scholarly journals Влияние редкоземельных металлов на стеклообразующую способность и кристаллизацию аморфных сплавов CoFeSiBNb

2022 ◽  
Vol 92 (1) ◽  
pp. 58
Author(s):  
Б.А. Русанов ◽  
В.Е. Сидоров ◽  
P. Svec ◽  
D. Janickovic ◽  
В.И. Ладьянов ◽  
...  
Keyword(s):  
Amorphous Alloys ◽  
Crystallization Process ◽  
A Priori ◽  
Glass Forming Ability ◽  
Analysis Method ◽  
Thermal Analysis Method ◽  
Glass Forming ◽  
Planar Flow Casting ◽  
Rare Earth Addition ◽  
Two Stages

In present work amorphous alloys Co48Fe25Si4B19Nb4-R (R = Nd, Sm, Tb, Yb) were obtained by planar flow casting in the form of ribbons with 3-5 mm wide and 35-45 μm thickness. It was found that crystallization process goes into two stages and depends on the used rare-earth addition and its content in the alloy by differential thermal analysis method. Glass-forming ability criteria were calculated. It is shown that paramagnetic Curie temperature of alloys in liquid state can be used as their a-priori criterion of glass-forming ability.

Formation, and mechanical and magnetic properties of bulk ferromagnetic Fe-Nb-B-Y-(Zr, Co) alloys

2006 ◽  
Vol 21 (4) ◽  
pp. 1019-1024 ◽  
Author(s):  
J.M. Park ◽  
J.S. Park ◽  
D.H. Kim ◽  
J-H. Kim ◽  
E. Fleury
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Amorphous Alloys ◽  
Amorphous Structure ◽  
Glass Forming Ability ◽  
Partial Replacement ◽  
Soft Magnetic ◽  
Glass Forming ◽  
Mold Casting ◽  
Co Alloys

Fe element was partially substituted by Zr and Co in an attempt to enhance the glass-forming ability, and mechanical and soft magnetic properties of Fe74-xNb6B17Y3(Zr, Co)x (x = 3, 5, 8) amorphous alloys. Both partial replacements resulted in the enhancement of the glass-forming ability, and 3-mm diameter rods with a fully amorphous structure were prepared by a copper mold casting method. Zr and Co containing Fe-based bulk amorphous alloys exhibited high compressive fracture strength of about 4 and 3.5 GPa, respectively. However, Zr and Co induced different effects on the magnetic properties. Whereas the partial replacement of Fe by Zr was found to decrease dramatically the saturation magnetization, the partial replacement of Fe by Co provided an increase of about 25% of the saturation magnetization.

scholarly journals Survey of BGFA Criteria for the Cu-Based Bulk Amorphous Alloys

2011 ◽  
Vol 2011 ◽  
pp. 1-5 ◽  
Author(s):  
D. Janovszky ◽  
K. Tomolya ◽  
M. Sveda ◽  
A. Roosz
Keyword(s):  
Amorphous Alloys ◽  
Critical Thickness ◽  
Glass Forming Ability ◽  
Bulk Glass ◽  
The Real ◽  
Bulk Amorphous Alloys ◽  
Glass Forming ◽  
Versus Plot ◽  
Mismatch Condition

To verify the effect of composition on the bulk glass forming ability (BGFA) of Cu-based alloys, properties have been collected from the literature (~100 papers, more than 200 alloys). Surveying the BGFA criteria published so far, it has been found that the atomic mismatch condition of Egami-Waseda is fulfilled for all the Cu-based BGFAs, the value being above 0,3. The Zhang Bangwei criterion could be applied for the binary Cu-based alloys. The Miracle and Senkov criteria do not necessarily apply for Cu based bulk amorphous alloys. The critical thickness versus plot of Lu and Liu extrapolates to , somewhat higher than the 0.33 value found in other BGFA alloys. The Park and Kim parameter correlates rather poorly with the critical thickness for Cu based alloys. The Cheney and Vecchino parameter is a good indicator to find the best glass former if it is possible to calculate the exact liquids projection. In 2009 Xiu-lin and Pan defined a new parameter which correlates a bit better with the critical thickness. Based on this survey it is still very difficult to find one parameter in order to characterize the real GFA without an unrealized mechanism of crystallization.

scholarly journals Crystallization Behavior of Al70Fe12.5V12.5Nb5 Amorphous Alloy Formed by Mechanical Alloying

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 383 ◽  
Author(s):  
Xuan Liu ◽  
Xingfu Wang ◽  
Yongli Si ◽  
Xiaokang Zhong ◽  
Fusheng Han
Keyword(s):  
Amorphous Alloy ◽  
Mechanical Alloying ◽  
Amorphous Alloys ◽  
Crystallization Behavior ◽  
Supercooled Liquid ◽  
Supercooled Liquid Region ◽  
Glass Forming Ability ◽  
Liquid Region ◽  
Application Field ◽  
Glass Forming

In this study, the formation and crystallization of the Al70Fe12.5V12.5Nb5 amorphous alloys has been investigated. The addition of Nb enhances the supercooled liquid region and glass forming ability of the Al-Fe-V amorphous alloys. The Al70Fe12.5V12.5Nb5 amorphous alloy exhibits two distinct crystallization steps and a large supercooled liquid region at more than 100 K. Kissinger and Ozawa analyses showed that the two activation energies for crystallization (Ex) were estimated to be 366.3 ± 23.9 and 380.5 ± 23.9 kJ/mol. Large supercooled liquid regions are expected to gain an application field of Al-based amorphous alloys.

Structure and Mechanical Behaviour of Al-Sc Alloys

2006 ◽  
Vol 519-521 ◽  
pp. 567-572
Author(s):  
Yu.V. Milman
Keyword(s):  
Corrosion Resistance ◽  
Aluminum Alloys ◽  
Mechanical Behavior ◽  
Mechanical Behaviour ◽  
Amorphous Alloys ◽  
High Strength ◽  
Glass Forming Ability ◽  
Superplastic Behavior ◽  
Glass Forming

The review of the works devoted to the influence of scandium on the structure, mechanical behavior and corrosion resistance of aluminum alloys is given. The wrought thermally non-hardenable alloys of Al- Mg system and thermally hardenable high-strength alloys of Al-Zn- Mg-Cu system are considered. The influence of Sc on the glass forming ability of amorphous alloys and on the superplastic behavior of aluminum alloys is discussed.

Effects of Microalloying on Glass Forming Ability and Thermodynamic Fragility of Cu-Pr-Based Amorphous Alloys

2007 ◽  
Vol 25 (5) ◽  
pp. 615-618 ◽  
Author(s):  
Li Xuelian ◽  
Bian Xiufang ◽  
Guo Jing ◽  
Zhao Yan ◽  
Wu Yuqin ◽  
...  
Keyword(s):  
Amorphous Alloys ◽  
Glass Forming Ability ◽  
Glass Forming
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