Three-dimensional Change of Elastomeric Impression Materials During the First 24 Hours: A Pilot Study

SUMMARY Objectives: To evaluate the three-dimensional (3D) changes of three elastomeric impression materials using a novel measurement method for the first 24 hours after preparation. Methods and Materials: Three impression materials consisting of a low-viscosity polyvinyl siloxane (PVS) (Aquasil LV, Dentsply Sirona, Charlotte, NC, USA) and two vinyl polyether silicone (VPES) materials consisting of a light body (EXA’lence LB, GC America, Alsip, IL, USA) and monophase (EXA’lence Monophase, GC America) materials were used in this study. All materials were prepared following manufacturer’s recommendations with approximately 1–2 millimeters of material placed on the measurement pedestal of a calibrated noncontact, video imaging based, volumetric change measuring device (AcuVol ver 2.5.9, Bisco, Schaumburg, IL, USA). Data collection was initiated immediately, with measurements made every 30 seconds for 24 hours. Each material was evaluated 10 times (n=10). Evaluated parameters included were 24-hour mean shrinkage, mean shrinkage at time of recommended first pour, mean shrinkage between recommended first pour and 24 hours, mean maximum shrinkage, and the time of maximum shrinkage. Mean data, both within and between each group, was evaluated using Kruskal–Wallis/Dunn’s tests at a 95% level of confidence (α=0.05). Results: All three materials were found to have significant differences (p<0.001) in volumetric shrinkage over 24 hours. Aquasil LV and EXA’lence LB polymerization shrinkage rates were statistically similar all through the 24-hour evaluation (p=0.92). All three materials demonstrated similar (p=0.19) shrinkage between 10 and 15 minutes after preparation, while between 5 and 16 hours both EXA’lence Monophase and low-viscosity materials demonstrated similar polymerization shrinkage values (p=0.22). EXA’lence Monophase demonstrated significantly greater 24-hour mean shrinkage (p<0.008) as well as shrinkage between recommended first pour time and 24 hours (p=0.003) than Aquasil LV and EXA’lence LB. EXA’lence Monophase demonstrated significantly greater (p=0.002) shrinkage at the recommended time of first pour as compared to Aquasil LV and EXA’lence LB that displayed similar shrinkage (p=0.89). Furthermore, all materials demonstrated increasing polymerization shrinkage values that reached a maximum between 16 for Aquasil LV and 20 hours for EXA’lence LB, after which some relaxation behavior was observed. However, EXA’lence Monophase did not display any relaxation behavior over the 24-hour evaluation. Conclusions: Under the conditions of this study, volumetric polymerization shrinkage was observed for one polyvinyl siloxane (PVS) and two vinyl polyether silicone (VPES) materials for up to 24 hours. All impression materials exhibited fast early volumetric shrinkage that continued past the manufacturer’s recommended removal time. Dimensional change behavior was not uniform within or between groups; resultant volume change between the manufacturer recommended pouring time and 24 hours might represent up to from 20% to 30% of the total material shrinkage. It may be prudent to pour elastomeric impressions at the earliest time possible following the manufacturer’s recommendations.

Preheated composite: Innovative approach for aesthetic restoration

Resin-based composites are today one of the most widely used restorative materials. However, its most debilitating problem is volumetric shrinkage due to polymerization which may result in contraction stress and subsequent micro leakage and adhesion failure. Preheating composites prior to polymerisation have several advantages over conventional composites. This review article highlights the mechanical properties, advantages and significance of preheated composites.

Mathematical modeling and multivariate analysis applied earliest soybean harvest associated drying and storage conditions and influences on physicochemical grain quality

Anticipating the harvest period of soybean crops can impact on the post-harvest processes. This study aimed to evaluate early soybean harvest associated drying and storage conditions on the physicochemical soybean quality using of mathematical modeling and multivariate analysis. The soybeans were harvested with a moisture content of 18 and 23% (d.b.) and subjected to drying in a continuous dryer at 80, 100, and 120 °C. The drying kinetics and volumetric shrinkage modeling were evaluated. Posteriorly, the soybean was stored at different packages and temperatures for 8 months to evaluate the physicochemical properties. After standardizing the variables, the data were submitted to cluster analysis. For this, we use Euclidean distance and Ward's hierarchical method. Then defining the groups, we constructed a graph containing the dispersion of the values of the variables and their respective Pearson correlations for each group. The mathematical models proved suitable to describe the drying kinetics. Besides, the effective diffusivity obtained was 4.9 × 10–10 m2 s−1 promoting a volumetric shrinkage of the grains and influencing the reduction of physicochemical quality. It was observed that soybean harvested at 23% moisture, dried at 80 °C, and stored at a temperature below 23 °C maintained its oil content (25.89%), crude protein (35.69%), and lipid acidity (5.54 mL). In addition, it is to note that these correlations' magnitude was substantially more remarkable for the treatments allocated to the G2 group. Furthermore, the electrical conductivity was negatively correlated with all the physicochemical variables evaluated. Besides this, the correlation between crude protein and oil yield was positive and of high magnitude, regardless of the group formed. In conclusion, the early harvest of soybeans reduced losses in the field and increased the grain flow on the storage units. The low-temperature drying and the use of packaging technology close to environmental temperatures conserved the grain quality.

Effect of thermal modification on wood properties of 38-year-old Cariniana legalis cultivated at different spacing

Planting spacing influences wood production. However, for tropical species we have scarce information about the effect of spacing on production and wood quality. In general, wood from native species produced in reforestation does not have the same quality compared to that from natural forests. Then, wood thermal modification can help improve the potential for using wood. In this context, our goal was to evaluate the influence of thermal modification on properties of 38-year-old Cariniana legalis wood cultivated at different spacing (3 x 1.5m, 3 x 2m and 3 x 2.5m) at the Luiz Antônio Experimental Station, Luiz Antônio City, São Paulo. We felled 15 trees, five of each spacing, and from each tree, a log, 1 meter in length, a central plank was cut, and from these planks, we cut specimens for anatomical and wood properties investigations according to standard techniques. In the specimens, a thermal modification at a temperature of 200ºC was carried out for one hour and after the specimens were compared with the control specimens. According to the results presented, we found that spacing did not influence vessel diameter, apparent density and volumetric shrinkage significantly. Thermal modification reduced apparent density and volumetric shrinkage. The reduction in vessel diameter can be estimated as a function of the wood thermal modification.

PREDICTION OF PEEK RESIN PROPERTIES FOR PROCESSING MODELING USING MOLECULAR DYNAMICS

Polymer Matrix Composites (PMCs) have been the subject of many recent studies due to their outstanding characteristics. For the processing of PMCs, a wide range of elevated temperatures is typically applied to the material, leading to the development of internal residual stresses during the final cool-down step. These residual stresses may lead to net shape deformations or internal damage. Also, volumetric shrinkage, and thus additional residual stresses, could be created during crystallization of the semi-crystalline thermoplastic matrix. Furthermore, the thermomechanical properties of semi-crystalline polymers are susceptible to the crystallinity content, which is tightly controlled by the processing parameters (processing temperature, temperature holding time) and material properties (melting and crystallization temperatures). Hence, it is vital to have a precise understanding of crystallization kinetics and its impact on the final component's performance to accurately predict induced residual stresses during the processing of these materials. To enable multi-scale process modeling of thermoplastic composites, molecular-level material properties must be determined for a wide range of crystallinity levels. In this study, the thermomechanical properties and volumetric shrinkage of the thermoplastic Poly Ether Ether Ketone (PEEK) resin are predicted as a function of crystallinity content and temperature using molecular dynamics (MD) modeling. Using crystallization-kinetics models, the thermo-mechanical properties are directly related to processing time and temperature. This research can ultimately predict the residual stress evolution in PEEK composites as a function of processing parameters.

Shrinkage properties of natural and diesel oil-contaminated fine soils from central Poland

The objectives of this paper are to provide a regional description of the shrinkage parameters of Neogene clays and glacial tills from central Poland; and to present the effects of hydrocarbon contamination on the shrinkage behaviour of soils. Forty samples containing from 19 to 90% clay-size particles were tested. The comparison of the three methods applied has indicated that the shrinkage limit values obtained by the BS 1377-2 method provide a greater margin of safety when used in the classification of expansive soils and yield the best matching in the analysis of the variability of the shrinkage limit in relation to other soil index parameters. A good correlation was found between the shrinkability index and the consistency index, which leads to a new classification of soils. The shrinkage tests of clean and diesel oil-contaminated samples revealed that contamination has a significant and irregular effect on the values of shrinkage parameters. For low degree of contamination the shrinkage limit of both soils had the lowest values and the volumetric shrinkage was maximum, and then with increasing ON content the shrinkage limit values tend to increase, while the volumetric shrinkage decreased.

Comparative Evaluation of Two Glass Polyalkenoate Cements: An In Vivo Pilot Study Using a Sheep Model

Poly(methyl methacrylate) (PMMA) is used to manage bone loss in revision total knee arthroplasty (rTKA). However, the application of PMMA has been associated with complications such as volumetric shrinkage, necrosis, wear debris, and loosening. Glass polyalkenoate cements (GPCs) have potential bone cementation applications. Unlike PMMA, GPC does not undergo volumetric shrinkage, adheres chemically to bone, and does not undergo an exothermic setting reaction. In this study, two different compositions of GPCs (GPCA and GPCB), based on the patented glass system SiO2-CaO-SrO-P2O5-Ta2O5, were investigated. Working and setting times, pH, ion release, compressive strength, and cytotoxicity of each composition were assessed, and based on the results of these tests, three sets of samples from GPCA were implanted into the distal femur and proximal tibia of three sheep (alongside PMMA as control). Clinical CT scans and micro-CT images obtained at 0, 6, and 12 weeks revealed the varied radiological responses of sheep bone to GPCA. One GPCA sample (implanted in the sheep for 12 weeks) was characterized with no bone resorption. Furthermore, a continuous bone–cement interface was observed in the CT images of this sample. The other implanted GPCA showed a thin radiolucent border at six weeks, indicating some bone resorption occurred. The third sample showed extensive bone resorption at both six and 12 weeks. Possible speculative factors that might be involved in the varied response can be: excessive Zn2+ ion release, low pH, mixing variability, and difficulty in inserting the samples into different parts of the sheep bone.