the I SC , V OC , FF , P max and η values were largest compared with the other DSSCs using aluminum phthalocyanines. For all the DSSCs using aluminum phthalocyanines, IPCE values at near-infrared region (700 nm) are larger than those at visible region (500 nm). Thus, the DSSC using near-infrared sensitization of nanocrystalline TiO 2 film by aluminum phthalocyanines was developed.


Author(s):  
Ibukun Akinsola ◽  
Alabi Aderemi Babatunde ◽  
Adedayo Kayode Seun ◽  
Nicola Coppede

Dye is one of the principal parts for high power conversion efficiency in a Dye-Sensitized Solar Cell. Conspicuous developments have taken place via the work of several researchers in the engineering of novel dye structures so as to enhance the performance of the system. The properties of a natural mineral dye were studied in this work. The structure of the dye was determined and discovered to have contains constituents that could enhance better absorption of solar radiation for use in a Dye-Sensitized Solar Cell (DSSC). The Lead sulphide and iron content of the mineral dye studied as revealed by the X-Ray diffraction analysis done suggest this. The X-Ray Fluorescence (XRF) done revealed that the concentration of Lead and Iron (Fe) is high as compared to other elements present in the material, probably as a result of the fact that it is a geological sample (of the earth) and which may even suggest its colour and hence makes it absorbs solar radiation of visible region at its wavelength (around 380 nm – 800 nm).  The functional groups present in the dye as obtained from the Fourier transform infrared spectroscopy are the Amine, Carbonyl, and hydroxyl groups, all of which confirm the suitability of the dye material in photosensitizing a semiconductor in a DSSC. The absorption spectra of the dye within the visible region of electromagnetic radiation show that the material has high, increased, and stable absorption of visible light which is suggesting a more durable natural dye for a DSSC than the easily degraded natural dyes of plants source. 


2019 ◽  
Vol 4 (1) ◽  
pp. 34
Author(s):  
Sudarlin Sudarlin

<p>Modification of cyanidin as sensitiser on Dye Sensitized Solar Cell (DSSC) has been carried out theoretically in this study using rhodanine acetic acid. The rhodanine acetic acid as electron withdrawing group can increase the electron density of the LUMO state, so injection of the excited electron to the semiconductor can also be increase. The theoretical method used is DFT/B3LYP theory by <em>NWChem</em> software. The calculation shows that the LUMO energy of cyanidin rhodanine acetic is higher than cyanidin, so electron injection to the conduction band of the semiconductor is easier. This condition is supported by reduced of HOMO-LUMO energy gap, so the range of the sunlight that can be involved in the electron excitation process is wider. In addition, the LUMO electron density of the cyanidin rhodanine acetic is localized at rhodanine acetic which makes the distance of the excited electron is closer to the semiconductor, thereby facilitating electron injection.</p>


2017 ◽  
Vol 20 (3) ◽  
pp. 109-113 ◽  
Author(s):  
S. N. Sadikin ◽  
M. Y.A. Rahman ◽  
A. A. Umar

This manuscript reports the use of TiO2-BaTiO3 composite films as a photoanode in dye-sensitized solar cell (DSSC). The influence of BaTiO3 content on the performance parameters of the DSSC has been investigated. The composite has been prepared on ITO glass substrate via sol-gel assisted with spin coating technique. The XRD analysis reveals that the sample is crystalline with the phase of BaTiO3 and anatase TiO2. From the FESEM observation, it was found that the pure sample contains bigger pores compared with the other samples prepared with various BaTiO3 contents. The samples become more compact as the content of BaTiO3 increases. The samples absorb more light in ultraviolet (UV) region than visible region. The area of absorption window varies with BaTiO3 content. The device utilizing the sample with 0 and 6 wt.% BaTiO3 demonstrated the lowest leak current. The device utilizing pure sample produced the highest η of 0.18%. This is due to this device utilized the sample with highest porosity, lowest leak current and charge transfer resistance, Rct.


2013 ◽  
Vol 771 ◽  
pp. 1-24 ◽  
Author(s):  
Karuppannan Rokesh ◽  
Alagarsamy Pandikumar ◽  
Kandasamy Jothivenkatachalam

Dye sensitized solar cell (DSSC) devices incorporating organic and inorganic materials have found a host of applications. The search for low-cost, high efficient and flexible devices has lead to a remarkable increase in the research and development of solar cell. The current review, describes the constitution components of DSSC in a detailed manner and their development and challenges are also discussed. We focused on various structural modifications in wide band gap nanocrystalline semiconductor materials for an efficient electron transfer to reduce the recombination rate. Fruitful attempts have been made to design new molecular dyes for the wide range of absorption in the visible region. Co-Sensitization is an appropriate technique to enhance the absorption range of dye molecules and to increase the efficiency of solar cell. Moreover hole transport materials, there are the efficient tool to replace redox couple based liquid electrolyte and it produce stable solid state DSSC. The successful modification of counter electrode with different morphology promotes the rate electron transfer into electrolyte. This review also covers the update technology to construct efficient, stable and flexible dye sensitized solar cell.


Silicon ◽  
2021 ◽  
Author(s):  
Radhika Rajendhiran ◽  
Venugopal Deivasigamani ◽  
Jayabal Palanisamy ◽  
Selvakumar Pitchaiya ◽  
Nandhakumar Eswaramoorthy ◽  
...  

2012 ◽  
Vol 51 ◽  
pp. 09MA05 ◽  
Author(s):  
Soo-Kyoung Kim ◽  
Min-Kyu Son ◽  
Jin-Kyoung Kim ◽  
Byung-Man Kim ◽  
Na-Yeong Hong ◽  
...  

2020 ◽  
Vol 2020 ◽  
pp. 1-12 ◽  
Author(s):  
Denny Widhiyanuriyawan ◽  
Prihanto Trihutomo ◽  
Sudjito Soeparman ◽  
Lilis Yuliati

Dye-Sensitized Solar Cell (DSSC) constitutes a solar cell using natural dyes from plants that are adsorbed in semiconductors to convert solar energy into electrical energy. DSSC has relatively inexpensive fabrication costs, is easy to produce, works in visible light, and is environmentally friendly. The disadvantage of DSSC is that its efficiency is still low compared to silicon solar cells. This low efficiency is due to obstacles in the flow of electric current on DSSC. In this study, DSSC has been successfully fabricated with the deposition of clathrin protein from cow brain. The zwitterions effect of protein on cow brain is able to reduce resistance and increase electric current on DSSC. The zwitterions effect of cow brain protein that fills gaps or empty spaces between TiO2 particles generates acidic reactions (capturing electrons) and bases (releasing electrons); hence, proteins in the cow brain are able to function as electron bridges between TiO2 molecules and generate an increase in electric current in DSSC. The method used in this research was to deposit clathrin protein from cow brain in a porous TiO2 semiconductor with a concentration of 0%, 25%, 50%, and 75%. Tests carried out on DSSC that have been performed were X-Ray Diffractometer (XRD) testing to determine the crystal structure formed, Fourier Transform Infrared Spectroscopy (FTIR) testing to determine the functional groups formed on DSSC, Scanning Electron Microscopy (SEM) testing to determine the surface morphological characteristics of the DSSC layer, and testing the efficiency using AM 1.5 G solar simulator (1000 W/m2) to determine the efficiency changes that occur in DSSC. From the XRD test results by increasing the concentration of cow brain protein in DSSC, the structure of amino acid crystals also increased and the crystal size increased with the largest crystal size of 42.25 nm at the addition of 75% of cow brain protein. FTIR test results show that the addition of cow brain protein will form functional protein-forming amino groups on DSSC. FTIR analysis shows the sharp absorption of energy by protein functional groups in the FTIR spectrum with increasing concentration of cow brain protein in DSSC. The SEM test results show that the concentration of additional molecules of protein deposited into TiO2 increases and the cavity or pore between the TiO2 molecules decreases. The reduction of cavities in the layers indicates that protein molecules fill cavities that exist between TiO2 molecules. From the results of testing using AM 1.5 G solar simulator (1000 W/m2), the highest efficiency value is 1.465% with the addition of 75% brain protein concentration.


2020 ◽  
Vol 23 (11) ◽  
pp. 403-408
Author(s):  
Yulia Nadhirah ◽  
RD Kusumanto ◽  
Abu Hasan

This study aimed to obtain the most efficient Dye-Sensitized Solar Cell (DSSC) using yellow sweet potato extract (Ipomoea Batatas L.) as a dye sensitizer, with acetic acid, polyethyleneglycol (PEG), and polyvinylalcohol (PVA) as TiO2 binding solution. This research includes the preparation of TiO2 paste with variations: 4 g TiO2 plus 2 M acetic acid (Paste-1), 3.5 g TiO2 plus 15 mL PEG-400 (Paste-2), and 0.5 g TiO2 plus 0.75 mL. PVA (Paste-3). Anthocyanin dye from yellow sweet potato was prepared and used to soak the TiO2 photoelectrode for 24 hours. UV-vis and FTIR spectra of dye solution from yellow sweet potato extract showed anthocyanin content at a maximum wavelength of 283 nm and were strengthened by the appearance of hydroxyl groups in the infrared spectra. The highest DSSC efficiency of 0.302% was obtained from PVA as a TiO2 binder, with an electric current of 0.0204 mA and an electric voltage of 338 mv.


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