scholarly journals CATALYST PROCESSING AND RECYCLING

2021 ◽  
Vol 7 (3) ◽  
pp. 99-104
Author(s):  
Jakub Kovalčík ◽  
Martin Straka ◽  
Peter Kačmáry ◽  
Tomáš Pavlík

Discussed auto catalysts contain interesting quantities of platinum noble metals, palladium and rhodium according to the type of auto catalyst, thereby becoming a possible source of these metal aims to acquaint themselves with catalysts in general, their history and last but not least the possibilities of processing and obtaining noble metals for further use. The article deals with knowledge at the theoretical level of use of methods in processing depleted catalysts. It is pyrometallurgical and hydrometallurgical methods. The platinum group metals (PGMs) palladium, platinum, and rhodium represent the key materials for automotive exhaust gas treatment. Since there are currently no adequate alternatives, the importance of these metals for the automotive industry is steadily rising. The high value of PGMs in spent catalysts justifies their recycling. The state-of the-art technology is to melt the ceramic carrier and collect the precious fraction in a liquid metal bath. As the feed material has quite high melting points, huge amounts of energy are required for this process. Hydrometallurgical treatments of the spent catalysts offer the possibility to recycle the PGMs with less energy and time demands. Moreover, automotive catalysts contain further valuable materials to improve the exhaust gas treatment. These compounds, like cerium oxide, cannot be recovered in pyrometallurgical processes.

Alloy Digest ◽  
1979 ◽  
Vol 28 (4) ◽  

Abstract CERROBASE Alloy is a bismuth-lead eutectic alloy that melts at 255 F (124 C). It is characterized by initial shrinkage followed by slow growth. Its low melting temperature and/or growth-shrinkage characteristics make it a useful industrial material. Among many applications, it is used for (1) anchoring inserts in wood, metal or plastics, (2) drop-hammer dies, (3) duplicate patterns in pottery and foundry, and (4) liquid metal bath for heat treating. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on casting, forming, heat treating, and machining. Filing Code: Bi-11. Producer or source: Cerro Metal Products.


1965 ◽  
Vol 38 (4) ◽  
pp. 782-790
Author(s):  
G. L. Hall ◽  
J. D. Rigby ◽  
J. W. Liska

Abstract A simple, reliable apparatus for measuring stress-strain properties of vulcanizates at temperatures up to at least 800° F has been developed. The heating medium is a molten metal bath which provides uniform temperature distribution and rapid heat transfer while excluding atmospheric oxygen. Ultimate tensile strengths are in excellent agreement with those obtained in conventional air-oven tests. Stress relaxation tests show the effects of excluding atmospheric oxygen from the specimens. Somewhat higher ultimate elongations are obtained in the liquid-bath than in air-oven apparatus, for which possible reasons are suggested. Results on vulcanizates of heat-resistant polymers demonstrate that retention of physical properties at 500° F or 600° F cannot be safely predicted from data obtained at 400° F. The curing system, as well as the base polymer, is very important to high temperature resistance. In both Diene and butyl rubber compounds, for example, resin cures were superior in this respect to more conventional curing systems.


2004 ◽  
Vol 54 (3) ◽  
pp. 193-200 ◽  
Author(s):  
Henrik Birgersson ◽  
Lars Eriksson ◽  
Magali Boutonnet ◽  
Sven G. Järås
Keyword(s):  

2019 ◽  
Vol 115 (8) ◽  
pp. 083702 ◽  
Author(s):  
Xi Zhao ◽  
Lixiang Yang ◽  
Yujie Ding ◽  
Pengju Zhang ◽  
Jing Liu

1993 ◽  
Author(s):  
Herbert R. Zweig ◽  
Stanley Fischler ◽  
William R. Wagner

Nanomaterials ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1582 ◽  
Author(s):  
S. Dittrich ◽  
S. Kohsakowski ◽  
B. Wittek ◽  
C. Hengst ◽  
B. Gökce ◽  
...  

PtPd catalysts are state-of-the-art for automotive diesel exhaust gas treatment. Although wet-chemical preparation of PtPd nanoparticles below 3 nm and kg-scale synthesis of supported PtPd/Al2O3 are already established, the partial segregation of the bimetallic nanoparticles remains an issue that adversely affects catalytic performance. As a promising alternative, laser-based catalyst preparation allows the continuous synthesis of surfactant-free, solid-solution alloy nanoparticles at the g/h-scale. However, the required productivity of the catalytically relevant size fraction <10 nm has yet to be met. In this work, by optimization of ablation and fragmentation conditions, the continuous flow synthesis of nanoparticles with a productivity of the catalytically relevant size fraction <10 nm of >1 g/h is presented via an in-process size tuning strategy. After the laser-based preparation of hectoliters of colloid and more than 2 kg of PtPd/Al2O3 wash coat, the laser-generated catalysts were benchmarked against an industry-relevant reference catalyst. The conversion of CO by laser-generated catalysts was found to be equivalent to the reference, while improved activity during NO oxidation was achieved. Finally, the present study validates that laser-generated catalysts meet the size and productivity requirements for industrial standard operating procedures. Hence, laser-based catalyst synthesis appears to be a promising alternative to chemical-based preparation of alloy nanoparticles for developing industrial catalysts, such as those needed in the treatment of exhaust gases.


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