Global-scale emergence of continental crust during the Mesoarchean–early Neoarchean

The timing of the emergence of subaerial landmasses is equivocally constrained as post-Archean and continues to be a much-debated issue. In this study, we document exceptionally 18O-depleted (δ18O < 4.7‰) Mesoarchean to early Neoarchean magmatism in India that shows a similarity with the coeval low-δ18O magmas reported from Australia, South America, and northern China. Such global-scale low-δ18O magmatism would require high-temperature meteoric water–rock interaction in the uppermost crust synchronous with magma generation, necessitating the emergence of a substantial volume of the continental crust. The timing of this low-δ18O magmatism coincides with the development of extensive, subaerial large igneous provinces, a downward shift in δ18O and Δ17O values in pelitic rocks, the rise of normalized 87Sr/86Sr in seawater, and an intermittent upsurge in the proportion of atmospheric oxygen. We propose that the emergence of substantial volumes of continental crust initiated at ca. 3.2 Ga and peaked at 2.8–2.6 Ga, facilitating the generation of globally distributed low-δ18O magmas, and this event can be linked to the first appearance of atmospheric oxygen.

Influence of crustal lithology and the thermal state on microseismicity in the Wakayama region, southern Honshu, Japan

Here we investigate the influence of the lithology and thermal state of the upper crust on earthquake distributions beneath the Wakayama region, southern Honshu, Japan, to better understand the influence of crustal conditions on regional seismogenesis. The earthquakes are concentrated in the deeper sections of mafic belts and shallower sections of pelitic belts, based on a comparison of relocated hypocenters and estimated subsurface geological structures. We compare the frictional properties of pelitic rocks and basalt, as obtained from petrological experiments, with the hypocenter depth distributions in pelitic and mafic belts to assess the control of crustal lithology on the depth extent of regional seismicity. The earthquake distributions are consistent with the temperature ranges over which the respective rock types are expected to exhibit a velocity-weakening behavior, based on the petrological experiments. The results suggest that the occurrence of shallow intraplate earthquakes is controlled by the temperature- and lithology-dependent friction of the upper crust.

Metamorphic facies: A review and some suggestions for changes

ABSTRACT The concept of metamorphic facies has been used as a tool in the interpretation of metamorphic rocks for almost 100 years. The preferred definition is a set of mineral assemblages which are repeatedly associated in space and time. Equilibrium or physical conditions (pressure-temperature) should not be part of the definition. The emphasis has always been on identification of the minerals with the petrographic microscope. Chemical analyses of the minerals using the electron microprobe is not necessary. The original definition of metamorphic facies used the metamorphic mineralogy of metabasic rocks. This bulk composition is not useful for the definition of all metamorphic facies. Several critical minerals in metabasic rocks cannot be readily identified with a petrographic microscope (albite versus oligoclase and actinolite versus hornblende). A revised set of metamorphic facies is proposed and mineral assemblages in both metabasic and pelitic rocks are outlined to provide definitions of the individual facies. Metamorphic facies should not be used to give quantitative estimates of P-T conditions. Only relative P-T can be estimated. The interpretation of “equilibrium” in metamorphic facies can be modeled using the Gibbs phase rule and simple assumptions about phases and components. This leads to an interpretation that metamorphic facies could represent divariant or higher variance equilibrium.

PRELIMINARY REPORT ON THE LACUSTRINE STRATA OF THE SANFRANCISCANA BASIN IN NORTHERN MINAS GERAIS, BRAZIL

We report new data on the geology and the fossil record of the Sanfranciscana Basin in sites to the north of the traditionally explored localities within Minas Gerais. The strata in the new explored area are formed by distinct lithologies, encompassing pelitic rocks with caliche levels and metric bodies of cross-bedded sandstone towards the top, similar to the fluviolacustrine beds of the Areado Group in the southern portions of the basin. Also similar to other regions of the São Francisco Craton, the deposits of the Sanfranciscana Basin studied herein lie discordantly to the rocks of the Bambuí Basin. We preliminarily report neopterygian fish scales, little informative archosaurian bones and an association of the ostracods Ilyocypris- Fossocytheridea. This ostracod association is registered for the first time in the Cretaceous of the Sanfranciscana Basin. The ostracods have been collected from the lacustrine, vertebrate-bearing rocks cropping out in Lagoa dos Patos and Coração de Jesus. The cytherideid Fossocytheridea assigns a minimal Aptian age to its bearing rocks. Its association with Ilyocypris was also reported in Upper Cretaceous oligohaline paleoenvironments in Brazil and Argentina, indicating similar depositional conditions to the strata reported in this paper. The putative affinities of the specimens of the Sanfranciscana Basin with F. ventrotuberculata, and their association with Ilyocypris, raise the hypothesis of a younger age for some levels of that basin in northern Minas Gerais, perhaps ranging into the Late Cretaceous. Keywords: Ostracoda, Archosauria, Areado Group, Cretaceous, Gondwana

C- and N-bearing Species in Reduced Fluids in the Simplified C–O–H–N System and in Natural Pelite at Upper Mantle P–T Conditions

C- and N-bearing species in reduced fluids weree studied experimentally in C–O–H–N and muscovite–C–O–H–N systems and in natural carbonate-bearing samples at mantle P–T parameters. The experiments reproduced three types of reactions leading to formation of hydrocarbons (HCs) at 3.8–7.8 GPa and 800–1400 C and at hydrogen fugacity (fH2) buffered by the Fe–FeO (IW) + H2O or Mo–MoO2 (MMO) + H2O equilibria: (i) Thermal destruction of organic matter during its subduction into the mantle (with an example of docosane), (ii) hydrogenation of graphite upon interaction with H2‑enriched fluids, and (iii) hydrogenation of carbonates and products of their reduction in metamorphic clayey rocks. The obtained quenched fluids analyzed after the runs by gas chromatography-mass spectrometry (GC–MS) and electronic ionization mass-spectrometry (HR–MS) contain CH4 and C2H6 as main carbon species. The concentrations of C2-C4 alkanes in the fluids increase as the pressure and temperature increase from 3.8 to 7.8 GPa and from 800 to 1400 C, respectively. The fluid equilibrated with the muscovite–garnet–omphacite–kyanite–rutile ± coesite assemblage consists of 50–80 rel.% H2O and 15–40 rel.% alkanes (C1 > C2 > C3 > C4). Main N-bearing species are ammonia (NH3) in the C–O–H–N and muscovite–C–O–H–N systems or methanimine (CH3N) in the fluid derived from the samples of natural pelitic rocks. Nitrogen comes either from air or melamine (C3H6N6) in model systems or from NH4+ in the runs with natural samples. The formula CH3N in the quenched fluid of the C–O–H–N system is confirmed by HR–MS. The impossibility of CH3N incorporation into K-bearing silicates because of a big CH3NH+ cation may limit the solubility of N in silicates at low fO2 and hence may substantially influence the mantle cycle of nitrogen. Thus, subduction of slabs containing carbonates, organic matter, and N-bearing minerals into strongly reduced mantle may induce the formation of fluids enriched in H2O, light alkanes, NH3, and CH3N. The presence of these species must be critical for the deep cycles of carbon, nitrogen, and hydrogen.

Prograde polyphase regional metamorphism of pelitic rocks, NW of Jamshedpur, eastern India: constraints from textural relationship, pseudosection modelling and geothermobarometry

The study area belongs to the Singhbhum metamorphic belt of Jharkhand, situated in the eastern part of India. The spatial distribution of the index minerals in the pelitic schists of the area shows Barrovian type of metamorphism. Three isograds, viz. garnet, staurolite and sillimanite, have been delineated and the textural study of the schists has revealed a time relation between crystallization and deformation. Series of folds with shifting values of plunges in the supracrustal rocks having axial-planar schistosity to the folds have been widely cited. Development of these folds could be attributed to the second phase of deformation. In total, two phases of deformation, D1 and D2, in association with two phases of metamorphism, M1 and M2, have been lined up in the study area. Chemographic plots of reactant and product assemblages corresponding to various metamorphic reactions suggest that the pattern of metamorphic zones mapped in space is in coherence with the temporal-sequential change during prograde metamorphism. The prograde P–T evolution of the study area has been obtained using conventional geothermobarometry, internally consistent winTWQ program and Perple_X software in the MnNCKFMASHTO model system. Our observations suggest that the progressive metamorphism in the area is not related to granitic intrusion or migmatization but that it was possibly the ascending plume that resulted in the M1 phase of metamorphism followed by D1 deformation. The second and prime metamorphic phase, M2, with its possible heat source generated by crustal overloading, was preceded by D1 and it lasted until late- to post-D2 deformation.

Metamorphism of Jhyallaphay-Barpak-Bhachchek area of Gorkha District, Lesser Himalaya and Higher Himalaya, Central Nepal

The study is focused on geological mapping, petrography and metamorphism of Jhyallaphat–Barpak–Bhachchek area, a part of Gorkha District, Central Nepal using a base of 1:25000 scale covering an area of 139.80 sq. km. The rocks of the study area can be broadly divided into two tectonic zones; the Lesser Himalaya consisting of fie lithological units, and the Higher Himalaya consisting of Formation I of the Tibetan Slab. Three metamorphic zones can be distinguished in the study area; biotite zone, garnet zone and kyanite zone. The biotite zone of the mineral assemblage in pelitic rocks consists of biotite+muscovite+chlorite+quartz, in psammitic rocks comprises of biotite+muscovite+chlorite+feldspar+quartz and in carbonate rocks comprises of biotite+muscovite+calcite/dolomite+feldspar+quartz, respectively. These mineral assemblages show that the area belongs to the greenschist facies. The mineral assemblage of the garnet zone in pelitic rocks constitutes garnet+biotite+muscovite+chlorite+quartz, and in psammitic rocks constitutes of garnet+biotite+muscovite+feldspar+quartz. The minerals assemblages found within the biotite and garnet zones represent the well-known inverted metamorphism in the Lesser Himalaya. Mineral assemblage of the kyanite zones constitutes of kyanite+garnet+biotite+muscovite+feldspar+quartz. The mineral assemblages of the both garnet and kyanite zones show that the area belongs to the epidote amphibolite facies. The bedding and foliation planes are almost parallel, showing that isograds also cut across the foliation. Therefore, the main metamorphic event should have followed development of foliation in the area. The rocks of the area show at least two metamorphic events: syntectonic prograde and post-tectonic retrograde. Syn-tectonic prograde metamorphism (M1), which has grown during a single phase of deformation and most frequently encountered garnet prophyroblast. Metamorphic deformation is represented by the presence of metamorphic foliation, stretching lineation, and S-C fabric. Post-tectonic retrograde metamorphism (M2), which is followed by retrograde mineral formation changing its P-T condition from high to low grade minerals, such as the formation of the biotite and chlorite minerals around the rims of the garnet porphyroblasts.