scholarly journals STUDY THERMAL BEHAVIOR OF HEAT CURE POLY (METHYL METHACRYLATE) REINFORCED BY BAMBOO AND RICE HUSK POWDERS FOR DENTURE APPLICATIONS

2019 ◽  
Vol 11 (4) ◽  
pp. 417-425
Author(s):  
Jawad K. Oleiwi ◽  
Qahtan Adnan Hamad ◽  
Hadil Jabbar Abdul Rahman
Keyword(s):  
Thermal Conductivity ◽  
Thermal Diffusivity ◽  
Methyl Methacrylate ◽  
Thermal Behavior ◽  
Rice Husk ◽  
Weight Fraction ◽  
Scanning Calorimetry ◽  
Poly Methyl Methacrylate ◽  
Heat Cure ◽  
Naoh Solution

The present research, studies the effect of adding two different types of reinforcing powders, which included: Bamboo (Ba) and Rice Husk (RH), that added with different weight fractions (2, 4, 6 and 8 wt. %), and with the selected size particles of (25µm and 75µm) on thermal behavior of heat Cure Poly (Methyl Methacrylate) such as thermal conductivity and thermal diffusivity in addition to the differential scanning calorimetry (DSC) analysis  and these tests were accomplished at temperature of laboratory. The poly Methyl Methacrylate properties which reinforced by (Bamboo and Rice Husk) powders are mainly influenced by the interfacial adhesion strength between the powders and the matrix, and in order to get better correlation between the natural powder and PMMA matrix, so the powders were treated with alkali (sodium hydroxide NaoH) solution prior to use as reinforcement materials. The results showed that the values of the thermal conductivity and thermal diffusivity increased with increasing of the weight fraction for both particle sizes (25 µm and 75 µm) of natural powders.

scholarly journals Use of Almond Shells and Rice Husk as Fillers of Poly(Methyl Methacrylate) (PMMA) Composites

Materials ◽  
2017 ◽  
Vol 10 (8) ◽  
pp. 872 ◽  
Author(s):  
Alessandra Sabbatini ◽  
Silvia Lanari ◽  
Carlo Santulli ◽  
Claudio Pettinari
Keyword(s):  
Methyl Methacrylate ◽  
Rice Husk ◽  
Poly Methyl Methacrylate

scholarly journals Effect of Low Hydroxyapatite Loading Fraction on the Mechanical and Tribological Characteristics of Poly(Methyl Methacrylate) Nanocomposites for Dentures

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 857
Author(s):  
Ahmed Fouly ◽  
Ahmed Mohamed Mahmoud Ibrahim ◽  
El-Sayed M. Sherif ◽  
Ahmed M.R. FathEl-Bab ◽  
A.H. Badran
Keyword(s):  
Friction Coefficient ◽  
Yield Strength ◽  
Methyl Methacrylate ◽  
Weight Fraction ◽  
Tribological Characteristics ◽  
Compressive Yield Strength ◽  
Wear Loss ◽  
Mechanical Mixing ◽  
Poly Methyl Methacrylate ◽  
Mechanical And Tribological Characteristics

Denture base materials need appropriate mechanical and tribological characteristics to endure different stresses inside the mouth. This study investigates the properties of poly(methyl methacrylate) (PMMA) reinforced with different low loading fractions (0, 0.2, 0.4, 0.6, and 0.8 wt.%) of hydroxyapatite (HA) nanoparticles. HA nanoparticles with different loading fractions are homogenously dispersed in the PMMA matrix through mechanical mixing. The resulting density, Compressive Young’s modulus, compressive yield strength, ductility, fracture toughness, and hardness were evaluated experimentally; the friction coefficient and wear were estimated by rubbing the PMMA/HA nanocomposites against stainless steel and PMMA counterparts. A finite element model was built to determine the wear layer thickness and the stress distribution along the nanocomposite surfaces during the friction process. In addition, the wear mechanisms were elucidated via scanning electron microscopy. The results indicate that increasing the concentration of HA nanoparticles increases the stiffness, compressive yield strength, toughness, ductility, and hardness of the PMMA nanocomposite. Moreover, tribological tests show that increasing the nanoparticle weight fraction considerably decreases the friction coefficient and wear loss.

Plasticizer effect on dielectric properties of poly(methyl methacrylate)/titanium dioxide composites

2021 ◽  
pp. 096739112110147
Author(s):  
Ufuk Abaci ◽  
H Yuksel Guney ◽  
Mesut Yilmazoglu
Keyword(s):  
Dielectric Constant ◽  
Titanium Dioxide ◽  
Dielectric Properties ◽  
Methyl Methacrylate ◽  
Pure Pmma ◽  
Segmental Mobility ◽  
Scanning Calorimetry ◽  
Poly Methyl Methacrylate ◽  
Casting Technique ◽  
Lcr Meter

The effect of plasticizer on dielectric properties of poly(methyl methacrylate) (PMMA)/titanium dioxide (TiO2) composites was investigated. Propylene carbonate (PC) was used as plasticizer in the samples which were prepared with the conventional solvent casting technique. Scanning Electron Microscopy with Energy Dispersive X-Ray Analysis (SEM-EDX) and Differential scanning calorimetry (DSC) analyses and LCR Meter measurements (performed between 300 K and 400 K), were conducted to examine the properties of the composites. With the addition of plasticizer, the thermal properties have changed and the dielectric constant of the composite has increased significantly. The glass transition temperature of pure PMMA measured 121.7°C and this value did not change significantly with the addition of TiO2, however, 112°C was measured in the sample with the addition 4 ml of PC. While the dielectric constant of pure PMMA was 3.64, the ε′ value increased to 5.66 with the addition of TiO2 and reached 12.6 with the addition of 4 ml PC. These changes have been attributed to increase in amorphous ratio that facilitates polymer dipolar and segmental mobility.

Influence of acrylonitrile butadiene rubber on recyclability of blends prepared from poly(vinyl chloride) and poly(methyl methacrylate)

2018 ◽  
Vol 36 (6) ◽  
pp. 495-504 ◽  
Author(s):  
Sunil S Suresh ◽  
Smita Mohanty ◽  
Sanjay K Nayak
Keyword(s):  
Methyl Methacrylate ◽  
Vinyl Chloride ◽  
Butadiene Rubber ◽  
Scanning Calorimetry ◽  
Elongation At Break ◽  
Poly Methyl Methacrylate ◽  
Impact Performance ◽  
Acrylonitrile Butadiene Rubber ◽  
Poly Vinyl Chloride ◽  
Spectroscopy Studies

The current investigation deals with the recycling possibilities of poly(vinyl chloride) and poly(methyl methacrylate) in the presence of acrylonitrile butadiene rubber. Recycled blends of poly(vinyl chloride)/poly(methyl methacrylate) are successfully formed from the plastic constituents, those are recovered from waste computer products. However, lower impact performance of the blend and lower stability of the poly(vinyl chloride) phase in the recycled blend restricts its further usage in industrial purposes. Therefore, effective utilisation acrylonitrile butadiene rubber in a recycled blend was considered for improving mechanical and thermal performance. Incorporation of acrylonitrile butadiene rubber resulted in the improvement in impact performance as well as elongation-at-break of the recycled blend. The optimum impact performance was found in the blend with 9 wt% acrylonitrile butadiene rubber, which shows 363% of enhancement as compared with its parent blend. Moreover, incorporated acrylonitrile butadiene rubber also stabilises the poly(vinyl chloride) phase present in the recycled blend, similarly Fourier transform infrared spectroscopy studies indicate the interactions of various functionalities present in the recycled blend and acrylonitrile butadiene rubber. In addition to this, thermogravimetric analysis indicates the improvement in the thermal stability of the recycled blend after the addition of acrylonitrile butadiene rubber into it. The existence of partial miscibility in the recycled blend was identified using differential scanning calorimetry and scanning electron microscopy.

Thermal behavior and properties of polystyrene/poly(methyl methacrylate) blends

2003 ◽  
Vol 91 (1) ◽  
pp. 609-620 ◽  
Author(s):  
Chengzhi Chuai ◽  
Kristoffer Almdal ◽  
Jørgen Lyngaae-Jørgensen
Keyword(s):  
Methyl Methacrylate ◽  
Thermal Behavior ◽  
Poly Methyl Methacrylate

Characterizations of Multiphase Biogenic Polymer Blends from Poly(L-lactide) and Poly(methyl methacrylate)

2005 ◽  
Vol 897 ◽  
Author(s):  
Kim-Phuong Nguyen Le ◽  
Richard Long Lehman ◽  
Kenneth VanNess ◽  
James D Idol
Keyword(s):  
Methyl Methacrylate ◽  
Melt Processing ◽  
Scanning Calorimetry ◽  
Modulated Differential Scanning Calorimetry ◽  
Binary Blends ◽  
Poly Methyl Methacrylate ◽  
New Material ◽  
Superior Mechanical Properties ◽  
Interconnected Structure

AbstractMelt processing of binary immiscible polymer systems has been a focus of our group as an economical and scalable route to achieve synergistic or superior mechanical properties at and around the co-continuous region without the need of compatibilization. System of poly(L-lactide) (PLLA) and poly(methyl methacrylate) (PMMA) was selected to target bio-related applications, including bone fillers and scaffolds, where the biodegradability of PLLA will enable the integration of native tissue into the material over time. Tunable properties such as morphology, interconnectivity, resorbability and interfacial bonding control the long-term integrity of the new material and influence the interaction and integration of new tissue. Binary blends of PLLA and PMMA has been prepared and characterized over a large range of compositions in which regions of co-continuity are of special interest. Such regions exhibit a well interconnected structure that ensures controlled release of resorbable PLLA. Modulated differential scanning calorimetry (MDSC) detected a broad and unexpected transition between 70 °C and 100 °C. The magnitude of this transition is greatest within co-continuous regions, suggesting the presence of a complex or other derivative of the two primary phases. This complex appears to provide a degree of compatibilization between the phases, thus inducing mechanical property synergism which has been confirmed by flexural and nano-indentation analyses.

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