scholarly journals Molecular weight distribution of pollutants in leachate from full scale landfill site

2016 ◽  
Vol 18 (2) ◽  
pp. 360-370

<div> <p>The main objective of this study was to investigate the differences between the main pollutants in young and intermediate age landfill leachate in terms of molecular weight distribution (MWD). Parameters of chemical oxygen demand (COD), five day - biochemical oxygen demand (BOD<sub>5</sub>), ultraviolet-visible spectrophotometry (UV-VIS spectrum), total kjehldahl nitrogen (TKN), ammonia nitrogen (NH<sub>4</sub>-N) and colour were fractioned by membranes with the nominal pore size of 1&micro;m, 0.05 &micro;m, 100 kDa, 50 kDa, 10 kDa, 1 kDa and 0.5 kDa. According to the MWD results appropriate treatment technology could be choosen easily. According to the MWD results the ratio of soluble fractions (&lt; 0.5 kDa) to total COD was 34% in young leachate (YL), whereas low molecular weight (MW) fractions were dominant in intermediate leachate (IL) having this ratio of 71%. Presence of lower MW compounds in IL was also confirmed with UV-VIS absorbance spectra and its spectrum was higher than the YL. According to the specific ultraviolet absorption (SUVA) values, the organic contents of all of these processes were hydrophilic. TKN and NH<sub>4</sub>-N analysis showed that in IL all the nitrogen present is in ammoniacal form, instead in YL there is still the presence of organic nitrogen. Furthermore more than half of the TKN was less than 0.5 kDa while 6 % and 16 % TKN found in wastewater from IL and YL was higher than 1 &micro;m respectively. The observations of this study may provide useful criteria to choose a suitable landfill leachate treatment processes.</p> </div> <p>&nbsp;</p>

2015 ◽  
Vol 26 (3) ◽  
pp. 49-53 ◽  
Author(s):  
Anna Kwarciak-Kozłowska ◽  
Aleksandra Krzywicka

Abstract The goal of this article was to compare the efficiency of Fenton and photo-Fenton reaction used for stabilised landfill leachate treatment. The mass ratio of COD:H2O2 was fixed to 1:2 for every stages. The dose of reagents (ferrous sulphate/hydrogen peroxide) was different and ranged from 0.1 to 0.5. To determine the efficiency of treatment, the BOD (biochemical oxygen demand COD (chemical oxygen demand), TOC (total organic carbon) , ammonia nitrogen and BOD/COD ratio was measured. The experiment was carried out under the following conditions: temperature was 25ºC, the initial pH was adjusted to 3.0. Every processes were lasting 60 minutes. The most appropriate dose of reagents was 0.25 (Fe2+/H2O2). It was found that the application of UV contributed to increase of COD, TOC and ammonia removal efficiencies by an average of 14%.


2013 ◽  
Vol 295-298 ◽  
pp. 1472-1477
Author(s):  
Tao Yu ◽  
Tao Huang ◽  
Yin Xi Pan ◽  
Lin Hai Yang

The technology used the coagulation-sedimentation + electro-oxidation joint reactor has been studied to treat landfill leachate. First adding FeCl30.4g/L into all leachate for coagulation and sedimentation, its CODcr elimination rate can achieve 35%, but does have no effect on ammonia nitrogen. Then using electro-oxidation reactor to deal with effluent water, the reaction order of electro-oxidation reactor is first-level, as the reaction conditions are 20mA/cm2 of electric current density, 140min of reaction time, the leachate CODcr elimination rate can reach to above 90%, the ammonia nitrogen elimination rate meets to 98% around. Using coagulation-sedimentation + electro coagulation joint reactor to treat landfill leachate can get stable effluent water quality with good treatment effect, has very high elimination efficiency of CODcr and ammonia nitrogen. It is a suitable treatment technology for landfill leachate.


Author(s):  
Amin Mojiri ◽  
Lou Ziyang ◽  
Wang Hui ◽  
Ali Gholami

Municipal solid waste has continued to be a major problem in many nations of the world. The primary methods of treating landfill leachate include physical-chemical and biological treatment processes. Pressure-driven membrane processes, such as microfiltration, ultrafiltration, nanofiltration, and reverse osmosis (RO), are among the utmost promising and capable ways for treating landfill leachate. The concentrated leachate created from pressure-driven membrane processes typically represents 13%–30% of total incoming landfill leachate. Concentrated leachate is a dark brown solution with high levels of pollutants. Treating concentrated leachate is extremely difficult, and thus, a combined treatment system is suggested. In the present study, concentrated landfill leachate was treated using a combined treatment technique that included electro-ozonation. The removal efficacies of chemical oxygen demand (COD), color, and nickel were monitored at original pH (7.3) as well as current and voltage of 4 A and 9 V, respectively.


2010 ◽  
Vol 61 (3) ◽  
pp. 641-649 ◽  
Author(s):  
Mohammed J. K. Bashir ◽  
Hamidi Abdul Aziz ◽  
Mohd Suffian Yusoff ◽  
A. A. M. Huqe ◽  
Soraya Mohajeri

Landfill leachate is one of the major contamination sources. In this study, the ability of synthetic ion exchange resins which carry different mobile ion for removing color, chemical oxygen demand (COD), and ammonia nitrogen (NH3-N) from stabilized leachate was investigated. The synthetic resin INDION 225 Na as a cationic exchanger and INDION FFIP MB as an anionic exchanger were used in this study. INDION 225 Na was used in hydrogen form (H+) and in sodium form (Na+), while INDION FFIP MB resin was used in hydroxide form (OH−) and in calcium form (Cl−) form. The results indicated better removal of color, COD and NH3-N by using INDION 225 Na in H+ as compared with Na+ form, while no performance differences were observed by using INDION FFIP MB in OH− or Cl− form. Applying cationic resin followed by anionic resin achieved 97, 88 and 94, percent removal of color, COD and NH3-N. The residual amounts were 160 Pt-Co, 290 mg/L and 110 mg/L of color, COD and NH3-N respectively.


2014 ◽  
Vol 68 (6) ◽  
Author(s):  
Dao-Bin Zhang ◽  
Xiao-Gang Wu ◽  
Yi-Si Wang ◽  
Hui Zhang

AbstractA study was conducted on the treatment of landfill leachate by combining the sequencing batch biofilm reactor (SBBR) method with the electro-Fenton method. The reduction of chemical oxygen demand (COD), biological oxygen demand (BOD5), and ammonia nitrogen (NH4+-N) from the leachate by the SBBR method was investigated. For the electro-Fenton experiment, the changes in COD and total organic carbon (TOC) with the increase in H2O2 dosage and electrolysis time under optimal conditions were also analysed. The results showed that the average efficiencies of reduction of COD, BOD5, and NH4+ -N achieved using the SBBR method were 21.6 %, 54.7 %, and 56.1 %, respectively. The bio-effluent was degraded by the subsequent electro-Fenton process, which was rapid over the first 30 min then subsequently slowed. After 60 min of the electro-Fenton treatment, the efficiencies of reduction of TOC, COD, and BOD5 were 40.5 %, 71.6 %, and 61.0 %, respectively. There is a good correlation between the absorbance of leachate at 254 nm (UV254) and COD or TOC during the electro-Fenton treatment.


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