Steel protection by superhydrophobic coating in atmosphere with high content of aggressive components

Author(s):  
L. E. Tsygankova ◽  
◽  
A. A. Uryadnikov ◽  
A. V. Dorokhov ◽  
L. G. Knyazeva ◽  
...  
2020 ◽  
Vol 25 (3) ◽  

100% humidity and the presence in the air of such corrosion stimulants as CO2, NH3 and H2S are characteristic of livestock buildings. Under these conditions, a surface phase film of moisture is formed on the surface of the metals in which the indicated micro-mixtures of air are dissolved and hydrated almost completely with the formation of NH4OH and acids H2CO3 and H2S. The potentiodynamic polarization method was used to study the corrosion and kinetics of electrode processes on steel with a superhydrophobic coating in a NaCl background solution (used to provide sufficient electrical conductivity) saturated in pairs with CO2 and NH3, NH3 and H2S. Similar studies were conducted with uncoated electrodes. Superhydrophobic coating was obtained on the basis of laser texturing of the surface with subsequent hydrophobization with fluoroxysilane (wetting angle 165±2°, rolling angle 3±1°). The influence of the duration of the exposure of the electrodes in solution (0,25…168 h) on the kinetics of electrode processes and the corrosion rate of steel is considered. In the presence of CO2 and NH3 dissolution products, the corrosion rate of an electrode with a superhydrophobic coating on the second and third days of exposure is about an order of magnitude, and on the fourth and seventh days it is more than an order of magnitude lower than without coating. During the entire time the electrodes are in solution, the anode process on the superhydrophobic electrode is inhibited compared to an unprotected electrode. The medium containing the dissolution products of NH3 and H2S is more aggressive than the previous solution. Therefore, the corrosion rate of the electrodes without coating and with a coating here is higher than in the latter one. The corrosion rate of electrodes with superhydrophobic coating in the study period is only 1,5…2,5 times lower than that of uncoated electrodes. During the first day of exposure, the anode process is inhibited, and in the next 144 hours, on the contrary, it is facilitated in comparison with an unprotected electrode. Taking into account the corrosivity of the chloride solution, the possible effect of the dissolution products of aggressive air micro-impurities in the absence of background salt was analyzed.


2020 ◽  
Vol 12 (2) ◽  
pp. 02023-1-02023-4
Author(s):  
Sanjay S. Latthe ◽  
◽  
Rajaram S. Sutar ◽  
A. K. Bhosale ◽  
Vishnu S. Kodag ◽  
...  

2021 ◽  
pp. 51227
Author(s):  
Xiaoying Sun ◽  
Jing Liu ◽  
Zhihui Zhang ◽  
Yuanyuan Zhi ◽  
Lujiang Jin ◽  
...  

ACS Omega ◽  
2021 ◽  
Author(s):  
Mohamed A. Abbas ◽  
Ahmed M. Eid ◽  
Moaz M. Abdou ◽  
Amr Elgendy ◽  
Rasha A. El-Saeed ◽  
...  
Keyword(s):  

2021 ◽  
Vol 47 (11) ◽  
pp. 15825-15833
Author(s):  
Suk Wy Yap ◽  
Norhasnidawani Johari ◽  
Saiful Amri Mazlan ◽  
Noor Azlina Hassan

2021 ◽  
Vol 5 (4) ◽  
pp. 110
Author(s):  
Flaminio Sales ◽  
Andrews Souza ◽  
Ronaldo Ariati ◽  
Verônica Noronha ◽  
Elder Giovanetti ◽  
...  

Polydimethylsiloxane (PDMS) is a polymer that has attracted the attention of researchers due to its unique properties such as transparency, biocompatibility, high flexibility, and physical and chemical stability. In addition, PDMS modification and combination with other materials can expand its range of applications. For instance, the ability to perform superhydrophobic coating allows for the manufacture of lenses. However, many of these processes are complex and expensive. One of the most promising modifications, which consists of the development of an interchangeable coating, capable of changing its optical characteristics according to some stimuli, has been underexplored. Thus, we report an experimental study of the mechanical and optical properties and wettability of pure PDMS and of two PDMS composites with the addition of 1% paraffin or beeswax using a gravity casting process. The composites’ tensile strength and hardness were lower when compared with pure PDMS. However, the contact angle was increased, reaching the highest values when using the paraffin additive. Additionally, these composites have shown interesting results for the spectrophotometry tests, i.e., the material changed its optical characteristics when heated, going from opaque at room temperature to transparent, with transmittance around 75%, at 70 °C. As a result, these materials have great potential for use in smart devices, such as sensors, due to its ability to change its transparency at high temperatures.


Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 652
Author(s):  
Divine Sebastian ◽  
Chun-Wei Yao ◽  
Lutfun Nipa ◽  
Ian Lian ◽  
Gary Twu

In this work, a mechanically durable anticorrosion superhydrophobic coating is developed using a nanocomposite coating solution composed of silica nanoparticles and epoxy resin. The nanocomposite coating developed was tested for its superhydrophobic behavior using goniometry; surface morphology using scanning electron microscopy and atomic force microscopy; elemental composition using energy dispersive X-ray spectroscopy; corrosion resistance using atomic force microscopy; and potentiodynamic polarization measurements. The nanocomposite coating possesses hierarchical micro/nanostructures, according to the scanning electron microscopy images, and the presence of such structures was further confirmed by the atomic force microscopy images. The developed nanocomposite coating was found to be highly superhydrophobic as well as corrosion resistant, according to the results from static contact angle measurement and potentiodynamic polarization measurement, respectively. The abrasion resistance and mechanical durability of the nanocomposite coating were studied by abrasion tests, and the mechanical properties such as reduced modulus and Berkovich hardness were evaluated with the aid of nanoindentation tests.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2629
Author(s):  
Shimin Chen ◽  
Bo Li ◽  
Rengui Xiao ◽  
Huanhu Luo ◽  
Siwu Yu ◽  
...  

In this work, a ternary TiO2/Graphene oxide/Polyaniline (TiO2/GO/PANI) nanocomposite was synthesized by in situ oxidation and use as a filler on epoxy resin (TiO2/GO/PANI/EP), a bifunctional in situ protective coating has been developed and reinforced the Q235 carbon steel protection against corrosion. The structure and optical properties of the obtained composites are characterized by XRD, FTIR, and UV–vis. Compared to bare TiO2 and bare Q235, the TiO2/GO/PANI/EP coating exhibited prominent photoelectrochemical properties, such as the photocurrent density increased 0.06 A/cm2 and the corrosion potential shifted from −651 mV to −851 mV, respectively. The results show that the TiO2/GO/PANI nanocomposite has an extended light absorption range and the effective separation of electron-hole pairs improves the photoelectrochemical performance, and also provides cathodic protection to Q235 steel under dark conditions. The TiO2/GO/PANI/EP coating can isolate the Q235 steel from the external corrosive environment, and may generally be regarded a useful protective barrier coating to metallic materials. When the TiO2/GO/PANI composite is dispersed in the EP, the compactness of the coating is improved and the protective barrier effect is enhanced.


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