scholarly journals STABILIZATION OF DRY SLUDGE OF LIQUID WASTE OF LEATHER TREATMENT BY USING FLY ASH

2010 ◽  
Vol 5 (1) ◽  
pp. 36-40
Author(s):  
Cahya Widiyati ◽  
Herry Poernomo

The experiment of solidification of dry sludge of liquid waste of leather treatment are containing chrome (Cr) by using fly ash has been done.  The experiment objective are immobilize Cr in the solid waste by using pozzoland cement was made of fly ash in order to stable in the repository.  The experiment were carried out by solidification of solid waste are containing total chrome of 1480.5 mg/kg sum of 2 - 10 weight % of (water + pozzoland cement) by using pozzoland cement was made from the mixture of fly ash and calcite were burned at 1000 oC temperature for 2 hours.  The characterization of the solid composite of stabilization result consist of the compressive strength test and the leaching test by American Nuclear Society (ANS-16.1) method.  The experiment result were shown that pozzoland cement  can binding solid waste sum of 10 weight % of (water + pozzoland cement) became the composite of waste concrete with the compressive strength of 577 ton/m2 and the chrome leaching test for 14 days of 0.059 mg/l.  The composite of waste concrete according to Bapedal rule for solidification of toxic waste with minimum compressive strength of 10 ton/m2 and maximum leached chrome of 5 mg/L.   Keywords: stabilization, solid waste, leather treatment, fly ash.

2018 ◽  
Vol 195 ◽  
pp. 01023 ◽  
Author(s):  
Ari Widayanti ◽  
Ria Asih Aryani Soemitro ◽  
Hitapriya Suprayitno ◽  
Januarti Jaya Ekaputri

Fly ash is a by-product obtained from coal combustion process. Some of the utilization of fly ash is to produce geopolymer products which have high compressive strength, fire, chemical resistance. This paper proposes fly ash from unit 1-7 Suralaya Power Plant Indonesia. The aims of this study are to obtain characterization of fly ash and mechanical properties of geopolymer paste based on variations of the alkali activator ratio. The method was based on previous research and laboratory investigation. XRF and compressive strength were analysed in this study. Alkali activator was obtained from NaOH and Na2SiO3 mixture. The ratio of Na2SiO3 to NaOH was in the range of 0.5-2.5. Geopolymer paste was casted in acrylic cylinders with a diameter of 2 cm and a height of 4 cm. The curing was conducted at room temperature until the day for the compressive strength test at 28 days. The result showed that the fly ash is classified as F class. Increasing the alkali activator ratio influenced the strength. The best composition of geopolymer paste is made with NaOH 8M, and the mass ratio of Na2SiO3 to NaOH is 2.5. This composition produced compressive strength of 98.6 MPa.


2010 ◽  
Vol 150-151 ◽  
pp. 1599-1602
Author(s):  
Ji Xing Xie ◽  
Jun Jing Chen ◽  
Jian Zhong Xu

The desulfurization ash, fly ash and metakaolin were uesd to prepare the geopolymer. Compressive strength test demonstrated that the optimum mass ratio of desulfurization ash, fly ash and metakaolin was 30:55:10 and the max strength reached 17.3 MPa. The XRD and SEM show that there is not new crystalline phase. The main crystalline phase of the matrix is non-reacted mullite in the fly ash. It was suggested that the emission of CO2 and SO2 were rehabited from geopolymer by analysis of those compositions volatilizing using TG/MS.


2016 ◽  
Vol 2016 ◽  
pp. 1-10
Author(s):  
Lijun Zhao ◽  
Hanshuang Xiao ◽  
Baodong Wang ◽  
Qi Sun

In recent years, one type of alumina rich fly ash (ARFA) with about 50 wt% of alumina has been extensively investigated for alumina extraction in China. Due to the silica in ARFA, alumina extraction would have to generate a huge amount of solid waste. There is a growing interest in the glasses in ARFA, because they are composed mainly of silica and could be removed prior to alumina extraction. In this work, the glasses in ARFA have been investigated by chemical methods, that is, acid and base digestions. The chemical compositions have been measured by XRF for ARFA from the digestion processes. The K2O standard, XRD, and FTIR spectroscopies were successfully used to define the digestions processes, and size analysis and SEM-EDX provided rich information on particle transformations. As a result, acid and base digestion methods were found to produce very similar results for the glasses in ARFA. The K2O standard was attributed to the formation of glasses by illites, and TiO2and Fe2O3were proposed to originate from ilmenite in alumina rich coals (ARC). Some implications of the results were also discussed for the alumina extraction from ARFA.


2020 ◽  
Vol 165 ◽  
pp. 03029
Author(s):  
Jiangong Yang

Through comparatively analyzing the impermeability and compressive strength test data of nano CaCO3 concrete with different content, this paper puts forward the method of optimizing the durability of nano CaCO3 concrete, and studies the influence of the content of fly ash on the durability of nano CaCO3 concrete on this basis, so as to provide a reference for improving the durability of concrete, so as to improve the recycling and reusing efficiency of building materials, and accelerate the practical application of nano CaCO3 concrete in engineering.


Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 141
Author(s):  
Zhengzhen Yao ◽  
Zhonghui Xu ◽  
Qin Shuai ◽  
Xiaoyue Chen ◽  
Zao Jiang ◽  
...  

This study aims to explore the solidification performance of municipal solid waste incineration fly ash (MSWIFA) through co-mechanical treatment with circulation fluidized bed combustion fly ash (CFBCFA). The mineral characterization, physical properties, and leaching resistance of the solidified bodies are investigated by X-ray diffraction spectroscopy (XRD), Fourier transform infrared spectroscopy (FT-IR), Thermogravimetry-differential thermal analysis (TG-DTA), compressive strength, porosity, and leaching test, respectively. C–S–H, ettringite (AFt), and Friedel’s salt (FS) are the predominant hydrate products in the CFBCFA based solidified bodies, which are similar to the cement based solidified bodies. However, CFBCFA based solidified bodies exhibit higher compressive strength (36.7 MPa) than cement based solidified bodies (11.28 MPa), attributing to the three reasons: lower porosity and more compact internal structure of CFBCFA based solidified bodies; large amounts of Ca(OH)2 originating from MSWIFA are conducive to promoting the hydration reaction extent and compressive strength of the CFBCFA based solidified bodies; excessive Ca(OH)2 would cause compressive strength deterioration for the cement based solidified bodies. The heavy metals (Zn, Cu, Cr, Cd, and Pb) concentrations in the extraction solution of the CFBCFA based solidified bodies are far below the requirements of Chinese National Standard GB 5085.3-2007. The solidification of MSWIFA through co-mechanical treatment could be an ideal substitute for cement solidification technology.


2011 ◽  
Vol 255-260 ◽  
pp. 3404-3410
Author(s):  
Shuang Xi Li ◽  
An Quan Xu ◽  
Xin Jun Tang ◽  
Quan Hu

It takes on the technical and economic double benefits that fly ash taking the place of cement. However, water/binder of modern concrete is generally low; the research on the concrete performance which is based on large water/binder is no longer suitable for analysis of modern concrete. As to this problem, using different proportions of W/B and FA dosage as influencing factors, specimen is compounded for the compressive strength test. Then, mechanical properties of HPC are studied systematically. Based on this, macro-performance is analyzed from a micro-mechanism point of view through taking the electron micrograph. As the study shows, strength of HPC mixed with fly ash has low characteristics at early period while high ones at later period. At later hydration, fly ash effect plays a significant role, the growth rate of concrete strength increases as the increase of FA dosage. Compressive strength of concrete decreases as the increase of W/B and FA dosage. When the W/B is high, compressive strength is not sensitive to the change of W/B and FA dosage; but when the W/B decreases from 0.30 to 0.25, the concrete strength transition occurs. The influence of W/B on concrete compressive strength is more significant than that of the FA dosage; in the preparation of HPC, fly ash can be added more and cement is added less relatively by decreasing the W/B, displaying the role of micro-aggregate filling and modification, improving the strength and other performance of concrete. The study on micro-mechanism proves well the macro-phenomena above.


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