scholarly journals High Energy Density Single Crystal NMC/Li6PS5Cl Cathodes for All-Solid-State Lithium Metal Batteries

2021 ◽  
Author(s):  
Christopher Doerrer ◽  
Isaac Capone ◽  
Sudarshan Narayanan ◽  
Junliang Liu ◽  
Christopher Grovenor ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Single Crystal ◽  
Discharge Capacity ◽  
Coulombic Efficiency ◽  
High Capacity ◽  
Composite Cathode ◽  
High Energy ◽  
High Energy Density ◽  
Composite Cathodes

<div><div><div><p>To match the high capacity of metallic anodes, all-solid-state batteries (ASSBs) re- quire high energy density, long-lasting composite cathodes such as Ni-Mn-Co (NMC)- based lithium oxides mixed with a solid-state electrolyte (SSE). However in practice, cathode capacity typically fades due to NMC cracking and increasing NMC/SSE in- terface debonding because of NMC pulverization, which is only partially mitigated by the application of a high cell pressure during cycling. Using smart processing proto- cols we report a single crystal particulate LiNi0.83Mn0.06Co0.11O2 and Li6PS5Cl SSE composite cathode with outstanding discharge capacity of 210 mAh g−1 at 30 °C. A first cycle coulombic efficiency of >85%, and >99% thereafter, was achieved despite a 5.5% volume change during cycling. A near-practical discharge capacity at a high areal capacity of 8.7 mAh cm−2 was obtained using a novel asymmetric anode/cathode cycling pressure of only 2.5 MPa/0.2 MPa.</p></div></div></div>

scholarly journals High Energy Density Single Crystal NMC/Li6PS5Cl Cathodes for All-Solid-State Lithium Metal Batteries

2021 ◽  
Author(s):  
Christopher Doerrer ◽  
Isaac Capone ◽  
Sudarshan Narayanan ◽  
Junliang Liu ◽  
Christopher Grovenor ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Single Crystal ◽  
Discharge Capacity ◽  
Coulombic Efficiency ◽  
High Capacity ◽  
Composite Cathode ◽  
High Energy ◽  
High Energy Density ◽  
Composite Cathodes

<div><div><div><p>To match the high capacity of metallic anodes, all-solid-state batteries (ASSBs) re- quire high energy density, long-lasting composite cathodes such as Ni-Mn-Co (NMC)- based lithium oxides mixed with a solid-state electrolyte (SSE). However in practice, cathode capacity typically fades due to NMC cracking and increasing NMC/SSE in- terface debonding because of NMC pulverization, which is only partially mitigated by the application of a high cell pressure during cycling. Using smart processing proto- cols we report a single crystal particulate LiNi0.83Mn0.06Co0.11O2 and Li6PS5Cl SSE composite cathode with outstanding discharge capacity of 210 mAh g−1 at 30 °C. A first cycle coulombic efficiency of >85%, and >99% thereafter, was achieved despite a 5.5% volume change during cycling. A near-practical discharge capacity at a high areal capacity of 8.7 mAh cm−2 was obtained using a novel asymmetric anode/cathode cycling pressure of only 2.5 MPa/0.2 MPa.</p></div></div></div>

Single crystal Ni-rich layered cathodes enabling superior performance in all-solid-state batteries with PEO-based solid electrolytes

2021 ◽  
Author(s):  
Maoyi Yi ◽  
Li Jie ◽  
Xin-ming Fan ◽  
Maohui Bai ◽  
Zhi Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Single Crystal ◽  
Solid Electrolytes ◽  
High Energy ◽  
High Energy Density ◽  
Superior Performance ◽  
Composite Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

PEO-based composite electrolytes are one of the most practical electrolytes in all-solid batteries (ASSBs). To achieve the perspective of ASSBs with high energy density, PEO based composite electrolytes should match...

scholarly journals Self-Supported Sheets-on-Wire CuO@Ni(OH)2/Zn(OH)2 Nanoarrays for High-Performance Flexible Quasi-Solid-State Supercapacitor

Processes ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 680
Author(s):  
Jianyang Jiang ◽  
Xiong Xiong Liu ◽  
Jiayu Han ◽  
Ke Hu ◽  
Jun Song Chen
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Electrode Materials ◽  
Red Light ◽  
High Capacity ◽  
High Energy ◽  
High Rate ◽  
High Energy Density ◽  
Supercapacitor Application ◽  
Charge Discharge

Transition metal hydroxides have attracted a lot of attention as the electrode materials for supercapacitors owing to their relatively high theoretical capacity, low cost, and facile preparation methods. However, their low intrinsic conductivity deteriorates their high-rate performance and cycling stability. Here, self-supported sheets-on-wire CuO@Ni(OH)2/Zn(OH)2 (CuO@NiZn) composite nanowire arrays were successfully grown on copper foam. The CuO nanowire backbone provided enhanced structural stability and a highly efficient electron-conducting pathway from the active hydroxide nanosheets to the current collector. The resulting CuO@NiZn as the battery-type electrode for supercapacitor application delivered a high capacity of 306.2 mAh g−1 at a current density of 0.8 A g−1 and a very stable capacity of 195.1 mAh g−1 at 4 A g−1 for 10,000 charge–discharge cycles. Furthermore, a quasi-solid-state hybrid supercapacitor (qss HSC) was assembled with active carbon, exhibiting 125.3 mAh g−1 at 0.8 A g−1 and a capacity of 41.6 mAh g−1 at 4 A g−1 for 5000 charge–discharge cycles. Furthermore, the qss HSC was able to deliver a high energy density of about 116.0 Wh kg−1. Even at the highest power density of 7.8 kW kg−1, an energy density of 20.5 Wh kg−1 could still be obtained. Finally, 14 red light-emitting diodes were lit up by a single qss HSC at different bending states, showing good potential for flexible energy storage applications.

A high-energy-density lithium-oxygen battery based on a reversible four-electron conversion to lithium oxide

Science ◽  
2018 ◽  
Vol 361 (6404) ◽  
pp. 777-781 ◽  
Author(s):  
C. Xia ◽  
C. Y. Kwok ◽  
L. F. Nazar
Keyword(s):  
Energy Density ◽  
Coulombic Efficiency ◽  
Bond Cleavage ◽  
High Capacity ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Oxide ◽  
Lithium Peroxide ◽  
Lithium Oxygen Battery ◽  
Electron Reduction

Lithium-oxygen (Li-O2) batteries have attracted much attention owing to the high theoretical energy density afforded by the two-electron reduction of O2 to lithium peroxide (Li2O2). We report an inorganic-electrolyte Li-O2 cell that cycles at an elevated temperature via highly reversible four-electron redox to form crystalline lithium oxide (Li2O). It relies on a bifunctional metal oxide host that catalyzes O–O bond cleavage on discharge, yielding a high capacity of 11 milliampere-hours per square centimeter, and O2 evolution on charge with very low overpotential. Online mass spectrometry and chemical quantification confirm that oxidation of Li2O involves transfer of exactly 4 e–/O2. This work shows that Li-O2 electrochemistry is not intrinsically limited once problems of electrolyte, superoxide, and cathode host are overcome and that coulombic efficiency close to 100% can be achieved.

scholarly journals High Energy Density Single-Crystal NMC/Li6PS5Cl Cathodes for All-Solid-State Lithium-Metal Batteries

2021 ◽  
Author(s):  
Christopher Doerrer ◽  
Isaac Capone ◽  
Sudarshan Narayanan ◽  
Junliang Liu ◽  
Chris R. M. Grovenor ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Single Crystal ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Lithium Metal Batteries

Graphite-Based Lithium-Free 3D Hybrid Anodes for High Energy Density All-Solid-State Batteries

2021 ◽  
pp. 1831-1838
Author(s):  
Xing Xing ◽  
Yejing Li ◽  
Shen Wang ◽  
Haodong Liu ◽  
Zhaohui Wu ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Solid State Batteries ◽  
All Solid State Batteries

High energy density lithium-ion batteries with carbon nanotube anodes

2010 ◽  
Vol 25 (8) ◽  
pp. 1636-1644 ◽  
Author(s):  
Brian J. Landi ◽  
Cory D. Cress ◽  
Ryne P. Raffaelle
Keyword(s):  
Carbon Nanotube ◽  
Energy Density ◽  
High Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Electrically Conductive ◽  
Single Walled Carbon Nanotube ◽  
Battery Energy ◽  
Graphite Composites

Recent advancements using carbon nanotube electrodes show the ability for multifunctionality as a lithium-ion storage material and as an electrically conductive support for other high capacity materials like silicon or germanium. Experimental data show that replacement of conventional anode designs, which use graphite composites coated on copper foil, with a freestanding silicon-single-walled carbon nanotube (SWCNT) anode, can increase the usable anode capacity by up to 20 times. In this work, a series of calculations were performed to elucidate the relative improvement in battery energy density for such anodes paired with conventional LiCoO2, LiFePO4, and LiNiCoAlO2 cathodes. Results for theoretical flat plate prismatic batteries comprising freestanding silicon-SWCNT anodes with conventional cathodes show energy densities of 275 Wh/kg and 600 Wh/L to be theoretically achievable; this is a 50% improvement over today's commercial cells.

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