Iron Oxide Nanoparticles: An Efficient Nano-catalyst

2019 ◽  
Vol 23 (9) ◽  
pp. 994-1004 ◽  
Author(s):  
Tokeer Ahmad ◽  
Ruby Phul ◽  
Huma Khan

Magnetic iron oxide nanoparticles have attracted attention because of their idiosyncratic physicochemical characteristics and vast range of applications such as protein separations, catalysis, magnetic resonance imaging (MRI), magnetic sensors, drug delivery, and magnetic refrigeration. The activity of the catalyst depends on the chemical composition, particle size, morphology and also on the atomic arrangements at the surface. The catalytic properties of iron oxide nanoparticles can be easily altered by controlling the shape, size, morphology and surface modification of nanomaterials. This review is focused on the use of iron oxide as a catalyst in various organic reactions viz. oxidation, hydrogenation, C-C coupling, dihydroxylation reactions and its reusability/recoverability.

2013 ◽  
Vol 12 (06) ◽  
pp. 1330002 ◽  
Author(s):  
K. SHAMILI ◽  
E. M. RAJESH ◽  
R. RAJENDRAN ◽  
S. R. MADHAN SHANKAR ◽  
M. ELANGO ◽  
...  

Magnetic iron oxide nanoparticles are promising material for various biological applications. In the recent decades, magnetic iron oxide nanoparticles (MNPs) have great attention in biomedical applications such as drug delivery, magnetic resonance imaging (MRI) and magnetic fluid hyperthermia (MFH). This review focuses on the colloidal stability and monodispersity properties of MNPs, which pay more attention toward biomedical applications. The simplest and the most promising method for the synthesis of MNPs is co-precipitation. The biocompatible MNPs are more interested in MRI application. This review also apportions synthesis, characterization and applications of MNP in biological and biomedical as theranostics and imaging.


2020 ◽  
pp. 2150008
Author(s):  
Meera Parthasarathy ◽  
Srikanth Adigopula ◽  
Harichandana Gownivari ◽  
Gnanaprasanna Mudhivedu ◽  
Anitha Vasudevan ◽  
...  

Nitration of aromatic compounds is an important industrial process, which creates significant environmental pollution because of the harsh mineral acid catalysts. In this work, we report the synthesis and application of magnetic iron oxide nanoparticles as green catalysts for aromatic nitration. Magnetic iron oxide nanoparticles were synthesized by co-precipitation method and tested for nitration reactions on selected aromatic substrates, phenol, benzaldehyde, methylbenzoate, [Formula: see text]-cresol and [Formula: see text]-cresol. For the nitration reactions, sodium nitrite was used as the nitro-source and hydrogen peroxide as the oxidant. Effect of reaction conditions like, solvent, temperature and microwave treatment were studied. The magnetic nanoparticles were found to be more stable after coating with a carbon shell by a one-pot carbonization method. The reactions were fast with good product yield under solvent-free microwave conditions. The nano-catalyst was recovered magnetically after the reaction and reused for three batches of nitration, without significant loss in catalytic activity. The nanoparticles were characterized using scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometry (XRD) and FTIR spectroscopy.


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