Graphite-Based Lithium-Free 3D Hybrid Anodes for High Energy Density All-Solid-State Batteries

2021 ◽  
pp. 1831-1838
Author(s):  
Xing Xing ◽  
Yejing Li ◽  
Shen Wang ◽  
Haodong Liu ◽  
Zhaohui Wu ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Solid State Batteries ◽  
All Solid State Batteries

Single crystal Ni-rich layered cathodes enabling superior performance in all-solid-state batteries with PEO-based solid electrolytes

2021 ◽  
Author(s):  
Maoyi Yi ◽  
Li Jie ◽  
Xin-ming Fan ◽  
Maohui Bai ◽  
Zhi Zhang ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Single Crystal ◽  
Solid Electrolytes ◽  
High Energy ◽  
High Energy Density ◽  
Superior Performance ◽  
Composite Electrolytes ◽  
Solid State Batteries ◽  
All Solid State Batteries

PEO-based composite electrolytes are one of the most practical electrolytes in all-solid batteries (ASSBs). To achieve the perspective of ASSBs with high energy density, PEO based composite electrolytes should match...

scholarly journals Recycling Strategies for Ceramic All-Solid-State Batteries—Part I: Study on Possible Treatments in Contrast to Li-Ion Battery Recycling

Metals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1523
Author(s):  
Lilian Schwich ◽  
Michael Küpers ◽  
Martin Finsterbusch ◽  
Andrea Schreiber ◽  
Dina Fattakhova-Rohlfing ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Future Research ◽  
Energy Storage Devices ◽  
Solid State Batteries ◽  
All Solid State Batteries

In the coming years, the demand for safe electrical energy storage devices with high energy density will increase drastically due to the electrification of the transportation sector and the need for stationary storage for renewable energies. Advanced battery concepts like all-solid-state batteries (ASBs) are considered one of the most promising candidates for future energy storage technologies. They offer several advantages over conventional Lithium-Ion Batteries (LIBs), especially with regard to stability, safety, and energy density. Hardly any recycling studies have been conducted, yet, but such examinations will play an important role when considering raw materials supply, sustainability of battery systems, CO2 footprint, and general strive towards a circular economy. Although different methods for recycling LIBs are already available, the transferability to ASBs is not straightforward due to differences in used materials and fabrication technologies, even if the chemistry does not change (e.g., Li-intercalation cathodes). Challenges in terms of the ceramic nature of the cell components and thus the necessity for specific recycling strategies are investigated here for the first time. As a major result, a recycling route based on inert shredding, a subsequent thermal treatment, and a sorting step is suggested, and transferring the extracted black mass to a dedicated hydrometallurgical recycling process is proposed. The hydrometallurgical approach is split into two scenarios differing in terms of solubility of the ASB-battery components. Hence, developing a full recycling concept is reached by this study, which will be experimentally examined in future research.

scholarly journals Co-Sintering Study of Na0.67[Ni0.1Fe0.1Mn0.8]O2 and NaSICON Electrolyte–Paving the way to High Energy Density All-Solid-State Batteries

2021 ◽  
Vol 9 ◽  
Author(s):  
Gerald Dück ◽  
Sahir Naqash ◽  
Martin Finsterbusch ◽  
Uwe Breuer ◽  
Olivier Guillon ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Cathode Material ◽  
Perfect Match ◽  
High Energy ◽  
High Energy Density ◽  
Superionic Conductors ◽  
Processing Route ◽  
Solid State Batteries ◽  
All Solid State Batteries

Sodium is a promising candidate for stationary storage applications, especially when the demand for lithium-ion batteries increases due to electromobility applications. Even though its energy density is lower, Na-ion technology is estimated to lead to a cost reduction of 30% compared to Li-ion technology. To improve safety as well as energy density, Na-based all-solid-state-batteries featuring solid electrolytes such as beta-alumina and sodium superionic conductors and cathode materials such as Na3V2(PO4)3 and NaxCoO2 have been developed over the past years. However, the biggest challenge are mixed cathodes with highly conductive interfaces, especially when co-sintering the materials. For example, a promising sodium superionic conductor type Na3Zr2Si2PO12 electrolyte sinters at 1,250°C, whereas the corresponding Na3V2PO12 cathode decomposes at temperatures higher than 900°C, posing a bottleneck. Thus in this paper, we synthesized Na0.62 [Ni0.10Fe0.10Mn0.80]O2 as cathode material for all-solid-state sodium-ion batteries via a relatively cheap and easy solution-assisted solid state reaction processing route. The thermal investigations of the pure cathode material found no degradation up to 1,260°C, making it a perfect match for Na3.4Zr2Si2.4P0.6O12 electrolyte. In our aim to produce a co-sintered mixed cathode, electron microscopy investigation showed a highly dense microstructure and the elemental mapping performed via energy dispersive X-ray spectroscopy and secondary ion mass spectrometry confirm that Na3.4Zr2Si2.4P0.6O12 and Na0.62 [Ni0.10Fe0.10Mn0.80]O2 do not react during sintering. However, the active cathode material forms a sodium rich and a sodium deficient phase which needs further investigation to understand the origin and its impact on the electrochemical performance.

scholarly journals Preparation and Application of Garnet Electrolyte Thin Films: Promise and Challenges

2020 ◽  
pp. 6-22 ◽  
Author(s):  
Xufeng Yan ◽  
Weiqiang Han
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Energy Density ◽  
Solid Electrolyte ◽  
High Energy ◽  
High Energy Density ◽  
Electrochemical Performances ◽  
Safety Property ◽  
Solid State Batteries ◽  
All Solid State Batteries

All-solid-state batteries (ASSBs) have attracted much attention in recent years, due to their high energy density, excellent cycling performance, and superior safety property. As the key factor of all-solid-state batteries, solid electrolyte determines the performance of the batteries. Garnet-typed cubic Li7La3Zr2O12(LLZO) has been reported as the most promising solid electrolyte on the way to ASSBs. Thin film electrolyte could contribute to a higher energy density and a lower resistance in a battery. This short review exhibits the latest efforts on LLZO thin film and discusses the different preparation methods, together with their effects on characteristics and electrochemical performances of the solid electrolyte film.

High Energy Density All-Solid-State Batteries: A Challenging Concept Towards 3D Integration

2008 ◽  
Vol 18 (7) ◽  
pp. 1057-1066 ◽  
Author(s):  
Loıc Baggetto ◽  
Rogier A. H. Niessen ◽  
Fred Roozeboom ◽  
Peter H. L. Notten
Keyword(s):  
Solid State ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
3D Integration ◽  
Solid State Batteries ◽  
All Solid State Batteries

Diffusion-Dependent Graphite Electrode for All-Solid-State Batteries with Extremely High Energy Density

2020 ◽  
Vol 5 (9) ◽  
pp. 2995-3004
Author(s):  
Ju Young Kim ◽  
Joonam Park ◽  
Myeong Ju Lee ◽  
Seok Hun Kang ◽  
Dong Ok Shin ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Graphite Electrode ◽  
High Energy ◽  
High Energy Density ◽  
Solid State Batteries ◽  
All Solid State Batteries

Unraveling the divalent pillar effects for the prolonged cycling of high-energy-density cathodes

2021 ◽  
Author(s):  
Byungwook Kang ◽  
Hyungjun Kim ◽  
Myungkyu Kim ◽  
Duho Kim ◽  
Maenghyo Cho
Keyword(s):  
Solid State ◽  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Promising Candidate ◽  
Significant Interest ◽  
Solid State Batteries

Solid-state batteries (SSBs) have attracted significant interest owing to their relatively high energy density and nonflammability. LiNi0.5Mn1.5O4 (LNMO) is a promising candidate for cathodes in SSBs because of its high...

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