scholarly journals Polycyclic aromatic hydrocarbons (PAHs) in coastal sediments from urban and industrial areas of Asaluyeh Harbor, Iran: distribution, potential source and ecological risk assessment

2016 ◽  
Vol 74 (4) ◽  
pp. 957-973 ◽  
Author(s):  
Alireza Raeisi ◽  
Hossein Arfaeinia ◽  
Morteza Seifi ◽  
Mehdi Shirzad-Siboni ◽  
Mozhgan Keshtkar ◽  
...  

The distribution and toxicity levels of 16 EPA priority pollutant polycyclic aromatic hydrocarbons (PAHs) in the sediments of Asaluyeh shore, Iran were investigated. The total concentrations of the PAHs in surface sediments ranged from 1,054 to 17,448 ng/g dry weights with a mean concentration of 8,067 ng/g. The spatial distribution of PAHs showed that PAH levels are much higher in the industrial areas in comparison with urban areas. Based on diagnostic ratios, pyrogenic activities were dominant sources of PAHs pollution in sediments comparing petroleum sources. The toxic equivalent concentrations (TEQ Carc) of PAHs ranged from 172 to 2,235 ng TEQ/g with mean value of 997.9. Toxicity levels were evaluated using sediment quality guidelines (SQGs) and toxic equivalent factors. Samples were collected from industrial and urban stations in Asaluyeh shores. According to SQGs, ΣPAHs concentrations in sediments of urban areas were below the ERL (effects range low), but the industrial samples had ΣPAHs concentrations between ERL and ERM (effects range median). Furthermore, ΣHPAHs (heavy PAHs) and some individual PAHs in some industrial stations exceeded ERM, indicating adverse ecological risk effects frequently occur. Findings demonstrate that the surface sediment from Asaluyeh shore is highly to very highly contaminated with PAHs.

2021 ◽  
Vol 8 (4) ◽  
pp. 257-266
Author(s):  
Ghafour Nourian ◽  
Neamat Jaafarzadeh Haghighi Fard ◽  
Abdul Rahim Pazira ◽  
Esmaeil Kohgardi

Background: Polycyclic aromatic hydrocarbons (PAHs) are stable and highly toxic environmental pollutants, which are produced mainly through combustion processes. The present study aimed to identify and determine PAHs compounds and their ecotoxicological effects in surface sediments of 20 stations in Bushehr province (Assaluyeh, Kangan, Khark, Emam Hasan, and Bushehr areas). Methods: All sediment samples (0-5 cm) were collected from 20 sites of Persian Gulf costs (Bushehr province, Iran). The concentration of PAHs was determined by HPLC. Then, in order to identify the sources of PAHs, ƩLPAHs/ƩHPAHs, IP/ (IP+BP), PH/AN, and AN/(PH+AN) ratios were obtained. Sediment quality guidelines (SQGs) and sediment quality criteria (SQC) were used to measure the PAHs ecotoxicological effects in sediments. Results: Based on PAHs isomeric ratios, the contaminants of sediments originated from pyrogenic resources. ƩPAHs values (ng/g dw) in sediment samples ranged from ND to 49180. The toxic equivalent concentration (TEQ car) of PAHs raged from ND-7999 ngTEQ/g. Based on SQGs and SQC, the concentrations of ƩPAHs compounds in 10% and 6% of the sampling stations exceeded effects range median (ERM) and frequent effect level (FEL), respectively, indicating negative ecological risk effects. Conclusion: Sampling stations sediments must be routinely checked for PAHs because may lead to a negative effect on the marine ecosystem, organisms, and humans.


2017 ◽  
Vol 19 (4) ◽  
pp. 561-569 ◽  
Author(s):  
Ye Li ◽  
Xinran Liu ◽  
Min Liu ◽  
Xiaofei Li ◽  
Qing Wang ◽  
...  

Pollution by PAHs in the estuarine–coastal area of the ECS should be paid attention.


2019 ◽  
Vol 20 (2) ◽  
pp. 271
Author(s):  
Deny Yogaswara ◽  
Ita Wulandari ◽  
Khozanah Khozanah ◽  
Edward Edward ◽  
Dede Falahudin

ABSTRACTBintan Island is the small island in the Riau Archipelago which borders Singapore and Malaysia. Its water is crossed by international shipping lines. Therefore, water quality in this area is potentially polluted by marine activities. The present study aimed to evaluate the concentration, spatial distribution, and assessment of ecological risks of polycyclic aromatic hydrocarbons (PAHs) in surface sediments from selected coastal water of Bintan. Surface sediments in this study were extracted by using the ultrasonic system and determined with GCMS. The data were visualized with ArGIS software for spatial distribution mapping, applied ratio diagnostic methods for the source of PAH contamination, and assess their ecological risk based on sediment quality guidelines. The results showed PAHs concentrations ranged from below the method detection limit (<DL) to 13.492 ng.g−1(dry weight) with the highest concentration of PAHs were detected at TJU 1 station as much as 13.492 ng.g-1. As many as seven types of PAHs were identified in Bintan water, they were Naphthalene (two rings), Fluorene and Anthracene (three rings); fluoranthene, Pyrene, Benzo (a) Pyrene and Chrysene (five rings). Based on diagnostic ratios, the sources of PAHs in this coastal area were mainly from pyrogenic origins. Ecological risk assessment has shown that the average value of ∑10 PAH in Bintan waters (5.855 ng.g-1) is lower than the corresponding ERL, ERM, TEL, and PEL value indicating that the adverse biological effects of PAHs are generally low.Keywords: Polycyclic Aromatic Hydrocarbons (PAHs), Distribution, Pollution, Bintan WatersABSTRAKPulau Bintan merupakan pulau kecil di Kepulauan Riau yang berbatasan langsung dengan negara Singapura dan Malaysia serta perairannya dilintasi oleh jalur pelayaran internasional sehingga potensi pencemaran dari aktivitas di laut sangat tinggi. Penelitian ini bertujuan untuk mengukur konsentrasi, distribusi spasial, sumber asal pencemaran dan analisis resiko lingkungan senyawa PAH dalam sedimen permukaan di perairan pesisir Pulau Bintan. Sedimen permukaan diekstraksi dengan sistem ultrasonik dan dianalisa akhir dengan GCMS. Data senyawa PAH diolah dengan software ArGIS untuk membuat peta distribusi spasial, dianalisa dengan metode diagnosa rasio untuk mengetahui sumber pencemarnya dan dibandingkan dengan nilai baku mutu sedimen untuk mengkaji resiko ekologinya. Hasil analisis di setiap stasiun sampling di Muara Pengudang dan Tanjung Uban menunjukkan konsentrasi Total PAH (TPAH) berkisar antara < limit deteksi alat (1 ngg-1) sampai 13,492 ng.g-1 berat kering dengan konsentrasi tertinggi terdeteksi di stasiun TJU 1 yaitu sebesar 13,492 ng.g-1.  Sebanyak tujuh jenis senyawa PAH teridentifikasi di perairan Bintan ini diantaranya Naphthalene, (dua cincin benzene), Fluorene dan Anthracene (tiga cincin benzene); Fluoranthene, Pyrene, Benzo (a) Pyrene, dan Chrysene (empat cincin benzene). Berdasarkan analisa diagnosa rasio, sumber pencemaran PAH di perairan pesisir Bintan adalah berasal dari kombinasi antara sumber pirogenik. Analisis resiko lingkungan menunjukkan nilai rata-rata ∑10 PAH di perairan Bintan (5,855 ngg-1) masih rendah dibandingkan nilai ERL, ERM, TEL dan PEL, hal tersebut mengindikasikan bahwa efek biologis senyawa PAH secara umum rendah.Kata kunci: Polisiklik Aromatik Hidrokarbon (PAH), Sebaran, Pencemaran, Perairan Bintan


2011 ◽  
Vol 23 (6) ◽  
pp. 578-588 ◽  
Author(s):  
Margarita Préndez ◽  
Carolina Barra ◽  
Carla Toledo ◽  
Pablo Richter

AbstractAlkanes and polycyclic aromatic hydrocarbons were quantified in samples of coastal sediments along Fildes Peninsula, King George Island, South Shetland Islands, Antarctica, during the summers of 2005 and 2007. Quantification was done by using GC-MS and applying the EPA 3550B method. Individual polycyclic aromatic hydrocarbon (PAHs) concentrations were below 14.4 ng g-1 dry wt in 2005 and below 88.7 ng g-1 dry wt in 2007. Alkanes concentrations were higher than those of PAHs and ranged from 8 to 2236 ng g-1 dry wt in 2005 and from 53 to 745 ng g-1 dry wt in 2007. Results of total PAHs and alkanes were integrated along with base administrative and geographic maps in a GIS environment to determine the geographic extent of hydrocarbons detected. The largest concentrations were found in areas near research stations where total n-alkanes suggest petrogenic sources and where some diagnostic ratios suggest the presence of some PAHs produced by pyrogenic processes. Even if concentrations of hydrocarbons are low, they seem to be a result of increases in scientific activities, in the activities of the stable population, in the number of tourists, or a combination of theses factors.


2013 ◽  
Vol 328 ◽  
pp. 323-327
Author(s):  
Cheng Di Dong ◽  
Chih Feng Chen ◽  
Yi Kuo Chang ◽  
Chiu Wen Chen

The surface samples were collected from the Love River mouth, Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Total PAHs concentrations varied from 785 to 1,893 ng/g dw. The spatial distribution of PAHs reveals that the PAHs concentration is relatively high in the river mouth region, and gradually diminishes toward the harbor region. Diagnostic ratios showed that the possible source of PAHs in the Love River mouth could be petroleum combustion. The toxic equivalent concentrations (TEQcarc) of PAHs varied from 117 to 272 ng TEQ/g dw. Higher total TEQcarc values were found in the river mouth region. As compared with the US Sediment Quality Guidelines (SQGs), the observed levels of PAHs at Love River mouth were lower than the effects range low (ERL), and would probably not exert adverse biological effects.


2021 ◽  
Vol 33 (2) ◽  
pp. 439-446
Author(s):  
S.Y. Pang ◽  
S. Suratman ◽  
J.H. Tay ◽  
N. Mohd Tahir

The surface distributions of aliphatic hydrocarbons and polycyclic aromatic hydrocarbons (PAHs) were investigated from coastal sediments of Brunei Bay, southern South China Sea. The concentrations of total n-alkane (TNA) and 16 USEPA priority PAHs ranged from 0.67 to 9.88 μg/g and 4.72 to 102 ng/g, respectively. Principal component analysis (PCA) clustered the hydrocarbons in surface sediments according to their relationship and geographical locations, anticipated to the inputs and activities in proximity. Biomarker diagnostic ratios revealed that biogenic n-alkane inputs in the coastal sediments are exported from the fluviomarine and mangrove swamp environment, while the PAHs inputs are derived from mixed petrogenic and petroleum combustion residues. Overall, the level of PAHs in the study area is between low to moderate, based on the comparison with other areas worldwide.


2012 ◽  
Vol 178-181 ◽  
pp. 992-995
Author(s):  
Chih Feng Chen ◽  
Chiu Wen Chen ◽  
Cheng Di Dong

Surface samples were collected from the Jen-Gen River mouth, Taiwan and analyzed for polycyclic aromatic hydrocarbons (PAHs). Total PAHs concentrations varied from 283 to 1,277 ng/g, with a mean concentration of 671 ng/g. The spatial distribution of PAHs reveals that the PAHs concentration is relatively high in the river mouth region, and gradually diminishes toward the harbor region. Diagnostic ratios showed that the possible source of PAHs in the Jen-Gen River mouth could be petroleum combustion. The toxic equivalent concentrations (TEQcarc) of PAHs varied from 43 to 169 ng TEQ/g. Higher total TEQcarc values were found in the river mouth region. As compared with the US Sediment Quality Guidelines (SQGs), the observed levels of PAHs at Jen-Gen River mouth were lower than the effects range low (ERL), and would probably not exert adverse biological effects.


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