The soil pollution of polycyclic aromatic hydrocarbons (PAHs) is serious in China, which not only affects the living and growing environment of plants and animals but also has a great impact on people’s health. The use of hydrophobic organic compounds to make use of surfactant ectopic elution processing is more convenient and cheaper as a repair scheme and can effectively wash out the polycyclic aromatic hydrocarbons in the soil. Therefore, we mixed sophorolipids:sodium dodecylbenzene sulfonate (SDBS):Na2SiO3 according to the mass ratio of 1:15:150. We explored the influencing factors of high and low concentrations of PAH-contaminated soil using a single factor test and four factors at a two-level factorial design. Then, the elution wastewater was treated by ultrasonic oxidation technology and the alkali-activated sodium persulfate technology. The results showed that: (1) In the single factor test, when the elution time is 8 h, the concentration of the compounded surfactant is 1200 mg/L, the particle size is 60 mesh, the concentration of NaCl is 100 mmol/L, and the concentration of KCl is 50 mmol/L, and the effect of the PAH-contaminated soil eluted by the composite surfactant is the best. Externally added NaCl and KCl salt ions have a more obvious promotion effect on the polycyclic aromatic hydrocarbon-contaminated soil; (2) in the interaction experiment, single factor B (elution time) and D (NaCl concentration) have a significant main effect. There is also a certain interaction between factor A (concentration agent concentration) and factor D, factor B, and factor C (KCl concentration); (3) the treatment of anthracene in the eluate by ultrasonic completely mineralizes the organic pollutants by the thermal and chemical effects produced by the ultrasonic cavitation phenomenon, so that the organic pollutants in the eluate are oxidized and degraded into simple environmentally friendly small molecular substances. When the optimal ultrasonic time is 60 min and the ratio of oxidant to activator is 1:2, the removal rate of contaminants in the eluent can reach 63.7%. At the same time, the turbidity of the eluent is significantly lower than that of the liquid after centrifugal separation, indicating that oxidants can not only remove the pollutants in elution water but also remove the residual soil particulate matter; and (4) by comparing the infrared spectrum of the eluted waste liquid before and after oxidation, it can be seen that during the oxidation process, the inner part of eluent waste liquid underwent a ring-opening reaction, and the ring-opening reaction also occurred in the part of the cyclic ester group of the surfactant, which changed from a ring to non-ring.
C-C and C-H bond cleavage reactions in acenaphthylene aromatic molecule, an ab-initio density functional theory study
