Physical and chemical properties of the mantle minerals explored by high-pressure and high-temperature experiments

2019 ◽  
Vol 48 (1) ◽  
pp. 36-45
Author(s):  
Ryosuke SINMYO
2014 ◽  
Vol 521 ◽  
pp. 658-661
Author(s):  
Lei Yang ◽  
Shang Guan Ju ◽  
Yu Kun Gao ◽  
Yan Hui Hu

Physical and chemical properties are closely related to desulfurization, regeneration performance and cycle stability for high temperature coal gas desulfurizer. This review focuses on influence rules of changes in regeneration atmosphere, temperature and space velocity on physical and chemical properties. A large number of experimental researches have shown that regeneration atmosphere, regeneration temperature, space velocity have an important influence on mechanical strength, active component and texture change for high temperature coal gas desulfurizer. The different regeneration atmosphere obviously results in different active ingredients for desulfurization sorbent after regeneration, and regeneration at a higher regeneration temperature will easily cause desulfurizer sintering, as well as small regeneration space velocity can lead to the formation of sulfates. In order to make the circulatory system of sulfidation-regeneration-sulfidation need to the requirements in industrial application, the further research of influence rules of regeneration condition on physical and chemical properties will be crucial.


Author(s):  
Hongtao Liu ◽  
Yiyang Liu ◽  
Tao Su

Molten salts were widely used in nuclear and solar power field due to the excellent heat transfer and storage. Molten fluoride salts were selected as primary and secondary coolants in the Molten Salt Reactor Experiment (MSRE) developed by Oak Ridge National Laboratory (ORNL). Therefore, it is dramatically important to study the physical and chemical properties of molten fluoride salts that impact on the design of reactor core and thermohydraulics. The molecular structure directly determines the physical and chemical properties of matter, so it is also essential to study the structure of molten salts. Spectroscopy has been proven to be a very useful tool for investigating molten salts structures. However, the standard instrument is inapplicable for measurement of the high temperature molten salts, especially for molten fluoride salts. To obtain the ultraviolet-visible (UV-Vis) absorption spectra of molten salts at high temperature, an instrument was designed to study the structures of molten salts in situ. The instrument is mainly composed of a vertical pit furnace connecting with a glovebox and an assembled cuvette which can operate from room temperature up to 800°C. The assembled cuvette is made of Hastelloy C/N as the main body with a reverse ‘T’ contour and diamond or crystalline CaF2 etc. as the window plates, so it can withstand the corrosion produced by the sample and allow the interest light passing through. The effective spectral range of this instrument is from 200 to 1000 nm. Performances of the instrument are testified by spectral studies on water under room temperature and molten salts under high temperature.


2002 ◽  
Vol 730 ◽  
Author(s):  
Ronald A. Guidotti ◽  
Frederick W. Reinhardt ◽  
Jinxiang Dai ◽  
David E. Reisner

AbstractIn this paper, we report on the preparation of synthetic FeS2 and CoS2 using a relatively inexpensive aqueous process. This avoids the material and handling difficulties associated with a high-temperature approach. An aqueous approach also allows ready scale-up to a pilot-plant size facility. The FeS2 and CoS2 were characterized with respect to their physical and chemical properties. The synthetic disulfides were incorporated into catholyte mixes for testing in single cells and batteries over a range of temperatures. The results of these tests are presented and compared to the performance of natural FeS2 (pyrite) and a commercial source of CoS2.


Author(s):  
B. W. Chappell

ABSTRACTMost granites result from partial melting within the crust. Granite melts produced at the lowest temperatures of partial melting mainly comprise close to equal amounts of the haplogranite components Qz, Ab and Or, with H2O. Many felsic granites were formed by partial melting under such conditions and are low-temperature types, with crystals of zircon and other restite minerals present in the initial magma. Such magmas evolve in composition, at least initially, through fractionation of that restite. If one of the four haplogranite components either becomes depleted or too low in amount to contribute further to the melt, then melting may proceed to higher temperatures without a contribution from that component. Melting will advance to significantly higher temperatures if there is a critical deficiency in one or more components and a high-temperature granite magma forms, in which zircon is completely soluble. Such magmas are extracted from the source in a completely molten state and may evolve by fractional crystallisation. They are monzonitic, tonalitic or A-type, depending on whether the critical deficiency occurred in the Qz, Or or H2O component. If the Ab component is critically deficient, as in pelitic rocks, the rocks may be infertile for granite production. The control that source rock compositions exert on both the physical and chemical properties of granite magmas provides a unifying element in granite gen


2012 ◽  
Vol 519 ◽  
pp. 164-168
Author(s):  
Fang Gao

High pressure NiH2 battery is a kind of secondary power consists of a nickel electrode and the hydrogen electrode with the quality of high stability, long service life, overcharge and overdischarge resisting advantages, the United States, Russia and France have launched high pressure NiH2 batteries and has been widely used in satellite, space stations and other areas. Performance of strength, Ability of Antioxidation, Chemical Durability, Dimensional Stability and akali retaition ability were strictly required by NiH2 battery’s seporatosr, zirconia cloth seporator can satisfy the use requirement in many aspects. Physical and chemical properties of areo density, average thickness, alkaline retention ability, alkaline absorbing ratio and battery performance were tested in this paper.


RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 64861-64870 ◽  
Author(s):  
R. O. Fuentes ◽  
L. M. Acuña ◽  
C. A. Albornoz ◽  
A. G. Leyva ◽  
N. Sousa ◽  
...  

Nanocrystalline Ni-substituted ceria is highly reversible and it has an extraordinary redox cyclicality associated to a high thermochemical stability of the material at relatively high temperature.


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