scholarly journals The Impact of Handbooks on the Concept Understanding and Learning Interests of Students on the Concept of Reaction Rate

2021 ◽  
Vol 7 (2) ◽  
pp. 239
Author(s):  
Zulham Handayani ◽  
A. Halim ◽  
Ibnu Khaldun
Author(s):  
Alexander P. Parobek ◽  
Patrick M. Chaffin ◽  
Marcy H. Towns

Reaction coordinate diagrams (RCDs) are chemical representations widely employed to visualize the thermodynamic and kinetic parameters associated with reactions. Previous research has demonstrated a host of misconceptions students adopt when interpreting the perceived information encoded in RCDs. This qualitative research study explores how general chemistry students interpret points and trends on a RCD and how these interpretations impact their inferences regarding the rate of a chemical reaction. Sixteen students participated in semi-structured interviews in which participants were asked to interpret the points and trends along provided RCDs and to compare relative reaction rates between RCDs. Findings derived from this study demonstrate the diversity of graphical reasoning adopted by students, the impact of students’ interpretations of the x-axis of a RCD on the graphical reasoning employed, and the influence of these ideas on inferences made about reaction rate. Informed by analytical frameworks grounded in the resources framework and the actor-oriented model of transfer, implications for instruction are provided with suggestions for how RCDs may be presented to assist students in recognizing the critical information encoded in these diagrams.


Author(s):  
Guglielmo Costa ◽  
Alessandro Bressan ◽  
Michela Mapelli ◽  
Paola Marigo ◽  
Giuliano Iorio ◽  
...  

Abstract Pair-instability (PI) is expected to open a gap in the mass spectrum of black holes (BHs) between ≈40 − 65 M⊙ and ≈120 M⊙. The existence of the mass gap is currently being challenged by the detection of GW190521, with a primary component mass of $85^{+21}_{-14}$ M⊙. Here, we investigate the main uncertainties on the PI mass gap: the 12C(α, γ)16O reaction rate and the H-rich envelope collapse. With the standard 12C(α, γ)16O rate, the lower edge of the mass gap can be 70 M⊙ if we allow for the collapse of the residual H-rich envelope at metallicity Z ≤ 0.0003. Adopting the uncertainties given by the starlib database, for models computed with the 12C(α, γ)16O rate −1 σ, we find that the PI mass gap ranges between ≈80 M⊙ and ≈150 M⊙. Stars with MZAMS > 110 M⊙ may experience a deep dredge-up episode during the core helium-burning phase, that extracts matter from the core enriching the envelope. As a consequence of the He-core mass reduction, a star with MZAMS = 160 M⊙ may avoid the PI and produce a BH of 150 M⊙. In the −2 σ case, the PI mass gap ranges from 92 M⊙ to 110 M⊙. Finally, in models computed with 12C(α, γ)16O −3 σ, the mass gap is completely removed by the dredge-up effect. The onset of this dredge-up is particularly sensitive to the assumed model for convection and mixing. The combined effect of H-rich envelope collapse and low 12C(α, γ)16O rate can lead to the formation of BHs with masses consistent with the primary component of GW190521.


Author(s):  
Fabian Guba ◽  
Florian Gaulhofer ◽  
Dirk Ziegenbalg

AbstractDynamic irradiation is a potent option to influence the interaction between photochemical reactions and mass transport to design high performant and efficient photochemical processes. To systematically investigate the impact of this parameter, the photocatalytic reduction of nitrobenzene was conducted as a test reaction. Dynamic irradiation was realized through provoked secondary flow patterns, multiple spatially distributed light emitting diodes (LEDs) and electrical pulsation of LEDs. A combined experimental and theoretical approach revealed significant potential to enhance photochemical processes. The reaction rate was accelerated by more than 70% and even more important the photonic efficiency was increased by more than a factor of 4. This renders imposed dynamic irradiation an innovative and powerful tool to intensify photoreactions on the avenue to large scale sustainable photochemical processes.


2020 ◽  
Vol 6 (7) ◽  
pp. 1931-1938
Author(s):  
Shanshan Zheng ◽  
Chao Li ◽  
Gaoliang Wei

Two quantitative structure–activity relationship (QSAR) models to predict keaq− of diverse organic compounds were developed and the impact of molecular structural features on eaq− reactivity was investigated.


2018 ◽  
Vol 234 (2) ◽  
pp. 19 ◽  
Author(s):  
C. E. Fields ◽  
F. X. Timmes ◽  
R. Farmer ◽  
I. Petermann ◽  
William M. Wolf ◽  
...  

2008 ◽  
Vol 58 (5) ◽  
pp. 1147-1154 ◽  
Author(s):  
Y. Lester ◽  
I. Gozlan ◽  
D. Avisar ◽  
H. Mamane

The photodegradation rate of sulphadimethoxine (SMT) in water was studied under polychromatic UV light, in a bench scale apparatus. SMT photolysis was carried out at pH levels of 2.5, 6.5 and 10 to study the impact of acid base properties on the degradation of SMT. The highest SMT photolysis fluence based rate was found at pH = 2.5 (k=7.22 × 10−4 cm2/mJ) and the lowest rate at pH = 10 (k=4.72 × 10−4 cm2/mJ), thus the reaction rate decreases with an increase in pH between pH values of 2.5–10. Results indicated that direct photolysis is not satisfactory for degradation of SMT by polychromatic UV lamp as a fluence of approximately 7,000 mJ/cm2 is needed to break down 99% of SMT at pH 6.5. The photodegradation products of SMT were studied at various pH values. Photodegradation of SMT results in dissimilar relative amounts of intermediates formed at different pH values which may exert a photon demand and impact on SMT photodegradation rate.


1978 ◽  
Vol 51 (1) ◽  
pp. 1-6 ◽  
Author(s):  
R. A. Pett ◽  
R. J. Tabar

Abstract For the type of natural rubber compound used in the impact absorbing bumper system, it has been shown that an apparent zero order reaction rate is valid for the degradation of tensile strength, elongation at break and tear strength during oven aging. The zero order rate applies to aging times beyond an induction period and prior to the onset of hardening. Since the rates follow the Arrhenius equation for rate-temperature dependence, accelerated aging can be readily applied to the prediction of long term changes in properties (within the temperature range of 82–171°C). The magnitude of the activation energy determined from losses in mechanical properties indicates the dominance of oxidative degradation as the mechanism of the losses in properties.


2021 ◽  
Vol 2 (1) ◽  
pp. 35-43
Author(s):  
Komarudin Komarudin ◽  
Suherman Suherman ◽  
Anita Anggraini

This research aims to determine the influence of students' learning activities on the ability to understanding mathematical concepts through the STEM Learning Approach Makerspace model based on PBL on SPLDV materials. As for the type of research Quasi-Experiments. The population in this study was 90 students who were distributed into 3 classes with 2 classes that sampled grades VIII A and VIII C. The sampling techniques in this study used randomized classes and data collection techniques in this study were tests and observations, while the research instruments used preliminary tests and final tests to measure the ability to understand mathematical concepts and observation sheets to see students' learning activities. Data analysis techniques using a two-way ANOVA test. The research showed that there is an influence of the PBL-based Makerspace STEM Learning Approach model on the ability to understand mathematical concepts, there is no influence on students' learning activities on mathematical concept comprehension capabilities, and there is no interaction between the PBL-based Stem Learning Approach Makerspace model and student learning activities on the ability to understand mathematical concepts. Conclusion, there is a positive direct effect of cognitive structures on the ability to understanding mathematical concepts.


2020 ◽  
Vol 22 (24) ◽  
pp. 13390-13397
Author(s):  
Edina Balog ◽  
Paszkál Papp ◽  
Ágota Tóth ◽  
Dezső Horváth ◽  
Gábor Schuszter

The evolution of different confined precipitation patterns is determined by the ratio of the chemical and hydrodynamic time scales.


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