The Use of Froth Flotation for Selective Separation of Plastic Wastes from Soil

2021 ◽  
Vol 6 (4) ◽  
pp. 135-138
Author(s):  
Kofi Moro ◽  
Dorothy A. Dechie

  The Use of Froth Flotation for Selective Separation of Plastic Wastes from Soil   Kofi Moro and Dorothy A. Dechie   Abstract — In recycling of plastics, unless the goal is to form composites or materials having special properties, it is not advisable to mix plastics of different kinds because of the differences in their molecular weights and chain lengths. Hence, there is the need to separate these plastics when they are mixed before recycle can be done. This project investigated the selective separation of Polypropylene (PP), Polystyrene (PS) and Polyethylene terephthalate (PET) plastics out of soils using froth flotation. Pulverized samples were prepared from post-consumer plastic sources (PP, PS and PET) and soil and mixed uniformly to form a composite sample. The composite sample was subjected to froth flotation. Two tests were performed. A first test, where there was no addition of a depressant (tannic acid), and a second test, where there was addition of tannic acid to depress some of the plastics in order to selectively separate them. Recoveries from each test work indicated that, plastics are naturally hydrophobic and can be floated out of soils without modifying their surface properties. However, selective separations of the plastics were achieved when tannic acid was used to modify the surface properties of the plastic types.

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1411 ◽  
Author(s):  
Martin Cvek ◽  
Miroslav Mrlik ◽  
Jakub Sevcik ◽  
Michal Sedlacik

A novel concept based on advanced particle-grafting technology to tailor performance, damping, and surface properties of the magnetorheological elastomers (MREs) is introduced. In this work, the carbonyl iron (CI) particles grafted with poly(trimethylsilyloxyethyl methacrylate) (PHEMATMS) of two different molecular weights were prepared via surface-initiated atom transfer radical polymerization and the relations between the PHEMATMS chain lengths and the MREs properties were investigated. The results show that the magnetorheological performance and damping capability were remarkably influenced by different interaction between polydimethylsiloxane chains as a matrix and PHEMATMS grafts due to their different length. The MRE containing CI grafted with PHEMATMS of higher molecular weight exhibited a greater plasticizing effect and hence both a higher relative magnetorheological effect and enhanced damping capability were observed. Besides bulk MRE properties, the PHEMATMS modifications influenced also field-induced surface activity of the MRE sheets, which manifested as notable changes in surface roughness.


2015 ◽  
Vol 1718 ◽  
pp. 97-102 ◽  
Author(s):  
Toralf Roch ◽  
Konstanze K. Julich-Gruner ◽  
Axel T. Neffe ◽  
Nan Ma ◽  
Andreas Lendlein

ABSTRACTPolymer-based therapeutic strategies require biomaterials with properties and functions tailored to the demands of specific applications leading to an increasing number of newly designed polymers. For the evaluation of those new materials, comprehensive biocompatibility studies including cyto-, tissue-, and immunocompatibility are essential. Recently, it could be demonstrated that star-shaped amino oligo(ethylene glycol)s (sOEG) with a number average molecular weight of 5 kDa and functionalized with the phenol-derived moieties desaminotyrosine (DAT) or desaminotyrosyl tyrosine (DATT) behave in aqueous solution like surfactants without inducing a substantial cytotoxicity, which may qualify them as solubilizer for hydrophobic drugs in aqueous solution. However, for biomedical applications the polymer solutions need to be free of immunogenic contaminations, which could result from inadequate laboratory environment or contaminated starting material. Furthermore, the materials should not induce uncontrolled or undesired immunological effects arising from material intrinsic properties. Therefore, a comprehensive immunological evaluation as perquisite for application of each biomaterial batch is required. This study investigated the immunological properties of sOEG-DAT(T) solutions, which were prepared using sOEG with number average molecular weights of 5 kDa, 10 kDa, and 20 kDa allowing analyzing the influence of the sOEG chain lengths on innate immune mechanisms. A macrophage-based assay was used to first demonstrate that all DAT(T)-sOEG solutions are free of endotoxins and other microbial contaminations such as fungal products. In the next step, the capacity of the different DAT(T)-functionalized sOEG solutions to induce cytokine secretion and generation of reactive oxygen species (ROS) was investigated using whole human blood. It was observed that low levels of the pro-inflammatory cytokines interleukin(IL)-1β and IL-6 were detected for all sOEG solutions but only when used at concentrations above 250 µg·mL-1. Furthermore, only the 20 kDa sOEG-DAT induced low amounts of ROS-producing monocytes. Conclusively, the data indicate that the materials were not contaminated with microbial products and do not induce substantial immunological adverse effectsin vitro,which is a prerequisite for future biological applications.


2019 ◽  
Vol 476 ◽  
pp. 452-459 ◽  
Author(s):  
V. Satulu ◽  
B. Mitu ◽  
A.M. Pandele ◽  
S.I. Voicu ◽  
L. Kravets ◽  
...  

1967 ◽  
Vol 34 (2) ◽  
pp. 115-121 ◽  
Author(s):  
Ragnar Ryhage

SummaryThe identification and approximate quantitative determination of methyl esters of fatty acids from commercial butterfat was obtained with a combined gaschromatograph-mass spectrometer instrument. Fifty-two components, straight chain saturated and unsaturated, as well as branched chain compounds, were identified. Seven monomethyl saturated fatty acid methyl ester isomers were identified for both C15 and C17, i.e. with chain lengths of 14 and 16 carbon atoms, respectively. Multibranched fatty acids with molecular weights of 326 and 368 were found. The results were obtained in one day.


2006 ◽  
Vol 2 (4) ◽  
pp. 170-174 ◽  
Author(s):  
Bing Shi ◽  
Hong Liang ◽  
Thomas B. Kuhn ◽  
Lawrence K. Duffy

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 5 ◽  
Author(s):  
Haruyuki Okamura ◽  
Masashi Yamagaki ◽  
Kyohei Nakata

An analysis of the network structures in thiol-ene UV curing resins was carried out using reworkable resins composed of di(meth)acrylate monomers having tertiary ester linkages. The effect of the functionality of the thiols, the functional ratio of the thiol and ene functions, their conversions and curing atmosphere on the chain lengths was discussed. A mixture of (meth)acrylates, thiol compounds, a photoradical initiator, and a photoacid generator was cured by irradiation at 365 nm. The cured samples were degraded by heating after irradiation at 254 nm. Size exclusion chromatography (SEC) and 1H NMR analyses of the degraded samples were carried out after the methylation. The crosslinking conditions strongly affected the network structures. The degraded samples have molecular weights between 250 and 2700. The molecular weights of the degraded resins increased with the functionality of the thiol compounds. The chain length dependence suggests that thiol compounds with a high functionality have a low reactivity due to steric hindrance. The chain lengths of the degraded networks were nearly proportional to the concentration of the (meth)acrylate monomers. The addition of reactive diluents enhanced the reactivity and increased the chain length.


Author(s):  
Maie A. Fadel ◽  
Nagwa A. Kamel ◽  
Mirhane M. Darwish ◽  
Salwa L. Abd El-Messieh ◽  
Kamal N. Abd-EL-Nour ◽  
...  

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