Nitrate isotope database for meteoric waters, surface water, soil water, and groundwaters

Author(s):  
Stephen D. Sebestyen ◽  
Carol Kendall ◽  
Emily M. Elliott ◽  
Sherry L. Schiff ◽  
Rebecca T. Barnes ◽  
...  
Koedoe ◽  
2020 ◽  
Vol 62 (2) ◽  
Author(s):  
Edward S. Riddell ◽  
Jaco Nel ◽  
Johan Van Tol ◽  
Daniel Fundisi ◽  
Faith Jumbi ◽  
...  

The semi-arid conditions in savanna landscapes ensure that ephemeral drainage dominates the hydrological network in these dryland systems. Quantification of their hydrological processes is important to inform ecosystem understanding and future conservation efforts under a changing climate, and to provide guidance for restoration. By combining in situ hydrometric observations, hydrochemistry, remote sensing and a soil water balance model, we characterise the groundwater–surface water interactions in ephemeral low-order catchments of the granitoid regions of the southern Kruger National Park (KNP). Streams at the lowest orders are augmented by lateral interflows from the catena, although the second- and third-order stream reaches are conduits for groundwater recharge to the fractured rock aquifer; the soils of the crests and foot-slopes also show preferential flow, and are truly recharge soils, whilst the duplex soils of the midslopes clearly show their responsive nature to a low soil moisture deficit in the shallow horizons. Actual evaporation (aET) differed between catena elements with surprisingly little variation at third-order hillslopes, with the greatest overall aET at the first order. Meanwhile, soil water balances demonstrated a significant variation in storage of the riparian zones as a result of interflow from upslope and aET losses. Furthermore, data support broader-scale observations that groundwater recharge through the vadose zone to the fractured rock aquifer is dependent upon threshold antecedent precipitation conditions. Moderate precipitation events (5 mm/day – 35 mm/day) over a 2–3 week period initiate groundwater responses with a 2–3 month lag, whilst intense precipitation events (100 mm/day) are expressed within 2–3 weeks.Conservation implications: Understanding the lateral connectivity of terrestrial ecosystems to the ephemeral drainage network expressed via hydrological processes in these savanna landscapes is important to infer potential impacts of climate variability on the continued conservation of these ecosystems, both within and external to protected areas.


2018 ◽  
Author(s):  
Aaron A. Smith ◽  
Doerthe Tetzlaff ◽  
Chris Soulsby

Abstract. Quantifying ecohydrological controls on soil water availability is essential to understand temporal variations in catchment storage. Soil water is subject to numerous time-variable fluxes (evaporation, root-uptake, and recharge), each with different water ages which in turn affect the age of water in storage. Here, we adapt StorAge Selection (SAS) function theory to investigate water flow in soils and identify soil evaporation and root-water uptake sources from depth. We use this to quantify the effects of soil-vegetation interactions on the inter-relationships between water fluxes, storage, and age. The novel modification of the SAS function framework is tested against empirical data from two contrasting soil-vegetation units in the Scottish Highlands; these are characterised by significant preferential flow, transporting younger water through the soil during high soil moisture conditions. Dominant young water fluxes, along with relatively low rainfall intensities, explain relatively stable soil water ages through time and with depth. Soil evaporation sources were more time-invariant with high preference for near-surface water, independent of soil moisture conditions, and resulting in soil evaporation water ages similar to near-surface soil waters (mean age: 50–65 days). Sources of root-water uptake were more variable: preferential near-surface water uptake occurred in wet conditions, with a deeper root-uptake source during dry soil conditions, which resulted in more variable water ages of transpiration (mean age: 56–79 days). The simple model structure provides a parsimonious means of constraining the water age of multiple fluxes from the upper part of the critical zone during time-varying conditions improving our understanding of vegetation influences on catchment scale water fluxes.


2011 ◽  
Vol 8 (2) ◽  
pp. 4151-4193 ◽  
Author(s):  
J. Tang ◽  
B. Zhang ◽  
C. Gao ◽  
H. Zepp

Abstract. Compared with overland flow from agricultural hillslopes, subsurface lateral flow is often overlooked partly due to monitoring difficulties and the lack of quantitative identification its role in nutrient delivery to surface water. The objectives of this study were to examine how subsurface lateral flow generates from hillslopes to streams and to quantify its contribution to nutrient loading in streams. Hillslope hydrology and stream hydrology were simultaneously monitored during two typical storms and subsurface flow was separated by chemical mixing model. Positive soil water potential at the soil depths from 0.60 to 1.50 m was observed at the middle course of the storm events, suggesting soil water was saturated following the storms and the drained after the end of the storms. The hydro-chemographs in the stream in a trench below a hillslope showed that suspended sediment, particulate N and P were dominant in the stream during the storms, while after the end of the rainstorms the nitrate concentration and electricity conductivity (EC) in the stream increased with time on the recession limbs of the hydrographs. Meanwhile, a rebound or delayed curve appeared on the recession limbs for several hours immediately after the end of rainstorms. All the synchronous data confirmed nitrate was delivered from the hillslope through subsurface lateral flow to the streams even after the end of rainstorms. A chemical mixing model based on EC and pH showed that the subsurface lateral flow during the rainstorm events accounted for 29% to 45% of the stream flow and about 86% of total NO3−-N loss (or 26% of total N loss) from the peanut hillslope and for 5.7% to 7.3% of the stream flow about 69% of total NO3−-N loss (or 28% of total N loss) from the catchment outlet. The results suggest that subsurface lateral flow generated within a shallow soil profile have to be paid more attention for controlling non-point source surface water pollution from intensive agricultural catchment.


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