scholarly journals Theoretical prediction of shape-resonance-enhanced nuclear motion effects in molecular photionization

1979 ◽  
Author(s):  
Joseph L. Dehmer ◽  
Dan Dill ◽  
Scott Wallace
Keyword(s):  
Theoretical Prediction ◽  
Shape Resonance ◽  
Nuclear Motion

scholarly journals Attosecond timing of electron emission from a molecular shape resonance

2020 ◽  
Vol 6 (31) ◽  
pp. eaba7762 ◽  
Author(s):  
S. Nandi ◽  
E. Plésiat ◽  
S. Zhong ◽  
A. Palacios ◽  
D. Busto ◽  
...  
Keyword(s):  
Potential Barrier ◽  
Molecular Spectroscopy ◽  
Molecular Shape ◽  
High Spectral Resolution ◽  
Shape Resonance ◽  
Nuclear Motion ◽  
Centrifugal Barrier ◽  
Ionization Time ◽  
Molecular Photoionization ◽  
Franck Condon

Shape resonances in physics and chemistry arise from the spatial confinement of a particle by a potential barrier. In molecular photoionization, these barriers prevent the electron from escaping instantaneously, so that nuclei may move and modify the potential, thereby affecting the ionization process. By using an attosecond two-color interferometric approach in combination with high spectral resolution, we have captured the changes induced by the nuclear motion on the centrifugal barrier that sustains the well-known shape resonance in valence-ionized N2. We show that despite the nuclear motion altering the bond length by only 2%, which leads to tiny changes in the potential barrier, the corresponding change in the ionization time can be as large as 200 attoseconds. This result poses limits to the concept of instantaneous electronic transitions in molecules, which is at the basis of the Franck-Condon principle of molecular spectroscopy.

Shape-Resonance-Enhanced Nuclear-Motion Effects in Molecular Photoionization

1979 ◽  
Vol 43 (14) ◽  
pp. 1005-1008 ◽  
Author(s):  
J. L. Dehmer ◽  
Dan Dill ◽  
Scott Wallace
Keyword(s):  
Shape Resonance ◽  
Nuclear Motion ◽  
Molecular Photoionization

Theoretical prediction of transport coefficients of antimony doped tin dioxide

2021 ◽  
Vol 47 (11) ◽  
pp. 15277-15281
Author(s):  
Rundong Wan ◽  
Kaicheng Jiang ◽  
Zhengfu Zhang ◽  
Ying Lei ◽  
Guocai Tian
Keyword(s):  
Theoretical Prediction ◽  
Tin Dioxide ◽  
Transport Coefficients

Theoretical prediction of intrinsic carrier mobility of monolayer C7N6: First-principles study

2021 ◽  
pp. 127340
Author(s):  
Yajing Zhang ◽  
Shuo Cao ◽  
Yanzhou Wang ◽  
Xiaodong Jian ◽  
Libin Shi ◽  
...  
Keyword(s):  
Theoretical Prediction ◽  
First Principles ◽  
Carrier Mobility ◽  
First Principles Study

Sublimation thermodynamics of pyrazinoic, dipicolinic and quinolinic acids: Experiment and theoretical prediction

2021 ◽  
Vol 155 ◽  
pp. 106369
Author(s):  
K.V. Drozd ◽  
A.N. Manin ◽  
A.P. Voronin ◽  
G.L. Perlovich
Keyword(s):  
Theoretical Prediction ◽  
Sublimation Thermodynamics

Theoretical Prediction of High-Performance Room-Temperature InGaAs/Si Single-Photon Avalanche Diode Fabricated by Semiconductor Interlayer Bonding

2021 ◽  
pp. 1-8
Author(s):  
Shaoying Ke ◽  
Zhixiang Chen ◽  
Jinrong Zhou ◽  
Jinlong Jiao ◽  
Xiaoqiang Chen ◽  
...  
Keyword(s):  
Theoretical Prediction ◽  
High Performance ◽  
Room Temperature ◽  
Single Photon ◽  
Avalanche Diode ◽  
Interlayer Bonding

scholarly journals Zinc removal and recovery from industrial wastewater with a microbial fuel cell: Experimental investigation and theoretical prediction

2021 ◽  
Vol 776 ◽  
pp. 145934
Author(s):  
Swee Su Lim ◽  
Jean-Marie Fontmorin ◽  
Hai The Pham ◽  
Edward Milner ◽  
Peer Mohamed Abdul ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Fuel Cell ◽  
Theoretical Prediction ◽  
Microbial Fuel Cell ◽  
Industrial Wastewater ◽  
Zinc Removal ◽  
Removal And Recovery
Sign in / Sign up

Export Citation Format

Share Document