scholarly journals RESEARCH OF MECHANOELECTRIC TRANSFORMATIONS IN ROCK WITH A SMALL DEGREE OF FLUID SATURATION

2018 ◽  
pp. 18-26 ◽  
Author(s):  
I. Ya. Chebotareva ◽  
A. N. Kamshilin
Keyword(s):  
Small Degree ◽  
Fluid Saturation ◽  
Mechanoelectric Transformations

scholarly journals Experimental study of mechanoelectric transformations in low saturated rocks

2019 ◽  
Vol 29 (2) ◽  
pp. 45-53
Author(s):  
I. Ya. Chebotareva ◽  
A. N. Kamshilin
Keyword(s):  
Salt Solution ◽  
Electrical Response ◽  
Rank Correlation ◽  
Response Spectra ◽  
Acoustic Effect ◽  
Polar Fluid ◽  
Fluid Saturation ◽  
Mechanoelectric Transformations ◽  
Lateral Inhomogeneity

The results of study of the electrical response of dry and slightly saturated with salted water (NaCl) or kerosene cores of Berea sandstone to acoustic effect in the frequency range of 0.5–10 kHz are presented herein. A strong lateral inhomogeneity by saturation was created during the experiments. The electrical response is sensitive to the addition of all types of fluid in the rock samples. At the same time, the reaction to the addition of highly concentrated salt solution in the samples is weak, while the reaction to the addition of weak concentrated salt solution and kerosene is strong. A high correlation is observed between the shape of the electrical response spectra of dry and damped cores, up to 0.9. For kerosene, the shape of the spectrum varies greatly, the rank correlation coefficient of the shape of the spectra is 0.3. The fact of a significant increase in electrical response on addition of non-polar fluid (kerosene) to the core is beyond the theoretical framework and may be associated with the creation of strong lateral petrophysical heterogeneity by saturation. The strong sensitivity of the amplitude of the electroseismic response of rocks to very weak but non-homogeneous saturation is interesting for the development of remote methods for determination of the type of fluid saturation of rocks, when searching for minerals and for the development of the methods for prediction of geophysical catastrophes.

Bimolecular Reactions, Transition-State Theory

2018 ◽  
Author(s):  
Niels Engholm Henriksen ◽  
Flemming Yssing Hansen
Keyword(s):  
Transition State ◽  
Saddle Point ◽  
Transition State Theory ◽  
Classical Mechanics ◽  
Small Degree ◽  
State Theory ◽  
Reaction Coordinate ◽  
Partition Functions ◽  
Bimolecular Reactions ◽  
Activated Complex

This chapter discusses an approximate approach—transition-state theory—to the calculation of rate constants for bimolecular reactions. A reaction coordinate is identified from a normal-mode coordinate analysis of the activated complex, that is, the supermolecule on the saddle-point of the potential energy surface. Motion along this coordinate is treated by classical mechanics and recrossings of the saddle point from the product to the reactant side are neglected, leading to the result of conventional transition-state theory expressed in terms of relevant partition functions. Various alternative derivations are presented. Corrections that incorporate quantum mechanical tunnelling along the reaction coordinate are described. Tunnelling through an Eckart barrier is discussed and the approximate Wigner tunnelling correction factor is derived in the limit of a small degree of tunnelling. It concludes with applications of transition-state theory to, for example, the F + H2 reaction, and comparisons with results based on quasi-classical mechanics as well as exact quantum mechanics.

scholarly journals Photon-magnon response to fluid variability and saturation levels in sandstone reservoirs

2020 ◽  
Vol 17 (6) ◽  
pp. 1065-1074
Author(s):  
Abdullah Musa Ali ◽  
Amir Rostami ◽  
Noorhana Yahya
Keyword(s):  
Oil Recovery ◽  
Relative Permittivity ◽  
Wave Interaction ◽  
Heterogeneous Porous Media ◽  
Injection System ◽  
Bragg Grating ◽  
Fibre Bragg Grating ◽  
Core Flooding ◽  
Oil Saturation ◽  
Fluid Saturation

Abstract The need to recover high viscosity heavy oil from the residual phase of reservoirs has raised interest in the use of electromagnetics (EM) for enhanced oil recovery. However, the transformation of EM wave properties must be taken into consideration with respect to the dynamic interaction between fluid and solid phases. Consequently, this study discretises EM wave interaction with heterogeneous porous media (sandstones) under different fluid saturations (oil and water) to aid the monitoring of fluid mobility and activation of magnetic nanofluid in the reservoir. To achieve this aim, this study defined the various EM responses and signatures for brine and oil saturation and fluid saturation levels. A Nanofluid Electromagnetic Injection System (NES) was deployed for a fluid injection/core-flooding experiment. Inductance, resistance and capacitance (LRC) were recorded as the different fluids were injected into a 1.0-m long Berea core, starting from brine imbibition to oil saturation, brine flooding and eventually magnetite nanofluid flooding. The fluid mobility was monitored using a fibre Bragg grating sensor. The experimental measurements of the relative permittivity of the Berea sandstone core (with embedded detectors) saturated with brine, oil and magnetite nanofluid were given in the frequency band of 200 kHz. The behaviour of relative permittivity and attenuation of the EM wave was observed to be convolutedly dependent on the sandstone saturation history. The fibre Bragg Grating (FBG) sensor was able to detect the interaction of the Fe3O4 nanofluid with the magnetic field, which underpins the fluid mobility fundamentals that resulted in an anomalous response.

scholarly journals Transiently increased risk of breast cancer after childbirth: implications for fertility treatments and surrogacy

2020 ◽  
Vol 35 (6) ◽  
pp. 1253-1255
Author(s):  
Zeev Blumenfeld ◽  
Norbert Gleicher ◽  
Eli Y Adashi
Keyword(s):  
Breast Cancer ◽  
Breast Cancer Risk ◽  
Cancer Risk ◽  
Meta Analysis ◽  
Small Degree ◽  
Short Term ◽  
Benefit Ratio ◽  
Professional Societies ◽  
Fertility Treatments ◽  
Increased Risk

Abstract Whereas longstanding dogma has purported that pregnancies protect women from breast cancer, a recent meta-analysis now mandates reconsideration since it reported an actual higher breast cancer risk for more than two decades after childbirth before the relative risk turns negative. Moreover, the risk of breast cancer appears higher for women having their first birth at an older age and with a family history and it is not reduced by breastfeeding. The process of obtaining informed consent for all fertility treatments, therefore, must make patients aware of the facts that every pregnancy, to a small degree, will increase the short-term breast cancer risk. This observation may be even more relevant in cases of surrogacy where women agree to conceive without deriving benefits of offspring from assuming the risk, thus creating a substantially different risk-benefit ratio. Consequently, it appears prudent for professional societies in the field to update recommendations regarding consent information for all fertility treatments but especially for treatments involving surrogacy.

Kimberlite Volcanology: Transport, Ascent, and Eruption

Elements ◽  
2019 ◽  
Vol 15 (6) ◽  
pp. 405-410 ◽  
Author(s):  
J. Kelly Russell ◽  
R. Stephen J. Sparks ◽  
Janine L. Kavanagh
Keyword(s):  
Physical Properties ◽  
Small Degree ◽  
Magma Ascent ◽  
Volcanic Deposits ◽  
And Control

Kimberlite rocks and deposits are the eruption products of volatile-rich, silica-poor ultrabasic magmas that originate as small-degree mantle melts at depths in excess of 200 km. Many kimberlites are emplaced as subsurface cylindrical-to-conical pipes and associated sills and dykes. Surficial volcanic deposits of kimberlite are rare. Although kimberlite magmas have distinctive chemical and physical properties, their eruption styles, intensities and durations are similar to conventional volcanoes. Rates of magma ascent and transport through the cratonic lithosphere are informed by mantle cargo entrained by kimberlite, by the geometries of kimberlite dykes exposed in diamond mines, and by laboratory-based studies of dyke mechanics. Outstanding questions concern the mechanisms that trigger and control the rates of kimberlite magmatism.

scholarly journals Studying the Depth Structure of the Kyrgyz Tien Shan by Using the Seismic Tomography and Magnetotelluric Sounding Methods

Geosciences ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 122
Author(s):  
Irina Medved ◽  
Elena Bataleva ◽  
Michael Buslov
Keyword(s):  
Seismic Tomography ◽  
High Velocity ◽  
Fault Zones ◽  
Magnetotelluric Sounding ◽  
Tien Shan ◽  
High Resistivity ◽  
Low Velocity ◽  
Low Resistivity ◽  
Velocity Models ◽  
Fluid Saturation

This paper presents new results of detailed seismic tomography (ST) on the deep structure beneath the Middle Tien Shan to a depth of 60 km. For a better understanding of the detected heterogeneities, the obtained velocity models were compared with the results of magnetotelluric sounding (MTS) along the Kekemeren and Naryn profiles, running parallel to the 74 and 76 meridians, respectively. We found that in the study region the velocity characteristics and geoelectric properties correlate with each other. The high-velocity high-resistivity anomalies correspond to the parts of the Tarim and Kazakhstan-Junggar plates submerged under the Tien Shan. We revealed that the structure of the Middle Tien Shan crust is conditioned by the presence of the Central Tien Shan microcontinent. It manifests itself as two anomalies lying one below the other: the lower low-velocity low-resistivity anomaly, and the upper high-velocity high-resistivity anomaly. The fault zones, limiting the Central Tien Shan microcontinent, appear as low-velocity low-resistivity anomalies. The obtained features indicate the fluid saturation of the fault zones. According to the revealed features of the Central Tien Shan geological structure, it is assumed that the lower-crustal low-velocity layer can play a significant role in the delamination of the mantle part of the submerged plates.

Structure and microstructure of near infrared-absorbing Au–Au2S nanoparticles

2007 ◽  
Vol 22 (9) ◽  
pp. 2531-2538 ◽  
Author(s):  
Mei Chee Tan ◽  
Jackie Y. Ying ◽  
Gan Moog Chow
Keyword(s):  
Optical Properties ◽  
Surface Segregation ◽  
Near Infrared ◽  
Small Degree ◽  
Core Shell ◽  
Shell Microstructure ◽  
Absorption Bands ◽  
Interfacial Effects ◽  
Nir Absorption ◽  
Structure And Microstructure

Near infrared (NIR) absorbing nanoparticles synthesized by the reduction of HAuCl4 with Na2S exhibited absorption bands at ∼530 nm, and in the NIR region of 650–1100 nm. The NIR optical properties were not found to be related to the earlier proposed Au2S–Au core-shell microstructure in previous studies. From a detailed study of the structure and microstructure of as-synthesized particles in this work, S-containing, Au-rich, multiply-twinned nanoparticles were found to exhibit NIR absorption. They consisted of amorphous AuxS (where x = 2), mostly well mixed within crystalline Au, with a small degree of surface segregation of S. Therefore, NIR absorption was likely due to interfacial effects on particle polarization from the introduction of AuxS into Au particles, and not the dielectric confinement of plasmons associated with a core-shell microstructure.

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