scholarly journals SEPARATION OF OIL-WATER EMULSIONS

Author(s):  
М.А. Ковалёва ◽  
Т.Н. Виниченко ◽  
В.Г. Шрам ◽  
Е.Г. Кравцова ◽  
М.А. Плахотникова

Одним из наиболее серьёзных осложнений при добыче и транспортировке нефти является интенсивное выпадение асфальто-смолистых и парафиновых отложений (АСПО). В данной работе проводилась оценка эффективности растворителей разной химической природы для удаления АСПО. На основании лабораторных данных были сделаны выводы о использовании неиногенного типа ПАВ, спиртов с различной молекулярной массой, оптимального соотношения алканового и ароматического компонента для растворения АСПО парафинового типа. One of the most serious complications in oil production and transportation is the intensive deposition of as-falto-resinous and paraffin deposits (ASPs). In this work, the effectiveness of solvents of different chemical nature for the removal of ASPs was evaluated. Based on laboratory data, conclusions were drawn about the use of noninogenic surfactants, alcohols with different molecular weights, and the optimal ratio of the alkane and aromatic components for the dissolution of paraffin-type ASPs.

2009 ◽  
Vol 12 (03) ◽  
pp. 470-476 ◽  
Author(s):  
Dongmei Wang ◽  
Huanzhong Dong ◽  
Changsen Lv ◽  
Xiaofei Fu ◽  
Jun Nie

Summary This paper describes successful practices applied during polymer flooding at Daqing that will be of considerable value to future chemical floods, both in China and elsewhere. On the basis of laboratory findings, new concepts have been developed that expand conventional ideas concerning favorable conditions for mobility improvement by polymer flooding. Particular advances integrate reservoir-engineering approaches and technology that is basic for successful application of polymer flooding. These include the following:Proper consideration must be given to the permeability contrast among the oil zones and to interwell continuity, involving the optimum combination of oil strata during flooding and well-pattern design, respectively;Higher polymer molecular weights, a broader range of polymer molecular weights, and higher polymer concentrations are desirable in the injected slugs;The entire polymer-flooding process should be characterized in five stages--with its dynamic behavior distinguished by water-cut changes; -Additional techniques should be considered, such as dynamic monitoring using well logging, well testing, and tracers; effective techniques are also needed for surface mixing, injection facilities, oil production, and produced-water treatment; andContinuous innovation must be a priority during polymer flooding. Introduction China's Daqing oil field entered its ultrahigh-water-cut period after 30 years of exploitation. Just before large-scale polymer-flooding application, the average water-cut was more than 90%. The Daqing oil-field is a large river-delta/lacustrine facies, multilayered with complex geologic conditions and heterogeneous sandstone in an inland basin. After 30 years of waterflooding, many channels and high-permeability streaks were identified in this oil field (Wang and Qian 2002). Laboratory research began in the 1960s, investigating the potential of enhanced-oil-recovery (EOR) processes in the Daqing oil field. After a single-injector polymer flood with a small well spacing of 75 m in 1972, polymer flooding was set on pilot test. During the late 1980s, a pilot project in central Daqing was expanded to a multiwell pattern with larger well spacing. Favorable results from these tests--along with extensive research and engineering from the mid-1980s through the 1990s--confirmed that polymer flooding was the preferred method to improve areal- and vertical-sweep efficiency at Daqing and to provide mobility control (Wang et al. 2002, Wang and Liu 2004). Consequently, the world's largest polymer flood was implemented at Daqing, beginning in 1996. By 2007, 22.3% of total production from the Daqing oil field was attributed to polymer flooding. Polymer flooding boosted the ultimate recovery for the field to more than 50% of original oil in place (OOIP)--10 to 12% OOIP more than from waterflooding. At the end of 2007, oil production from polymer flooding at the Daqing oil field was more than 10 million tons (73 million bbl) per year (sustained for 6 years). The focus of this paper is on polymer flooding, in which sweep efficiency is improved by reducing the water/oil mobility ratio in the reservoir. This paper is not concerned with the use of chemical gel treatments, which attempt to block water flow through fractures and high-permeability strata. Applications of chemical gel treatments in China have been covered elsewhere (Liu et al. 2006).


1991 ◽  
Vol 31 (1) ◽  
pp. 386 ◽  
Author(s):  
Alan J. Sheehy

For over 40 years it has been speculated that bacteria can facilitate, increase or extend oil production from petroleum reservoirs. This speculation was supported in the laboratory by dramatic increases in oil recovered from experimental systems and in the field by anecdotal accounts of improvements in oil production. Most of these studies were poorly conceived and inadequately controlled. This drew industry criticism and created an environment where proposals to implement microbiologically enhanced oil recovery (microbial EOR) were summarily dismissed. The program implemented for the Alton Field, Surat Basin, was designed to overcome industry scepticism and document unambiguously in the field the effectiveness of a new microbial EOR strategy called Biological Stimulation of Oil production (BOS). An approximate 40 per cent increase in oil production has been sustained, compared to control operations on the same well, for eighteen months.The thrust to introduce pilot and field programs of BOS is compelling. BOS shares the advantages common to all biotechnologies in exploiting the extraordinary growth potential of microorganisms, providing flexibility through the extreme diversity of microbial metabolites and using cheap feedstocks. The BOS process generates ultramicrocells from those bacteria present naturally in the reservoir to be treated. This promotes injectivity, dispersion and persistence of the BOS system in the extreme environments which characterise petroleum reservoirs. The nutrients injected with the ultramicrocells result in metabolites forming within the bacterial cell surface. These metabolites cause re-profiling of the formation through the generation of emulsions and the development of concentrated surfactants at the oil-water interface.Ecological strategies designed to negate previously documented problems in the application of microbial EOR have been shown to be effective in laboratory experiments and field applications. Overcoming environmental extremes and developing persistence of beneficial organisms have been given special attention.


Author(s):  
Boying Li ◽  
Yuhui Zhou ◽  
Su Li ◽  
Yiping Ye ◽  
Hongfa Liu

AbstractFault-karst reservoirs are featured by complex geological characteristics, and accurate and fast simulation of such kind of reservoirs using traditional simulator and simulation methods is pretty hard. Herein, we tried to discrete the complex fault-karst structures into one-dimensional connected units connecting the well, fracture and cave based on reservoir static physical parameters and injection-production dynamics. Two characteristic parameters, conductivity and connected volume, are proposed to characterize the inter-well connectivity and material basis. Meanwhile, the high-speed non-Darcy seepage term is introduced into the material balance equations for well-fracture-cave connected units to describe the actual seepage characteristics within the fault-karst reservoirs, and to better simulate the oil/water production dynamics. Based on this method, a fracture reservoir model of 1 injection-3 production was established. The change of oil–water action law in different injection and extraction systems under two production regimes of fixed production rate and fixed pressure is analyzed. A case study was conducted on S fault zone, where the flow of oil and gas did not follow the Darcy seepage rule and with a β value of 103–104, the single well flow pressure and oil production were perfectly matched with the real data. In addition, connected units with more prominent high-speed non-Darcy features were found to have better connectivity, which might shed light on the more accurate prediction of inter-well connectivity. Moreover, an improved injection-production well pattern and was proposed based on connectivity prediction model and reservoir engineering method to solve the problems of insufficient natural energy supply and overhigh oil production rate in Block S. Furthermore, the injection/production rate as well as the timing and cycle of water injection was predicted and optimized so as to better guide to site operations.


1977 ◽  
Vol 23 (3) ◽  
pp. 584-588 ◽  
Author(s):  
C A Spencer ◽  
G S Challand

Abstract Abnormally high plasma thyrotropin values were found by radioimmunoassay in some patients when an antiserum to porcine thyrotropin was used, normal results being obtained with an antiserum raised to human thyrotropin. These discrepancies were found in some subjects with no biochemical or clinical evidence of hypothyroidism and occasionally in sera from patients with unequivocal hyperthyroidism. We found a substance in serum that cross reacts with the anti-porcine antiserum, is stable on repeated freezing and thawing, and is independent of the 125I-labeled tracer preparation. It is unlikely that this substance is a separation-stage artefact related to immunoglobulins. Its apparent molecular weight (gel filtration) is 114 000, as compared with apparent molecular weights for standard thyrotropin and endogenous thyrotropin (as found in idiopathic hypothyroidism) of 34 700 and 38 000, respectively. We believe the substance is a normal serum constituent that is present in large quantities in a minority of subjects. Apparently unrelated to TSH, its exact chemical nature remains unidentified.


Author(s):  
G. S. Stepanova ◽  
Y. G. Mamedov ◽  
I. A. Babayeva ◽  
A. A. Mosina ◽  
T. L. Nenartovich ◽  
...  

2020 ◽  
Vol 52 (1) ◽  
pp. 382-389 ◽  
Author(s):  
K. Robertson ◽  
R. Heath ◽  
R. Macdonald

AbstractThe Blane Field is located in the central North Sea in Block 30/3a (Licence P.111), approximately 130 km SE of the Forties Field, in a water depth of 75 m (246 ft). It straddles the UK/Norway median line with 82% of the field in the UK and 18% in Norway. Blane produces undersaturated oil from the Upper Forties Sandstone Member of the Sele Formation and contains good quality light oil within a four-way structural closure; it has a hydrodynamically tilted original oil–water contact. The field stock-tank oil initially in place estimate is 93 MMbbl with an expected ultimate recovery of 33 MMbbl. Blane first oil was achieved in September 2007. The field has been developed by two horizontal producers located on the central crest of the field supported by a water injector drilled on the NW flank. Oil production peaked at c. 17 000 bopd in 2007 and the field is currently in decline. By the end of 2018 production was c. 3000 bopd with 55% water-cut. Cumulative oil production to the end of 2018 was 26.6 MMbbl.


2020 ◽  
Vol 993 ◽  
pp. 689-694
Author(s):  
Jian Li ◽  
Toyoji Kakuchi ◽  
Xian De Shen

The core-first synthesis of four-armed star-shaped poly(N,N-diethylacrylamide) with predicted molecular weights and narrow molecular weight distributions (Mw/Mn=1.17) was carried out by the Tris(pentafluorophenyl)borane (B(C6F5)3) -catalyzed group transfer polymerization (GTP) using ethyldimethylsilane (EtMe2SiH) as hydrosilylane. The optimal ratio of the precursor to the hydrosilylation agent was 1:4.2.


1975 ◽  
Vol 1975 (1) ◽  
pp. 437-441 ◽  
Author(s):  
Frank J. Freestone ◽  
Richard B. Tabakin

ABSTRACT The U.S. Environmental Protection Agency has sponsored two separate research contracts in the field of oil-water separation for the fiscal year 1974. One project, with Pollution Abatement Research, Inc., of Dallas, Texas, concerns the development of a chemically assisted, back-washable coalescer with chemically assisted backwash solids scrubber. This device is designed for use on offshore oil production platforms, although it has a wide potential of applicability. Preliminary tests made with large-volume samples of produced water from an offshore oil production platform yielded very promising results with less than 10 ppm produced oil in the effluent water. The second project, with the Ben Holt Company of Pasadena, California, is to develop a new concept of adsorption of oil-contaminated water onto a regenerable coked surface. The project is aimed at chemically stabilized emulsions and dissolved oils. A bench-scale device has been built, and testing has proven the feasibility of the concept. The rationale for the development of each of these devices is presented along with detailed information concerning test results of each device.


Author(s):  
O. N. Opanasenko ◽  
N. P. Krutko ◽  
O. V. Luksha ◽  
O. L. Zhigalova

Physicochemical aspects of the regulation of interfacial processes occurring at the oil-water-rock interface in the presence of ionic surfactants and their compositions are considered with the goal of developing efficient, scientifically grounded innovative technologies ensuring enhanced oil recovery and refining. A complex of studies of surface phenomena in the presence of ionic surfactants made it possible to identify criteria for evaluating the effectiveness of their action at the oil-water-rock interface, which makes it possible to predict the behavior of surfactants in real conditions of oil production and to use them purposefully in various enhanced oil recovery technologies.


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