scholarly journals Occurrence and distribution of pharmaceuticals in raw, finished, and drinking water from seven large river basins in China

2019 ◽  
Vol 17 (3) ◽  
pp. 477-489 ◽  
Author(s):  
Jia Lv ◽  
Lan Zhang ◽  
Yongyan Chen ◽  
Bixiong Ye ◽  
Jiayi Han ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Water Samples ◽  
Solid Phase ◽  
Tap Water ◽  
River Basins ◽  
Large River ◽  
Mass Spectrometry Analysis ◽  
Detection Rates ◽  
Large River Basins

Abstract The occurrence of pharmaceuticals in the drinking water is a growing concern in China. In this study, we determined the concentration and distribution of 59 selected pharmaceuticals in raw, finished, and tap water samples from 79 drinking water treatment plants (DWTPs) in 15 cities, encompassing seven large river basins in China, using solid-phase extraction pretreatment and ultra-high-performance liquid chromatography–tandem mass spectrometry analysis. Forty-seven pharmaceuticals were detected in raw water samples, with detection rates of 1.27–96.20% and average concentrations of 0.09–128.87 ng/L. Forty-three pharmaceuticals were detected in finished water samples, with detection rates of 1.27–96.20% and average concentrations of 0.07–59.17 ng/L. Forty-two pharmaceuticals were detected in tap water samples, with detection rates of 1.27–94.94% and average concentrations of 0.07–58.43 ng/L. Purification methods implemented by DWTPs are capable of removing some pharmaceuticals from water treatment systems; however, low concentrations of pharmaceuticals were detected in drinking water, raising concerns about the possible human health implications of long-term exposure to low-dose pharmaceuticals. The detection and quantification of pharmaceuticals in municipal water samples presented in this study represent the most extensive analysis of commonly used pharmaceuticals and personal care products located in Chinese river basins.

scholarly journals Correlations of water iodine concentration to earlier goitre frequency in Sweden—an iodine sufficient country with long-term iodination of table salt

2019 ◽  
Vol 24 (1) ◽  
Author(s):  
Sofia Manousou ◽  
Maja Stål ◽  
Robert Eggertsen ◽  
Michael Hoppe ◽  
Lena Hulthén ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
National Survey ◽  
Water Samples ◽  
Tap Water ◽  
Thyroid Volume ◽  
Iodine Concentration ◽  
Urinary Iodine Concentration ◽  
Table Salt ◽  
Water Treatment Plants

Abstract Background Before iodination of Swedish table salt in 1936, iodine deficiency resulting in goitre and hypothyroidism was common. Sweden has become iodine sufficient, as shown in a national survey in 2007, proving its iodination fortification programme effective for the general population. The objective of this study was to collect drinking water from water treatment plants nationally and test if water iodine concentration (WIC) correlated to urinary iodine concentration (UIC) of school-aged children in a national survey 2007 to former goitre frequency in 1929 and to thyroid volume data in 2007. Methods In 2012, 166 treatment plants, located in 57% (166 of 290) of all Swedish municipalities, were asked to collect drinking water samples of approximately 10 ml. In 2007, tap water samples of the same volume were collected from 30 randomly selected schools for the national survey. Analysis of WIC was done in both treatment plants in 2012 (n = 166) and tap water in 2007 (n = 30). The correlation of WIC to the children’s UIC and thyroid volume after iodination was tested based on data from the national survey in 2007. The association of WIC to former goitre frequency was tested based on pre-iodination data, derived from a map of goitre frequency drawn in 1929. Results The median WIC from water treatment plants was 4.0 μg/L (range 0–27 μg/L). WIC was similar in coastal and inland areas, for both ground and surface water. WIC correlated with historical goitre areas and was lower in the goitre areas than in non-goitre areas (p < 0.001). WIC in the same municipalities as the schools correlated with the UIC of children (p < 0.01), but not with their thyroid volume. Conclusions WIC still contributes to iodine nutrition in Sweden, but iodination overrides the goitre effect.

scholarly journals High frequency of Helicobacter pylori DNA in drinking water in Kermanshah, Iran, during June–November 2012

2013 ◽  
Vol 12 (3) ◽  
pp. 504-512 ◽  
Author(s):  
Alvandi Amirhooshang ◽  
Abiri Ramin ◽  
Aryan Ehsan ◽  
Rezaei Mansour ◽  
Bagherabadi Shahram
Keyword(s):  
Helicobacter Pylori ◽  
Drinking Water ◽  
Water Samples ◽  
Tap Water ◽  
Piping System ◽  
Detection Rates ◽  
High Prevalence ◽  
Polymerase Chain ◽  
H Pylori ◽  
Drinking Water Samples

To gain a better understanding of transmission and selecting appropriate measures for preventing the spread of Helicobacter pylori, the aim of this study was to investigate the prevalence of H. pylori in drinking water samples in Kermanshah, Iran. Drinking water samples were collected from around Kermanshah and filtered through 0.45 μm nitrocellulose filters. The bacterial sediment was subjected to DNA extraction and polymerase chain reaction (PCR) for H. pylori detection using newly designed primers targeted at the conserved region of the ureC gene. The overall detection rates for H. pylori DNA in the water samples were 56% (66/118) with a frequency of 36% (25/70) in tap water samples and 85% (41/48) in wells. The detection limit was 50 bacteria per liter of filtered water and a pure H. pylori DNA copy number of 6 per reaction. Based on the evidence we may suggest that recontamination occurred and H. pylori entered into the water piping system through cracked or broken pipes or was released from established H. pylori biofilms on pipes. In conclusion, a high prevalence of H. pylori was detected in drinking water samples that strengthens the evidence of H. pylori transmission through drinking water.

Cryptosporidium oocysts: are they still a risk for human population? A case study in Italy

2020 ◽  
Vol 30 (Supplement_5) ◽  
Author(s):  
C Pignata ◽  
S i Bonetta ◽  
S a Bonetta ◽  
S M Cacciò ◽  
A R Sannella ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Water Samples ◽  
Tap Water ◽  
Treatment Plant ◽  
Drinking Water Treatment ◽  
Water Treatment Plant ◽  
Rt Pcr ◽  
Cryptosporidium Spp ◽  
Cryptosporidium Oocysts

Abstract Over the past decade, several outbreaks of cryptosporidiosis have been reported in many EU countries in association with the consumption of contaminated drinking water, recreational waters, food consumption and contact with animals. The aim of this study was to evaluate the occurrence of Cryptosporidium oocysts in a drinking water treatment plant (DWTP) located in a rural area of northern Italy. Influent and effluent samples at the DWTP, together with tap water samples from a public fountain were collected for three years (2013-2016). All samples were analysed for the presence of Cryptosporidium spp. oocysts by the EPA Method 1623 based on immunomagnetic separation (IMS)/immunofluorescence assay (IFA), complemented by 4,6-diamidino-2-phenylindole (DAPI) staining. The detection has been implemented with a reverse transcriptase-PCR (RT-PCR) protocol to evaluate the oocyst viability. The results highlighted a high variability of oocyst concentrations in all samples (mean 4.3 - 5.8/100 L) and a high percentage variability of the DAPI-positive specimens (mean 48.2% - 40.3%). Conversely, RT-PCR did not reveal the presence of any viable C. parvum and C. hominis oocysts. A nested PCR targeting Cryptosporidium 18S ribosomal DNA was carried out in two water samples to deepen the understanding of the obtained results. This test revealed the presence of a particular Cryptosporidium genotype associated with wild animals in the river and in tap water. Although the recovered Cryptosporidium genotype is not a human pathogen, its presence demonstrates the existence of a potential pathogen Cryptosporidium spp. contamination risk. Moreover, these results underline the importance of considering unconventional (not bacterial) biological contaminations (protozoa) in water resources in rural areas, including those of developed countries. Key messages The supply source and the drinking water treatment plant examined represent a classic example of a system that requires continuous monitoring to guarantee population health. Cryptosporidium oocysts may still be a Public Health problem even in industrialized countries, especially in rural and mountain areas.

scholarly journals Impact of Water Treatment Processes on Selected Heavy Metals Concentrations in Drinking Water Within Katsina Metropolis

2020 ◽  
pp. 336-342
Author(s):  
Yusuf Abdulrashid ◽  
Nuraddeen Abdurrahman ◽  
Kamaladdeen Abdullahi ◽  
Aisha Ado Shehu
Keyword(s):  
Heavy Metals ◽  
Drinking Water ◽  
Water Treatment ◽  
Water Samples ◽  
Tap Water ◽  
P Value ◽  
Raw Water ◽  
Value Analysis ◽  
Treatment Processes ◽  
The Impact

The research focused on the impact of water treatment processes on selected heavy metals concentrations in drinking water within Katsina metropolis. Water samples were collected from taps, sachets and Ajiwa dam raw waters and analyzed for Pb, Cu, Fe, Ni, Mn, Zn and Mg using atomic absorption spectrophotometer (AAS). The solid residues filtered from the treated samples were also analyzed using x-ray fluorescence (XRF) method. The result obtained from the water analysis shows that Cu concentration determined between (0.862-17.232) µg/L with the highest concentration below WHO limit in Ajiwa dam raw water, Pb concentration determined between (0.000-109.63) µg/L with the highest concentration above WHO limit in Ajiwa dam raw water, Ni concentration was detected in almost all the water samples, with the concentration between (0.000-0.72) µg/L, all the concentrations were below WHO limit, Mn concentration determined between (16.554-66.234) µg/L with the highest concentration within WHO limit in Ajiwa dam raw water, Zn concentration determined between (47.286-58.122) µg/L with the highest concentration within WHO limit in tap water, Mg concentration determined between (102.5-213.77) µg/L with the highest concentration within WHO limit in Ajiwa dam raw water. While the amount(%) of isolated element shows that Si(42.51), O(25.39), K(0.24), Ca(1.16), Ti(0.16), Mn(0.04), Fe(1.19), Cu(0.02), Zn(0.009), Ag(0.40), Ba(0.31), Ce(0.03), Nd(0.002), Eu(0.03), Re(0.04), Cl(1.14) and S(0.22) with Silicon with the highest percentage and Neodymium with the least percentage value. Analysis of variance (ANOVA) shows that Pb (p-value 0.000), Cu (p-value 0.000), Fe (p-value 0.000), Ni (p-value 0.490), Mn (p-value 0.007), Zn (p-value 0.000) and Mg (p-value 0.046). This results show that the concentrations of heavy metals analyzed were either removed or drastically reduced to tolerable level or standard limit set by WHO for safe drinking water through series of water treatment processes and this render the water in the areas safe for drinking for now.

ECOLOGICAL AND PHYSIOLOGICAL ASSESSMENT OF CHEMICAL COMPOSITION OF DRINKING TAP WATER IN KHANTY-MANSIYSK AND SALEKHARD

2020 ◽  
pp. 159-167
Author(s):  
V.V. Lapenko ◽  
L.N. Bikbulatova ◽  
E.M. Ternikova
Keyword(s):  
Drinking Water ◽  
Chemical Composition ◽  
Water Samples ◽  
Tap Water ◽  
Iron Concentration ◽  
Absorption Spectrometry ◽  
Northern Region ◽  
Transport Processes ◽  
Magnesium Concentration ◽  
Geochemical Environment

Water is very important for humans, as it is a solvent for metabolic products. Moreover, it is necessary for metabolism, biochemical and transport processes. The elemental status in persons depends on the geochemical environment and consumption of bioelements with food and water. The aim of the paper is to conduct a comprehensive assessment of chemical composition of drinking tap water in Khanty-Mansiysk and Salekhard. Materials and Methods. The chemical composition of 100 samples of drinking tap water was analyzed by atomic absorption spectrometry, spectrophotometry and capillary electrophoresis. All in all, there were 50 samples from Khanty-Mansiysk and 50 samples from Salekhard. The results were compared with Sanitary Rules and Norms 2.1.4.1074-01. Results. Drinking tap water in Salekhard contains a significantly higher concentration of iron, which is much above the maximum allowable concentration, if compared to water samples in Khanty-Mansiysk (p=0.03). In the cities under consideration, the water undergoes high-quality reagent-free treatment. However, the deterioration of the water supply networks in Salekhard is 3 times as high as in Khanty-Mansiysk. Calcium and magnesium concentration in water samples from Khanty-Mansiysk is 5.6 and 3.9 times lower than the MAC; in water samples from Salekhard calcium concentration is 6.3 (p=0.008) and magnesium concentration 4.6 (p<0.001) times lower than the MAC. Conclusion. The consumption of ultra-fresh drinking water leads to low intake of bioelements, which are a part of enzymes contributing to the human antioxidant defense and can result in manifestation of cardiovascular diseases. This is especially true for Salekhard with very soft drinking water and high iron concentration, which excess can exhibit prooxidant properties. Keywords: tap water, bioelements, northern region, antioxidants. Вода является важнейшим соединением для человека: необходима в качестве растворителя продуктов метаболизма и протекания обменных, биохимических и транспортных процессов. Элементный статус организма человека зависит от геохимического окружения и поступления биоэлементов с пищей и водой. Цель. Провести комплексную оценку химического состава водопроводной воды городов Ханты-Мансийск и Салехард. Материалы и методы. Методами атомно-абсорбционной спектрометрии, спектрофотометрии и капиллярного электрофореза проанализирован химический состав 100 проб водопроводной воды: по 50 из Ханты-Мансийска и Салехарда. Результаты сравнивали с СанПиН 2.1.4.1074-01. Результаты. В водопроводной воде Салехарда установлена превышающая ПДК и достоверно более высокая концентрация железа сравнительно с водой Ханты-Мансийска (р=0,03). При условии качественной безреагентной водоподготовки в изучаемых городах это обусловлено изношенностью водопроводных сетей в Салехарде, более чем в 3 раза превышающей этот показатель в Ханты-Мансийске. Концентрация кальция и магния в воде Ханты-Мансийска в 5,6 и 3,9 раза ниже ПДК; в воде Салехарда – в 6,3 (р=0,008) и 4,6 (р<0,001) раза ниже ПДК соответственно. Заключение. Употребление ультрапресной питьевой воды на фоне очень малого поступления с водой биоэлементов, входящих в состав ферментов антиоксидантной защиты организма человека, может привести к манифестации кардиоваскулярных заболеваний. Это особенно актуально для г. Салехарда с очень мягкой питьевой водой с повышенным содержанием железа, избыток которого может проявлять прооксидантные свойства. Ключевые слова: водопроводная вода, биоэлементы, северный регион, антиоксиданты.

Use of a stable carbon isotope to assess the efficiency of a drinking water treatment method with CO2

2012 ◽  
Vol 65 (6) ◽  
pp. 983-988 ◽  
Author(s):  
M. Poberžnik ◽  
A. Leis ◽  
A. Lobnik
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Dissolved Inorganic Carbon ◽  
Tap Water ◽  
Stable Carbon Isotope ◽  
Research Work ◽  
Drinking Water Treatment ◽  
Treatment Method ◽  
Water Supply Systems ◽  
Co2 Gas

CO2 gas with a special isotopic signature (δ13C = −35.2‰ vs. VPDB) was used as a marker to evaluate the efficiency of a drinking water treatment method and the effect of an ultrasonic (US) stirrer. This treatment was developed to prevent precipitation and corrosion effects in water–supply systems. The research work was performed using a laboratory-scale pilot plant that was filled with tap water. The stable isotope analyses of δ13C-DIC (Dissolved Inorganic Carbon) in the water samples indicated that the maximum content of added CO2 gas in DIC was in the range of 35 to 45%. The use of the US stirrer during the entire experiment decreased the method's overall efficiency by 10%, due to degassing at a late stage of the experiment but accelerated the dissolution process in the early experimental stage.

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